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Diphenyl phosphate creatine immobilized on magnetite nanoparticles: an efficient and recyclable catalyst for Aza-Michael reaction

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Abstract

In this paper, diphenyl phosphate creatine was successfully immobilized on Fe3O4 nanoparticles and used as the highly efficient catalyst for the aza-Michael reaction of 5-substituted tetrazole and α,β-unsaturated carbonyl. The prepared nanocatalyst was fully analyzed by various techniques such as Fourier-transform Infrared Spectroscopy (FT-IR), Field Emission Scanning electron microscope (FE-SEM), Vibrating Sample Magnetometer (VSM), Thermal Gravimetric Analysis (TGA) and X-ray Diffraction (XRD). This procedure possesses numerous advantages such as simple work-up, high yield and short reaction times.

Graphic abstract

This paper discusses a method for the synthesis of substituted tetrazoles via aza-Michael reaction using Fe3O4@Diphenyl phosphate creatine nanoparticles as a new catalyst.

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Acknowledgements

The authors gratefully acknowledge the Faculty of Chemistry of Tarbiat Modares University for supporting this work.

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Authors and Affiliations

  1. Department of Chemical, Faculty of Sciences, Tarbiat Modares University, Tehran, 14117-13116, Iran

    Farzane Pazoki, Fahimeh Mohammadpanah, Arefe Salamat Manesh, Jamshid Azarnia Mehraban & Akbar Heydari

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  1. Farzane Pazoki
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  2. Fahimeh Mohammadpanah
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  3. Arefe Salamat Manesh
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  4. Jamshid Azarnia Mehraban
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  5. Akbar Heydari
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Corresponding author

Correspondence to Akbar Heydari.

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This article is dedicated to the memory of Mohammad-Ali Rajai.

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Pazoki, F., Mohammadpanah, F., Salamat Manesh, A. et al. Diphenyl phosphate creatine immobilized on magnetite nanoparticles: an efficient and recyclable catalyst for Aza-Michael reaction. J Chem Sci 132, 30 (2020). https://doi.org/10.1007/s12039-019-1721-7

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  • DOI: https://doi.org/10.1007/s12039-019-1721-7

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