Skip to main content
Log in

Polyacrylamide grafted cellulose as an eco-friendly flocculant: Efficient removal of organic dye from aqueous solution

  • Published:
Fibers and Polymers Aims and scope Submit manuscript

Abstract

The efficient and safe flocculation of colored wastewaters from textile and leather industries is of great significance for natural environment and human health. In this work, an eco-friendly bamboo pulp cellulose grafting ployacrylamide (BPC-g-PAM) flocculant was synthesized and employed to remove organic dyes from dye solutions by flocculation. The flocculation performance of the synthesized BPC-g-PAM was evaluated by chroma and turbidity removals of a series of cationic and disperse dye solutions. A L9(34) orthogonal experiment was designed to optimize the flocculation process of the BPC-g-PAM. The positive results showed that, the BPC-g-PAM exhibited an excellent flocculation performance to organic dye solutions. The average decolorization rate reached 96.7 % and the chroma could be reduced to 5° or even lower for the disperse dye solutions. The mechanism of the BPC-g-PAM flocculation to disperse dyes was investigated and determined as chemical adsorption kinetics. Furthermore, the eco-friendly BPC-g-PAM also held an excellent biodegradability of 66.5 % at 45 d and 67.6 % at 90 d in soil extracting solution, which were far higher than the corresponding data of the commercial PAM.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. D. Tian, X. X. Zhang, C. H. Lu, G. P. Yuan, W. Zhang, and Z. H. Zhou, Cellulose, 21, 473 (2014).

    Article  CAS  Google Scholar 

  2. H. C. Zhu, Y. Zhang, X. G. Yang, L. Shao, X. M. Zhang, and J. M. Yao, Carbohydr. Polym., 135, 145 (2016).

    Article  CAS  Google Scholar 

  3. A. K. Verma, R. R. Dash, and P. Bhunia, J. Environ. Manage., 93, 154 (2012).

    Article  CAS  Google Scholar 

  4. M. M. El-Zawahry, F. Abdelghaffar, R. A. Abdelghaffar, and H. M. Mashaly, Fiber. Polym., 17, 186 (2016).

    Article  CAS  Google Scholar 

  5. C. Z. Liang, S. P. Sun, F. Y. Li, Y. K. Ong, and T. S. Chung, J. Membr. Sci., 469, 306 (2014).

    Article  CAS  Google Scholar 

  6. S. Eftekhari, A. Habibi-Yangjeh, and S. Sohrabnezhad, J. Hazard. Mater., 178, 349 (2010).

    Article  CAS  Google Scholar 

  7. S. M. K. N. Islam, A. S. W. Kurny, and F. Gulshan, Environmental Processes, 2, 215 (2015).

    Article  CAS  Google Scholar 

  8. H. C. Zhu, Y. Zhang, X. G. Yang, H. Y. Liu, X. M. Zhang, and J. M. Yao, Ind. Eng. Chem. Res., 54, 2825 (2015).

    Article  CAS  Google Scholar 

  9. K. Q. Zhou, Q. J. Zhang, B. Wang, J. J. Liu, P. Y. Wen, Z. Gui, and Y. Hu, J. Clean. Prod., 81, 281 (2014).

    Article  CAS  Google Scholar 

  10. L. Liu, Q. Liao, J. P. Xie, Z. Q. Qian, W. J. Zhu, X. Chen, X. P. Su, R. J. Meng, and J. M. Yao, Cellulose, 23, 3819 (2016).

    Article  CAS  Google Scholar 

  11. D. Vandamme, S. Eyley, G. Van den Mooter, K. Muylaert, and W. Thielemans, Bioresource Technol., 194, 270 (2015).

    Article  CAS  Google Scholar 

  12. T. Cai, H. J. Li, R. Yang, Y. W. Wang, R. H. Li, H. Yang, A. M. Li, and R. S. Cheng, Cellulose, 22, 1439 (2015).

    Article  CAS  Google Scholar 

  13. M. Riera-Torres, C. Gutiérrez-Bouzán, and M. Crespi, Desalination, 252, 53 (2010).

    Article  CAS  Google Scholar 

  14. S. H. Wang, M. X. Wei, Q. L. Xu, and H. S. Jia, Fiber. Polym., 17, 212 (2016).

    Article  CAS  Google Scholar 

  15. W. J. Zhu, L. Liu, Q. Liao, X. Chen, Z. Q. Qian, J. Y. Shen, J. L. Liang, and J. M. Yao, Cellulose, 23, 3785 (2016).

    Article  CAS  Google Scholar 

  16. L. Liu, Z. Y. Gao, X. P. Su, X. Chen, L. Jiang, and J. M. Yao, ACS Sustain. Chem. Eng., 3, 432 (2015).

    Article  CAS  Google Scholar 

  17. Z. Yang, K. X. Ren, E. Guibal, S. Y. Jia, J. C. Shen, X. T. Zhang, and W. B. Yang, Chemosphere, 161, 482 (2016).

    Article  CAS  Google Scholar 

  18. R. Das, S. Ghorai, and S. Pal, Chem. Eng. J., 229, 144 (2013).

    Article  CAS  Google Scholar 

  19. Q. T. Lin, H. L. Peng, S. X. Zhong, and J. X. Xiang, J. Hazard. Mater., 285, 199 (2015).

    Article  CAS  Google Scholar 

  20. Z. Yang, H. J. Li, H. Yan, H. Wu, H. Yang, Q. Wu, H. B. Li, A. M. Li, and R. S. Cheng, J. Hazard. Mater., 276, 480 (2014).

    Article  CAS  Google Scholar 

  21. G. Banerjee, S. Pandey, A. K. Ray, and R. Kumar, Water Air Soil Poll., 226, 4 (2015).

    Article  Google Scholar 

  22. S. Sinha, S. Mishra, and G. Sen, J. Int. J. Biol. Macromol., 60, 141 (2013).

    Article  CAS  Google Scholar 

  23. L. Liu, J. P. Xie, Y. J. Li, Q. Zhang, and J. M. Yao, Cellulose, 23, 723 (2016).

    Article  CAS  Google Scholar 

  24. E. Lam, K. B. Male, J. H. Chong, A. C. W. Leung, and J. H. T. Luong, Trends Biotechnol., 30, 283 (2012).

    Article  CAS  Google Scholar 

  25. H. Y. Liu, X. G. Yang, Y. Zhang, H. C. Zhu, and J. M. Yao, Water Res., 59, 165 (2014).

    Article  CAS  Google Scholar 

  26. Y. N. Phang, S. Y. Chee, C. O. Lee, and Y. L. Teh, Polym. Degrad. Stabil., 96, 1653 (2011).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Juming Yao.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yang, X., Chen, K., Zhang, Y. et al. Polyacrylamide grafted cellulose as an eco-friendly flocculant: Efficient removal of organic dye from aqueous solution. Fibers Polym 18, 1652–1659 (2017). https://doi.org/10.1007/s12221-017-1216-4

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12221-017-1216-4

Keywords

Navigation