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Enhanced thermal and mechanical properties of polypropylene composites with hyperbranched polyester grafted sisal microcrystalline

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Abstract

Polypropylene composites were prepared by melt compounding method with hyperbranched polyester grafted sisal microcrystalline and CaCO3. The thermal and mechanical properties of polypropylene composites were investigated by means of thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), wide angle X-ray diffraction (WAXD), scanning electron microscopy (SEM), melt flow indexer (MFI), dynamic mechanical analysis (DMA) and mechanical tests. It was found that the thermal and mechanical properties of PP composites were greatly improved by incorporating MCC-g-HPG-SA. For example, the impact strength, flexural strength, and toughness of the composites with 4 wt% MCC-g-HPG-SA loading were 64.71 kJ/m2, 42.72 MPa, and 2186.69 J/m3, significantly increased by 238.3 %, 18.4 % and 1843.9 % respectively, as compared with PP/MCC/CaCO3 composites. In addition, thermal stability of PP/MCCg-HPG-SA/CaCO3 composites also showed an obvious enhancement compared with PP/MCC/CaCO3 composites.

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References

  1. C. S. R. Freire, A. J. D. Silvestre, C. P. Neto, M. N. Belgacem, and A. Gandini, J. Appl. Polym. Sci., 100, 1093 (2006).

    Article  CAS  Google Scholar 

  2. N. A. Bhimte and P. T. Tayade, Aaps Pharmscitech, 8, 7 (2007).

    Article  Google Scholar 

  3. X. E. Xiao, S. R. Lu, B. Qi, C. Zeng, Z. K. Yuan, and J. H. Yu, RSC Adv., 4, 14928 (2014).

    Article  CAS  Google Scholar 

  4. S. K. Sahoo, S. Mohanty, and S. K. Nayak, J. Appl. Polym. Sci., 132, 12 (2015).

    Google Scholar 

  5. P. V. Joseph, K. Joseph, and S. Thomas, Compos. Sci. Technol., 59, 1625 (1999).

    Article  CAS  Google Scholar 

  6. X. Li, L. G. Tabil, and S. Panigrahi, J. Polym. Environ., 15, 25 (2007).

    Article  Google Scholar 

  7. H. Z. He, Y. Zhao, K. X. Wang, X. He, H. Q. Zhou, Y. D. Yao, and Y. H. Feng, Polym. Compos., 35, 1038 (2014).

    Article  CAS  Google Scholar 

  8. B. R. Lei, Y. R. Zhang, Y. J. He, Y. F. Xie, B. P. Xu, Z. D. Lin, L. H. Huang, S. Z. Tan, M. G. Wang, and X. Cai, Mater. Des., 66, 103 (2015).

    Article  CAS  Google Scholar 

  9. N. Chand, A. Nigrawal, and D. Jain, J. Nat. Fiber., 5, 270 (2008).

    Article  CAS  Google Scholar 

  10. Y. Q. Liu and M. Kontopoulou, Polymer, 47, 7731 (2006).

    Article  CAS  Google Scholar 

  11. N. Xu, W. F. Shi, M. Gong, and J. P. Feng, J. Mater. Sci., 41, 3707 (2006).

    Article  CAS  Google Scholar 

  12. C. Pavithran, P. S. Mukherjee, M. Brahmakumar, and A. D. Damodaran, J. Mater. Sci., 26, 455 (1991).

    Article  CAS  Google Scholar 

  13. I. O. Oladele and O. G. Agbabiaka, Fiber. Polym., 16, 650 (2015).

    Article  CAS  Google Scholar 

  14. A. Orue, A. Jauregi, C. Pena-Rodriguez, J. Labidi, A. Eceiza, and A. Arbelaiz, Compos. Pt. B-Eng., 73, 132 (2015).

    Article  CAS  Google Scholar 

  15. C. Yang, L. M. Zang, J. H. Qiu, E. Sakai, X. L. Wu, and Y. Iwase, RSC Adv., 4, 40345 (2014).

    Article  CAS  Google Scholar 

  16. A. Asif, W. F. Shi, X. F. Shen, and K. M. Nie, Polymer, 46, 11066 (2005).

    Article  CAS  Google Scholar 

  17. H. B. Hu, Y. Yuan, and W. F. Shi, Prog. Org. Coat., 75, 474 (2012).

    Article  CAS  Google Scholar 

  18. R. K. Kainthan, E. B. Muliawan, S. G. Hatzikiriakos, and D. E. Brooks, Macromolecules, 39, 7708 (2006).

    Article  CAS  Google Scholar 

  19. D. Schmaljohann, P. Potschke, R. Hassler, B. I. Voit, P. E. Froehling, B. Mostert, and J. A. Loontjens, Macromolecules, 32, 6333 (1999).

    Article  CAS  Google Scholar 

  20. K. Q. Sui, Q. B. Zhang, Y. Y. Liu, L. Tan, and L. Liu, e-Polymers, 14, 6 (2014).

    Article  Google Scholar 

  21. A. Sunder, M. Kramer, R. Hanselmann, R. Mulhaupt, and H. Frey, Angew. Chem. Int. Ed., 38, 3552 (1999).

    Article  CAS  Google Scholar 

  22. N. Xu, W. Zhou, and W. F. Shi, Polym. Adv. Technol., 15, 654 (2004).

    Article  CAS  Google Scholar 

  23. G. Jannerfeldt, L. Boogh, and J. A. E. Manson, Polym. Eng. Sci., 41, 293 (2001).

    Article  CAS  Google Scholar 

  24. N. Cai, C. Li, X. G. Luo, Y. N. Xue, L. Shen, and F. Q. Yu, J. Mater. Sci., 51, 797 (2016).

    Article  CAS  Google Scholar 

  25. L. Zhou, B. Z. He, J. C. Huang, Z. H. Cheng, X. Xu, and C. Wei, ACS Appl. Mater. Interfaces, 6, 7719 (2014).

    Article  CAS  Google Scholar 

  26. P. V. Joseph, K. Joseph, S. Thomas, C. K. S. Pillai, V. S. Prasad, G. Groeninckx, and M. Sarkissova, Compos. Pt. AAppl. Sci. Manuf., 34, 253 (2003).

    Article  Google Scholar 

  27. M. K. Seo, J. R. Lee, and S. J. Park, Mater. Sci. Eng. A, 404, 79 (2005).

    Article  Google Scholar 

  28. A. R. Bhattacharyya, T. V. Sreekumar, T. Liu, S. Kumar, L. M. Ericson, R. H. Hauge, and R. E. Smalley, Polymer, 44, 2373 (2003).

    Article  CAS  Google Scholar 

  29. J. W. Duan and Q. Dou, J. Appl. Polym. Sci., 130, 206 (2013).

    Article  CAS  Google Scholar 

  30. S. N. Maiti and P. K. Mahapatro, Int. J. Polym. Mater., 14, 205 (1990).

    Article  CAS  Google Scholar 

  31. X. H. Liu and Q. J. Wu, Polymer, 42, 10013 (2001).

    Article  CAS  Google Scholar 

  32. S. N. Maiti and P. K. Mahapatro, J. Appl. Polym. Sci., 42, 3101 (1991).

    Article  CAS  Google Scholar 

  33. R. Codispoti, D. V. Oliveira, R. S. Olivito, P. B. Lourenco, and R. Fangueiro, Compos. Pt. B-Eng., 77, 74 (2015).

    Article  CAS  Google Scholar 

  34. D. Wan, Y. J. Wang, X. Wen, J. Qiu, Z. W. Jiang, H. Y. Tan, and T. Tang, Polym. Eng. Sci., 52, 1457 (2012).

    Article  CAS  Google Scholar 

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Correspondence to Shaorong Lu, Yuqi Li or Jinhong Yu.

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Wu, L., Lu, S., Pan, L. et al. Enhanced thermal and mechanical properties of polypropylene composites with hyperbranched polyester grafted sisal microcrystalline. Fibers Polym 17, 2153–2161 (2016). https://doi.org/10.1007/s12221-016-6257-6

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  • DOI: https://doi.org/10.1007/s12221-016-6257-6

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