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Local Electrical Characterization of PVDF Textile Filament

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Abstract

The piezoelectric behavior of poly(vinylidene fluoride), PVDF, has been known for several decades and is clearly related to its crystalline phases. Many works made on films or fibers have focused on the characterization of the phase transitions during various PVDF processing and on its electromechanical activity by combining several techniques. Piezo-force microscopy (PFM) is an interesting tool to underline the crystalline forms and piezoelectricity efficiency of PVDF at the local scale. However, this technique is little used on samples in the form of fibers and in this case, it is most often nanofibers. In this work, two conventional PVDF textile filaments, with different weak draw ratio, are produced and analyzed by FTIR, XRD, and PFM. We demonstrate that the PFM analysis can be relevant for specimens presenting low signals during other characterizations. Therefore, the local piezo-/ferroelectricity into the fiber is highlighted underlining the existence of the polar phases of PVDF. Then, the effective piezoelectric coefficient d33 of PVDF fiber drawn with a ratio of 1.5 is estimated at 12 pm/V.

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Acknowledgements

This work is carried out under the regional program “Projets Emergents” and in the framework of the project entitled “Development of tricomponent piezoelectric polymer fibers for energy harvesting textiles”. The authors thank the Region Nord-Pas-de-Calais (France) for its financial support, and also gratefully acknowledge Solvay for the supply of PVDF. The “Région Hauts-de-France” and the “Fonds Européen de Développement Régional (FEDER)” under the “Contrat de Plan État-Région (CPER)” project “Chemistry and Materials for a Sustainable Growth” are also gratefully acknowledged for funding of MFP-3D microscope.

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Authors and Affiliations

  1. Unit of Catalysis and Solid Chemistry (UCCS), University Artois, CNRS, Centrale Lille, ENSCL, University Lille, UMR 8181, F-62300, Lens, France

    Anthony Ferri, Antonio Da Costa & Rachel Desfeux

  2. ENSAIT, GEMTEX — Textile Research Laboratory, F-59000, Lille, France

    François Rault, Cédric Cochrane, Matthieu Boudriaux, Guillaume Lemort, Christine Campagne & Eric Devaux

  3. LMCPA EA 2443, UPHF, F-59313, Valenciennes, France

    Christian Courtois

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  1. Anthony Ferri
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  2. François Rault
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Correspondence to François Rault.

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Ferri, A., Rault, F., Da Costa, A. et al. Local Electrical Characterization of PVDF Textile Filament. Fibers Polym 20, 1333–1339 (2019). https://doi.org/10.1007/s12221-019-8519-6

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  • DOI: https://doi.org/10.1007/s12221-019-8519-6

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