Skip to main content
Log in

Photocatalytic activity of ZnO composites against rhodamine B and rhodamine 6G

  • Published:
Fibers and Polymers Aims and scope Submit manuscript

Abstract

The development of nanostructures based on interaction of organic matrix and metal oxide particles (such as polypyrrole/zinc oxide composites) introduces interesting advantages due to synergistic/complementary photocatalytic activity of resulting material. Particularly, the available high surface area of resulting composite contributes with minimal aggregation of metal oxide nanoparticles and reduces the electron/hole pair recombination rate (if applied as a photocatalyst). Results indicate that superior performance is detected for composite of polypyrrole/zinc oxide applied in the photodegradation of rhodamine B and rhodamine 6G in comparison with degradation established by colloidal photocatalyst (surfactant/zinc oxide/dye). Progressive cleavage of organic dye molecule takes place in substitution to typical N-deethylation process.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Y. L. Lai, M. Meng, Y. F. Yu, X. T. Wang, and T. Ding, Appl. Catal. B - Environ., 105, 335 (2011).

    Article  CAS  Google Scholar 

  2. Q. Hui, J. Ye, N. Li, and J. Xiong, Fiber. Polym., 15, 1648 (2014).

    Article  CAS  Google Scholar 

  3. M. Ahmad, E. Ahmed, Z. L. Hong, W. Ahmed, A. Elhissi, and N. R. Khalid, Ultrason. Sonochem., 21, 761 (2014).

    Article  CAS  Google Scholar 

  4. A. Kocakusakoglu, M. Daglar, M. Konyar, H. C. Yatmaz, and K. Öztürk, J. Eur. Ceram. Soc., 35, 2845 (2015).

    Article  CAS  Google Scholar 

  5. R. C. Pawar, D. H. Choi, J. S. Lee, and C. S. Lee, Mater. Chem. Phys., 151, 167 (2015).

    Article  CAS  Google Scholar 

  6. E. G. L. Oliveira, J. J. Rodrigues, and H. P. de Oliveira, Chem. Eng. J., 172, 96 (2011).

    Article  CAS  Google Scholar 

  7. E. R. Macedo, L. De Boni, L. Misoguti, C. R. Mendonça, and H. P. de Oliveira, Colloid Surf. A-Physicochem. Eng. Asp., 392, 76 (2011).

    Article  CAS  Google Scholar 

  8. M. A. Chougule, S. Sen, and V. B. Patil, J. Appl. Polym. Sci., 125, E541 (2012).

    Article  CAS  Google Scholar 

  9. M. A. Chougule, D. S. Dalavi, S. Mali, P. S. Patil, A. V. Moholkar, G. L. Agawane, J. H. Kim, S. Sen, and V. B. Patil, Measurement, 45, 1989 (2012).

    Article  Google Scholar 

  10. Y. Q. Chen, Z. W. Zhao, and C. X. Zhang, Synth. Met., 163, 51 (2013).

    Article  CAS  Google Scholar 

  11. M. Q. He, L. L. Bao, K. Y. Sun, D. X. Zhao, W. B. Li, J. X. Xia, and H. M. Li, Express Polym. Lett., 8, 850 (2014).

    Article  CAS  Google Scholar 

  12. E. R. Macedo, P. S. Oliveira, and H. P. de Oliveira, J. hotochem. Photobiol. A-Chem., 307–308, 108 (2015).

    Article  Google Scholar 

  13. A. H. P. de Oliveira and H. P. de Oliveira, Polym. Bull., 70, 579 (2013).

    Article  Google Scholar 

  14. Y. C. Yang, J. W. Wen, J. H. Wei, R. Xiong, J. Shi, and C. X. Pan, ACS Appl. Mater. Interface, 5, 6201 (2013).

    Article  CAS  Google Scholar 

  15. J. Hazarika and A. Kumar, Synth. Met., 175, 155 (2013).

    Article  CAS  Google Scholar 

  16. D. X. Han, Y. Chu, L. K. Yang, Y. Liu, and Z. X. Lv, Colloid Surf. A-Physicochem. Eng. Asp., 259, 179 (2005).

    Article  CAS  Google Scholar 

  17. J. Upadhyay and A. Kumar, Mater. Sci. Eng. B-Adv., 178, 982 (2013).

    Article  CAS  Google Scholar 

  18. S. X. Xing and G. K. Zhao, J. Appl. Polym. Sci., 104, 1987 (2007).

    Article  CAS  Google Scholar 

  19. R. N. Gayen, K. Sarkar, S. Hussain, R. Bhar, and A. K. Pal, Indian J. Pure Appl. Phy., 49, 470 (2011).

    CAS  Google Scholar 

  20. M. Babazadeh, F. R. Gohari, and A. Olad, J. Appl. Polym. Sci., 123, 1922 (2012).

    Article  CAS  Google Scholar 

  21. Y. Z. Fan, G. P. Chen, D. M. Li, Y. H. Luo, N. Lock, A. P. Jensen, A. Mamakhel, J. L. Mi, S. B. Iversen, Q. B. Meng, and B. B. Iversen, Int. J. Photoenergy, 2012, Art. Id. 173865 (2012).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Helinando P. de Oliveira.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Nascimento, K.N.d.S., de Oliveira, M.C.A., Oliveira, P.S. et al. Photocatalytic activity of ZnO composites against rhodamine B and rhodamine 6G. Fibers Polym 16, 2177–2183 (2015). https://doi.org/10.1007/s12221-015-5456-x

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12221-015-5456-x

Keywords

Navigation