Abstract
The geochemical study of siliciclastic rocks from the Lower Cambrian of Parahio Valley has been studied to describe the provenance, chemical weathering and tectonic setting. The K2O/Al2O3 ratio and positive correlation of Co (r=0.85), Ni (r=0.86), Zn (r=0.82), Rb (r=0.98) with K2O reflects that the presence of clay minerals control the abundances of these elements and suggests a warm and humid climate for this region. The chondrite normalized REE pattern of the samples is equivalent to upper continental crust, which reflects enriched LREE and flat HREE with negative Eu anomaly. The tectonic setting discriminant diagram log[K2O/Na2O] vs. SiO2; [SiO2/Al2O3] vs. log[K2O/Na2O]; [SiO2/20] – [K2O+Na2O] – [TiO2+Fe2O3+MgO] indicates transitional tectonic setting from an active continental margin to a passive margin. The discriminant function plot indicates quartzose sedimentary provenance, and to some extent, the felsic igneous provenance, derived from weathered granite, gneissic terrain and/or from pre-existing sedimentary terrain. The CIA value indicates low to moderate degree of chemical weathering and the average ICV values suggests immature sediments deposited in tectonically active settings. The A–CN–K diagram indicates that these sediments were generated from source rocks of the upper continental crust.
Similar content being viewed by others
References
Armstrong-Altrin J S, Nagarajan R, Madhavaraju J, Rosalez-Hoz L, Lee Y I, Balaram V, Cruz-Martínez A and Avila-Ramírez G 2013 Geochemistry of the Jurassic and Upper Cretaceous shales from the Molango Region, Hidalgo, eastern Mexico: Implications for source-area weathering, provenance, and tectonic setting; Comptes Rendus Geosci. 345 185–202.
Armstrong-Altrin J S, Machain-Castillo M L, Rosales-Hoz L, Carranza-Edwards A, Sanchez-Cabeza J A and Ruíz-Fernández A C 2015 Geochemistry of deep sea sediments from the south-western Gulf of Mexico, Mexico: Implication for depositional environment; Cont. Shelf Res. 95 15–26.
Bau M and Dulski P 1996 Distribution of yttrium and rare-earth elements in the Penge and Kuruman iron-formations, Transvaal Supergroup, South Africa; Precamb. Res. 79 37–55.
Bhargava O N 2008a Paleozoic successions of Indian Plate; Geol. Soc. India Memoir 74 209–244.
Bhargava O N 2008b An update of introduction to the Spiti geology; J. Palaeontol. Soc. India 53 (2) 113–128.
Bhargava O N and Srikantia S V 1985 Trilobite and other trace fossils from the Kunzum La Formation, Eastern Lahaul Valley, Himachal Himalaya; J. Geol. Soc. India 26 880–886.
Bhargava O N and Bassi U K 1986 Silurian reefal buildups, Spiti–Kinnaur, Himachal Himalaya, India; Facies 15 35–52.
Bhargava O N and Bassi U K 1988 Trace fossils from the Paleozoic–Mesozoic sequence of Spiti–Kinnaur (Himachal Himalaya) with comments on palaeoenvironmental control on their frequency; J. Geol. Soc. India 32 227–238.
Bhargava O N, Kumar G and Gupta S S 1982 Late Lower to Early Middle Cambrian trace fossils, Spiti Valley, Himalachal Himalaya; J. Geol. Soc. India 23 (4) 183–191.
Bhargava O N, Srivastava R N and Gadhoke S K 1991 Late Proterozoic–Paleozoic Spiti basin; Sedimentary Basins of India, pp. 236–260.
Bhatia M R 1983 Plate tectonics and geochemical composition of sandstones; J. Geol. 91 611–627.
Bhatia M R and Cook K A W 1986 Trace element characteristics of graywackes and tectonic setting discriminant of sedimentary basins; Contrib. Mineral. Petrol. 92 181–193.
Condie C K, Noll P D and Conway Jr C M 1992 Geochemical and detrital mode evidence for two sources of Early Proterozoic sedimentary rocks from the Tonto basin Supergroup, central Arizona; Sedim. Geol. 77 51–76.
Cox R and Lowe D R 1995 A conceptual review of regional scale controls on the composition of clastic sediment and the coevolution of continental blocks and their sedimentary cover; J. Sedim. Res. 65 1–12.
Cullers R L and Graf J 1983 Rare earth elements in igneous rocks of the continental crust: intermediate and silicic rocks, ore petrogenesis; In: Rare-Earth Geochemistry (ed.) Henderson P. Elsevier, Amsterdam, pp. 275–312.
Dabard M P 1990 Lower Brioverian formations (Upper Proterozoic) of the Armorican Massif (France): Geodynamic evolution of source areas revealed by sandstone petrography and geochemistry; Sedim. Geol. 69 45–58.
DaPeng L, YueLong C, Zhong W, Yu L and Jian Z 2012 Paleozoic sedimentary record of the Xing-Meng Orogenic Belt, Inner Mongolia: Implications for the provenances and tectonic evolution of the Central Asian Orogenic Belt; Chinese Sci. Bull. 57 776–785.
Dickinson W R and Suczek C A 1979 Plate tectonics and sandstone composition; AAPG Bull. 63 2164–2182.
Etemad-Saeed N, Hosseini-Barzi M and Armstrong-Altrin J S 2011 Petrography and geochemistry of clastic sedimentary rocks as evidence for provenance of the Lower Cambrian Lalun Formation, Posht-ebadam block, Central Iran; J. Afr. Earth Sci. 61 142–159.
Fedo C M, Nesbitt H W and Young G M 1995 Unraveling the effects of potassium metasomatism in sedimentary rocks and paleosoils, with implications for paleoweathering conditions and provenance; Geology 23 921–924.
Fedo C M, Eriksson K and Krogstad E J 1996 Geochemistry of shales from the Archean (3.0 Ga) Buhwa Greenstone Belt, Zimbabwe: Implications for provenance and source-area weathering; Geochim. Cosmochim. Acta 60 1751–1763.
Fedo C M, Young G M and Nesbitt G M 1997 Paleoclimatic control on the composition of the Paleoproterozoic Serpent Formation, Huronian Supergroup, Canada: A greenhouse to icehouse transition; Precamb. Res. 86 201–223.
Fu X, Wang J, Zeng Y, Tan F and Feng X 2010 REE geochemistry of marine oil shale from the Changshe Mountain area, northern Tibet, China; Int. J. Coal Geol. 81 191–199.
Fuchs G 1981 Outline of the geology of the Himalaya; Mitt. Osterr. Geol. Ges. 74/75 101–127.
Fuchs G 1982 The geology of the Pin valley in Spiti, HP, India; Jahrb. Geol. Bundesanstalt. 125 325–359.
Gansser A 1964 Geology of the Himalaya; Interscience Publishers, London, 289p.
Govindaraju K 1994 Compilation of working values and sample description for 383 geostandards; Geostandards Newsletter 18. Special Issue l58p.
Griesbach C L 1891 Geology of the Central Himalayas; Geol. Surv. India Memoir 23 1–232.
Harnois L 1988 The CIW index: A new chemical index of weathering; Sedim. Geol. 55 319–322.
Hayden H H 1904 The geology of the Spiti with parts of Bashahr and Rupshu; Geol. Surv. India Memoir 36 (1) 1–129.
Heim A and Gansser A 1939 Central Himalayas: Geological Observations of the Swiss Expedition 1936; Memoir Societ. Helvetica Sci.
Kroonenberg S B 1994 Effects of provenance, sorting and weathering on the geochemistry of fluvial sands from different tectonic and climatic environments; Proc. 29th Int. Geol. Cong. A, pp. 69–81.
Kumar G, Raina B K, Bhargava O N, Maithy P K and Babu R 1984 The Precambrian–Cambrian boundary problem and its prospects, northwest Himalaya, India; Geol. Mag. 121 (3) 211–219.
Laird M G 1972 Sedimentology of the Greenland Group in the Paparoa Range, west coast, South Island; New Zeal. J. Geol. Geopys. 15 372–393.
Liu S, Liu Y, Ge L., Ye Z., Faxiong G and Zhang D 2006 REE geochemical characteristics and geological significance of mudstones from Neogene, Nanpu Sag, Bohai basin; Geoscience 20 449–456 (in Chinese).
Madhavaraju J 2015 Geochemistry of Campanian–Maastrichtian sedimentary rocks in the Cauvery basin, south India; In: Constraints on paleoweathering, provenance and Cretaceous environments (ed.) Ramkumar M, Chemostratigraphy: Concepts, Techniques and Applications; Elsevier Spec. Vol., pp. 185–214.
Madhavaraju J and Ramasamy S 2002 Petrography and major element geochemistry of Late Masstrichtian–Early Palaeocene sediments of Tiruchirapalli, Tamil Nadu – Paleoweathering and provenance implication; J. Geol. Soc. India 59 133–142.
Madhavaraju J and Lee Y I 2010 Influence of Deccan volcanism in the sedimentary rocks of Late Maastrichtian–Danian age of Cauvery basin, southeastern India: Constraints from Geochemistry; Curr. Sci. 98 528–537.
Madhavaraju J and González-León C M 2012 Depositional conditions and source of rare earth elements in carbonate strata of the Aptian–Albian Mural Formation, Pitaycachi section, northeastern Sonora, Mexico; Rev. Mex. Cienc. Geol. 29 478–491.
Madhavaraju J, González-León C M, Yong Il Lee Armstrong-Altrin J S and Reyes-Campero L M 2010 Geochemistry of the Mural Formation (Aptian-Albian) of the Bisbee Group, Northern Sonora, Mexico; Cretaceous Res. 31 400–414.
Madhavaraju J, Erik Ramirez-Montoya E, Monreal R, González–Leon C M, Pi-Puig T, Espinoza-Maldonado I G and Grijalva-Noriega F J 2016 Paleoclimate, paleoweathering and paleoredox conditions of Lower Cretaceous shales from the Mural Limestone, Tuape section, northern Sonora, Mexico: Constraints from clay mineralogy and geochemistry; Rev. Mex. Cienc. Geol. 33 (1) 34–48.
Matsuda 1985 Late Permian to early Triassic conodont paleobiogeography in the ‘Tethys Realm’; In: The Tethys, Her Paleogeography and Paleobiostratigraphy from Paleozoic to Mesozoic (eds) Nakazawa K and Dickins J M, Tokoyoi University Press, pp. 157–170.
McCann T 1991 Petrological and geochemical determination of provenance in the southern Welsh basin; In: Developments in Sedimentary Provenance (eds) Morton A C, Todd S P and Haughton P D W; Geol. Soc. Spec. Publ. 57 215–230.
McLennan S M and Taylor S R 1991 Sedimentary rocks and crustal evolution: Tectonic setting and secular trends ; J. Geol. 99 1–21.
McLennan S M, Hemming S, McDaniel D K and Hanson G N 1993 Geochemical approaches to sedimentation, provenance and tectonics; In: Processes Controlling the Composition of Clastic Sediments (eds) Johnson M J and Basu A, Geological Society of America Special Paper, USA, pp. 21–40.
Myrow P M, Thompson K R, Hughes N C, Paulsen T S, Sell B K and Parcha S K 2006 Cambrian stratigraphy and depositional history of the northern Indian Himalaya, Spiti Valley, north-central India; Geol. Soc. Am. 118 (3–4) 491–510.
Myrow P M, Hughes N C, Goodge J W, Fanning C M, Williams I S, Peng S, Bhargava O N, Parcha S K and Pogue K R 2010 Extraordinary transport and mixing of sediment across Himalayan central Gondwana during the Cambrian–Ordovician; Geol. Soc. Am. Bull. 122 (9–10) 1660–1670.
Nagarajan R, Madhavaraju J, Nagendra R, Armstrong-Altrin J S and Moutte J 2007a Geochemistry of Neoproterozoic shales of the Rabanpalli Formation, Bhima basin, Northern Karnataka, southern India: Implications for provenance and paleoredox conditions; Rev. Mex. Cienc. Geol. 24 150–160.
Nagarajan R, Armstrong-Altrin J S, Nagendra R, Madhavaraju J and Moutte J 2007b Petrography and geochemistry of terrigenous sedimentary rocks in the Neoproterozoic Rabanpalli Formation, Bhima basin, southern India: Implications for paleoweathering condition, provenance, and source rock composition; J. Geol. Soc. India 70 297–312.
Nath B N, Kunzendorf H and Pluger W L 2000 Influence of provenance, weathering and sedimentary process on the elemental ratios of the fine-grained fraction of the bedload sediments from the Vembanad Lake and the adjoining continental shelf; southwest coast of India; J. Sedim. Res. 70 1081–1094.
Nathan S 1976 Geochemistry of the Greenland Group (early Ordovician), New Zealand; New Zeal. J. Geol. Geop. 19 683–706.
Nesbitt H W and Young G M 1982 Early Proterozoic climates and plate motions inferred from major element chemistry of lutites; Nature 299 715–717.
Nesbitt H W and Young G M 1984 Prediction of some weathering trends of plutonic and volcanic rocks based on thermodynamic and kinetic considerations; Geochim. Cosmochim. Acta 8 1523–1534.
Nyakairu G W A and Koeerl C 2001 Mineralogical and chemical composition and distribution of rare earth elements in clay-rich sediments from central Uganda; Geochem. J. 35 13–28.
Pandey S and Parcha S K 2013 Systematics, biometry of the species Opsidiscus from the middle Cambrian succession of the Spiti basin, India; J. Geol. Soc. India 82 330–338.
Parcha S K 1996 Cambrian biostratigraphy in the Tethyan zone of the Spiti Himalaya and its boundary problems; Newsl. Stratigr. 34 (1) 3–11.
Parcha S K 1998 Biostratigraphy of the Middle Cambrian sequences of Spiti Himalaya and its correlation with analogous sequences in Kashmir Himalaya; Jahrb Geol. Bundesamst. 209 (2) 231–246.
Parcha S K 1999 Cambrian biostratigraphy in the Tethyan sequences of the Spiti Valley, Himachal Himalaya, India; Newsl. Stratigr. 37 (3) 177–190.
Parcha S K and Pandey S 2011 Ichnofossils and their significance in the Cambrian successions of the Parahio Valley in the Spiti basin, Tethys Himalaya, India; J. Asian Earth Sci. 42 1097–1116.
Peng S C, Hughes N C, Heim N A, Sell B K, Zhu X J, Myrow P M and Parcha S K 2009 Cambrian trilobites from the Parahio and Zanskar Valleys, Indian Himalaya; Paleontol. Soc. Memoir 71 1–95.
Perri F, Critelli S, Cavalcante F, Mongelli G, Dominici R, Sonnino M and De Rosa R 2012 Provenance signatures for the Miocene volcaniclastic succession of the Tufiti di Tusa Formation, southern Apennines, Italy; Geol. Mag. 149 423–442.
Peterson J A 2009 Geochemical provenance of clastic sedimentary rocks in the western Cordillera: Utah, Colorado, Wyoming, and Oregon.
Potter P E, Maynard J B and Anddepetris P J 2005 Mud and Mudstones: Introduction and Overview; Heidelberg, Springer-Verlag, 297p.
Rahman M J and Sujuki S 2007 Geochemistry of sandstones from the Miocene Surma Group, Bengal basin, Bangladesh: Implications for Provenance, tectonic setting and weathering; Geochem. J. 41 415–428.
Ramachandran A, Madhavaraju J, Ramasamy S, Lee Y I, Rao S, Chawngthu D L and Velmurugan K 2016 Geochemistry of the Proterozoic clastic rocks of Kerur Formation of Kaladgi–Badami basin, Northern Karnataka, South India: Implications for paleoweathering and provenance; Turk. J. Earth Sci 25 126–144.
Ranga Rao, Dhar C L, Rao S V and Shah S K 1982 Contribution to the stratigraphy of Spiti; Him. Geol. 12 98–113.
Reed F R C 1910 The Cambrian fossils of Spiti; Geol. Surv. India, New Series 7 (1) 1–70.
Roser B P and Korsch R J 1986 Determination of tectonic setting of sandstone–mudstone suites using SiO2 content and K2O/Na2O ratio; J. Geol. 94 635–650.
Roser B P and Korsch R J 1988 Provenance signature of sandstone–mudstone suite determined using discriminant function analysis of major element data; Chem. Geol. 67 119–139.
Sari A and Koca D 2012 An approach to provenance, tectonic and redox conditions of Jurassic–Cretaceous Akkuyu Formation, Central Taurids, Turkey; Min. Res. Explor. Bull. 144 51–74.
Srikantia S V 1981 The lithostratigraphy, sedimentation and structure of the Proterozoic–Phanerozoic formations of Spiti basin in the Higher Himalayas of Himachal Pradesh India; In: Contemporary Geoscientific Research in Himalaya (ed.) Sinha A K, Bishen Singh Mahendra Pal Publisher, Dehradun, India 1 31–38.
Srikantia S V and Bhargava O N 1998 Geology of Himachal Pradesh; Geological Society of India, 406p.
Tang Y, Sang L, Yuan Y, Zhang Y and Yang Y 2012 Geochemistry of Late Triassic pelitic rocks in the NE part of Songpan–Ganzi basin, western China: Implications for source weathering, provenance and tectonic setting; Geosci. Front. 3 (5) 647–660.
Taylor S R and McLennan S M 1985 The Continental Crust: Its Composition and Evolution; Oxford, Blackwell, 349p.
Thakur V C 1992 Geology of Western Himalaya; Pergamon Press, Oxford, 363p.
van de Kamp P C and Leake B E 1985 Petrography and geochemistry of feldspathic and mafic sediments of the northeastern Pacific margin; Trans. Roy. Soc. Edin. Earth 76 411–449.
Zaid S M 2012 Provenance, diagenesis, tectonic setting and geochemistry of Rudies sandstone (Lower Miocene), Warda Field, Gulf of Suez, Egypt; J. Afr. Earth Sci. 66–67 56–71.
Acknowledgements
The authors are thankful to the Director, Wadia Institute of Himalayan Geology, Dehradun, for providing facilities and giving permission to publish this work. They are thankful to the anonymous reviewers for their insightful reviews. The authors also thank Dr Hakim Rai and Dr D R Rao for giving critical comments and corrections to shape the manuscript in the present form.
Author information
Authors and Affiliations
Corresponding author
Additional information
Corresponding editor: N V Chalapathi Rao
Rights and permissions
About this article
Cite this article
Pandey, S., Parcha, S.K. Provenance, tectonic setting and source-area weathering of the lower Cambrian sediments of the Parahio valley in the Spiti basin, India. J Earth Syst Sci 126, 27 (2017). https://doi.org/10.1007/s12040-017-0803-5
Received:
Revised:
Accepted:
Published:
DOI: https://doi.org/10.1007/s12040-017-0803-5