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Synthesis of newly fluorinated thermoplastic polyurethane elastomers and their blood compatibility

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Abstract

In this paper, newly polyether polyol containing fluorine in the side chain, 6,9-polyoctafluorine hexanoic ether tetradecane glycol (PFEG) was successfully synthesized via cationic ring-opening polymerization method. By means of one-step bulk polymerization method, its mixture with polytetramethylene ether glycol (PTMEG) was used as soft segment to fabricate fluorinated thermoplastic polyurethane (FTPU) elastomers, which were further characterized by SEM, 1HNMR, FTIR, XRD, contact angle, tensile and thermal stability measurements. Hemocompatibility in vitro was evaluated through protein adsorption and platelet adhesion measurements, while cytocompatibility was assessed by MTT assay and cell adhesion. Results showed that the as-synthesized FTPU elastomers have satisfactory blood compatibility, cytocompatibility, mechanical and thermal stability properties.

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Authors and Affiliations

  1. School of Materials Science and Engineering, Shanghai Institute of Technology, Shanghai, 201418, China

    Run-Ping Jia, An-Xin Zong, Xin-Yao He, Jia-Yue Xu & Mao-song Huang

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  1. Run-Ping Jia
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  2. An-Xin Zong
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  3. Xin-Yao He
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  4. Jia-Yue Xu
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  5. Mao-song Huang
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Correspondence to Run-Ping Jia.

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Jia, RP., Zong, AX., He, XY. et al. Synthesis of newly fluorinated thermoplastic polyurethane elastomers and their blood compatibility. Fibers Polym 16, 231–238 (2015). https://doi.org/10.1007/s12221-015-0231-6

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  • DOI: https://doi.org/10.1007/s12221-015-0231-6

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