Skip to main content
Log in

Experimental investigation of liquid water droplet removal in a simulated polymer electrolyte membrane fuel cell gas channel with gas diffusion layer characteristics

  • Published:
Journal of Mechanical Science and Technology Aims and scope Submit manuscript

Abstract

Since the accumulation of liquid water droplets in gas flow channels significantly affects the performance of polymer electrolyte membrane (PEM) fuel cells, a comprehensive understanding of liquid water removal from the cell is of great importance to achieve optimal water management. This study is mainly concerned with the ex situ measurement of water droplet growth and its removal in a non-reacting simulated cathode channel for PEM fuel cells. To this end, the dynamic behavior of a liquid water droplet at the gas flow channel/gas diffusion layer (GDL) interface was investigated experimentally using a specially designed transparent cell device with different GDLs. The effects of the GDL parameters (GDL thickness and micro-porous layer (MPL) inclusion) on water droplet removal are mainly investigated by analyzing the contact angle hysteresis with inlet air flow rate (Reynolds number). The critical Reynolds number is employed to evaluate the droplet removal from the GDL surface. It is observed that the water droplet on a thinner GDL tends to be removed under a higher critical Reynolds number. In addition, it is shown that the GDL with an MPL requires a higher critical Reynolds number for the water droplet removal under the same droplet height. The results suggest that the structure of the GDL sample has considerable influence on the water droplet removal. It is thought that the data obtained from this study can provide useful insight into the design of a GDL with enhanced water removal capability for PEM fuel cells.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. Larminie and A. Dicks, Fuel cell systems explained, John Wiley & Sons, New York, USA (2000).

    Google Scholar 

  2. M. M. Mench, Fuel cell engines, 1st ed., John Wiley & Sons, New Jersey, USA (2008).

    Book  Google Scholar 

  3. Y. Wang, K. S. Chen, J. Mishler, S. C. Cho and C. C. Adroher, A review of polymer electrolyte membrane fuel cells: Technology, applications, and needs on fundamental research, Applied Energy, 88 (2011) 981–1007.

    Article  Google Scholar 

  4. K. Tüber, D. Pócza and C. Hebling, Visualization of water buildup in the cathode of a transparent PEM fuel cell, Journal of Power Sources, 124 (2003) 403–414.

    Article  Google Scholar 

  5. F. Y. Zhang, X. G. Yang and C. Y. Wang, Liquid water removal from a polymer electrolyte fuel cell, Journal of The Electrochemical Society, 153 (2006) A225–A232.

    Article  Google Scholar 

  6. H.-S. Kim and K. Min, Experimental investigation of dynamic responses of a transparent PEM fuel cell to step changes in cell current density with operating temperature, Journal of Mechanical Science and Technology, 22 (2008) 2274–2285.

    Article  Google Scholar 

  7. P. K. Das, A. Grippin, A. Kwong and A. Z. Weber, Liquid-Water-Droplet Adhesion-Force Measurements on Fresh and Aged Fuel-Cell Gas Diffusion Layers, Journal of The Electrochemical Society, 159 (5) (2012) B489–B496.

    Article  Google Scholar 

  8. S. C. Cho, Y. Wang and K. S. Chen, Droplet dynamics in a polymer electrolyte fuel cell gas channel: forces, deformation, and detachment. I: theoretical and numerical analyses, Journal of Power Sources, 206 (2012) 119–128.

    Article  Google Scholar 

  9. S. C. Cho, Y. Wang and K. S. Chen, Droplet dynamics in a polymer electrolyte fuel cell gas channel: forces, deformation, and detachment. II: comparisons of analytical solution with numerical and experimental results, Journal of Power Sources, 210 (2012) 191–197.

    Article  Google Scholar 

  10. C. E. Colosqui, M. J. Cheah, I. G. Kevrekidis and J. B. Benziger, Droplet and slug formation in polymer electrolyte membrane fuel cell flow channels: The role of interfacial forces, Journal of Power Sources, 196 (2011) 10057–10068.

    Article  Google Scholar 

  11. A. Esposito, A. D. Montello, Y. G. Guezennec and C. Pianese, Experimental investigation of water droplet-air flow interaction in a non-reacting PEM fuel cell channel, Journal of Power Sources, 195 (2010) 2691–2699.

    Article  Google Scholar 

  12. I. Manke et al., Investigation of water evolution and transport in fuel cells with high resolution synchrotron X-ray radiography, Applied Physics Letters, 90 (2007) 174105.

    Article  Google Scholar 

  13. K. W. Feindel, S. H. Bergens and R. E. Wasylishen, The influence of membrane electrode assembly water content on the performance of a polymer electrolyte membrane fuel cell as investigated by 1H NMR microscopy, Physical Chemistry Chemical Physics, 9 (15) (2007) 1850–1857.

    Article  Google Scholar 

  14. M. A. Hickner, N. P. Siegel, K. S. Chen, D. N. McBrayer, D. S. Hussey, D. L. Jacobson and M. Arif, Real-Time Imaging of Liquid Water in an Operating Proton Exchange Membrane Fuel Cell, Journal of The Electrochemical Society, 153 (5) (2006) A902–A908.

    Article  Google Scholar 

  15. Z. W. Dunbar and R. I. Masel, Magnetic resonance imaging investigation of water accumulation and transport in graphite flow fields in a polymer electrolyte membrane fuel cell: Do defects control transport? Journal of Power Sources, 182 (2008) 76–82.

    Article  Google Scholar 

  16. L. Hao and P. Cheng, An analytical model for micro-droplet steady movement on the hydrophobic wall of a micro-channel, International Journal of Heat and Mass Transfer, 53 (2010) 1243–1246.

    Article  MATH  Google Scholar 

  17. K. S. Chen, M. A. Hickner and D. R. Noble, Simplified models for predicting the onset of liquid water droplet instability at the gas diffusion layer/gas flow channel interface, International Journal of Energy Research, 29 (2005) 1113–1132.

    Article  Google Scholar 

  18. L. Chen, Y.-L. He and W.-Q. Tao, Effects of surface microstructures of gas diffusion layer on water droplet dynamic behaviors in a micro gas channel of proton exchange membrane fuel cells, International Journal of Heat and Mass Transfer, 60 (2013) 252–262.

    Article  Google Scholar 

  19. Y. B. Salah, Y. Tabe and T. Chikahisa, Two phase simulation in a channel of a polymer electrolyte membrane fuel cell using the lattice Boltzmann method, Journal of Power Sources, 199 (2012) 85–93.

    Article  Google Scholar 

  20. S. G. Kandlikar, E. J. See, M. Koz, P. Gopalan and R. Banerjee, Two-phase flow in GDL and reactant channels of a proton exchange membrane fuel cell, International Journal of Hydrogen Energy, 39 (2014) 6620–6636.

    Article  Google Scholar 

  21. R. Anderson, L. Zhang, Y. Ding, M. Blanco, X. Bi and D. P. Wilkinson, A critical review of two-phase flow in gas flow channels of proton exchange membrane fuel cells, Journal of Power Sources, 195 (2010) 4531–4553.

    Article  Google Scholar 

  22. S. Lister, D, Sinton and N. Djilali, Ex situ of liquid water transport in PEM fuel cell gas diffusion layer, Journal of Power Sources, 154 (2006) 95–105.

    Article  Google Scholar 

  23. T. C. Wu and N. Djilali, Experimental investigation of water droplet emergence in a model polymer electrolyte membrane fuel cell micro-channel, Journal of Power Sources, 208 (2012) 248–256.

    Article  Google Scholar 

  24. X. C. Adroher and Y. Wang, Ex situ and modeling study of two-phase flow in a single channel of polymer electrolyte membrane fuel cells, Journal of Power Sources, 196 (2011) 9544–9551.

    Article  Google Scholar 

  25. J. Li, J. Zhao and S. Wang, Gas-liquid two-phase flow in a mini-square-channel with a permeable wall (influence of surface characteristics of a permeable wall), International Journal of Heat and Mass Transfer, 66 (2013) 90–100.

    Article  Google Scholar 

  26. Y. Qin, X. Li, K. Jiao, Q. Du and Y, Yin, Effective removal and transport of water in a PEM fuel cell flow channel having a hydrophilic plate, Applied Energy, 113 (2012) 116–126.

    Article  Google Scholar 

  27. E. C. Kumber, K. V. Sharp and M. M. Mench, Liquid droplet behavior and instability in a polymer electrolyte fuel cell flow channel, Journal of Power Sources, 161 (2006) 333–345.

    Article  Google Scholar 

  28. A. Theodorakakos, T. Ous, M. Gavaises, J. M. Nouri, N. Nikolopoulos and H. Yanagihara, Dynamics of water droplets detached from porous surfaces of relevance to PEM fuel cells, Journal of Colloid and Interface Science, 300 (2006) 673–687.

    Article  Google Scholar 

  29. M. Mortazavi and K. Tajiri, Effect of the PTFE content in the gas diffusion layer on water transport in polymer electrolyte fuel cells (PEFCs), Journal of Power Sources, 245 (2014) 236–244.

    Article  Google Scholar 

  30. S.-K. Lee and K. Ito, Cross-Sectional Visualization and Analysis of Droplet Behavior in Gas Flow Channel in PEFC, Journal of The Electrochemical Society, 161 (1) (2014) F58–F66.

    Article  Google Scholar 

  31. P. Gopalan and S. G. Kandlikar, Effect of Channel Materials on Water Droplet Dynamics in a PEMFC Gas Channel, Journal of The Electrochemical Society, 160 (6) (2013) F487–F495.

    Article  Google Scholar 

  32. C. Novak, E. Hsu, R. Schuster and X. Wang, Measuring Critical Velocity of Water Droplet Removal on Gas Diffusion Layers of Proton Exchange Membrane Fuel Cells, Proceedings of the ASME 2013 11 th Fuel Cell Science, Engineering and Technology Conference, Minneapolis, MN, USA (2013) FuelCell2013-18084.

    Google Scholar 

  33. S. G. Kandlikar, M. L. Garofalo and Z. Lu, Water management in a PEMFC: Water transport mechanism and material degradation in gas diffusion layers, Fuel Cells, 11 (6) (2011) 814–823.

    Article  Google Scholar 

  34. R. Anderson, D. P. Wilkinson, X. Bi and L. Zhang, Two-phase flow pressure drop hysteresis in an operating proton exchange membrane fuel cell, Journal of Power Sources, 196 (2011) 8031–8040.

    Article  Google Scholar 

  35. Y. Hiramitsu, K. Kobayashi and M. Hori, Gas diffusion layer design focusing on the structure of the contact face with catalyst layer against water flooding in polymer electrolyte fuel cell, Journal of Power Sources, 195 (2010) 7559–7567.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Han-Sang Kim.

Additional information

Recommended by Associate Editor Yong-Tae Kim

Han-Sang Kim received his B.S. and M.S. degrees from the Department of Mechanical Engineering at Seoul National University in 1989 and 1991, respectively. He then obtained his Ph.D. from Seoul National University in 2005. He is currently an assistant professor in the Department of Mechanical and Automotive Engineering at Seoul National University of Science and Technology.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yoon, Y., Jo, Y. & Kim, HS. Experimental investigation of liquid water droplet removal in a simulated polymer electrolyte membrane fuel cell gas channel with gas diffusion layer characteristics. J Mech Sci Technol 28, 5221–5230 (2014). https://doi.org/10.1007/s12206-014-1146-7

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12206-014-1146-7

Keywords

Navigation