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Self-assembly, structures and properties of three new Ni(II) coordination polymers derived from two different bis-pyridyl-bis-amide ligands and two aromatic polycarboxylates

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Abstract

Three new Ni(II) coordination polymers exhibiting different 1D and 2D framework structures have been hydrothermally synthesized: [Ni(L 1)(1,3-BDC)(H 2O) 3] ⋅H 2O (1), [Ni(L 1)(1,3,5-HBTC)(H 2O) 3] (2), [Ni 3(L 2)3(1,3,5-BTC) 2(H 2O) 8] ⋅12H 2O (3) [L 1= N,N ′-bis(pyridin-3-yl)cyclohexane-1,4-dicarboxamide, L 2= N,N ′-bis(3-pyridyl)octandiamide, 1,3-H 2BDC = 1,3-benzenedicarboxylic acid, 1,3,5-H 3BTC = 1,3,5-benzenetricarboxylic acid]. X-ray single crystal diffraction analyses revealed that polymer 1 is a 2D interlaced layer based on the 1D [Ni(L 1)(1,3-BDC)(H 2O) 3] meso-helical chains. Polymer 2 is a 1D wave-shaped chain derived from the 1D [Ni(L 1)] n chain and monodentate coordinated 1,3,5-HBTC anions. Polymer 3 possesses an interesting 2D layer containing the trinuclear [Ni 3(1,3,5-BTC) 2] substructural unit and 1D zigzag [Ni(L 2)] n chain, representing a 3,4-connected {6 ⋅8 2} 2 {62⋅82⋅10⋅12} topology. Finally, the adjacent 1D chains or the 2D layers are connected through hydrogen bonding interactions to construct 3D supramolecular networks. Further, the thermal stability, solid state fluorescent property and photocatalytic activity of 1–3 have been investigated.

Three new Ni(II) coordination polymers have been hydrothermally synthesized by self-assembly of two bis-pyridyl-bis-amide ligands (L1, L2) and two aromatic polycarboxylates (1,3-H2BDC, 1,3,5-H3BTC). The thermal stability, fluorescent properties and the photocatalytic activities of polymers 1–3 have been studied.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 21471021, 21501013, 21401010), New Century Excellent Talents in University (NCET-09-0853) and Program of Innovative Research Team in University of Liaoning Province (LT2012020).

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  1. Department of Chemistry, Bohai University, Jinzhou, 121000, People’s Republic of China

    HONGYAN LIN, JUNJUN SUN, GUOCHENG LIU∗, XIANG WANG & PANWEN CHEN

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  2. JUNJUN SUN
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  3. GUOCHENG LIU∗
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Correspondence to HONGYAN LIN or GUOCHENG LIU∗.

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Supplementary Information (SI)

X-ray crystallographic data for polymers 1–3 reported in this paper have been deposited in the Cambridge Crystallographic Data Center with CCDC reference numbers CCDC 1041874 for 1, 1435170 for 2 and 1435171 for 3. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif. The tables of selected bond lengths and angles, the related hydrogen bonding geometries of polymers 1–3 (Tables S1–S4), and additional figures (structural figures, IR spectra, PXRD and TG curves, Figures S1–S12) are available in Supplementary Information; see, www.ias.ac.in/chemsci.

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LIN, H., SUN, J., LIU∗, G. et al. Self-assembly, structures and properties of three new Ni(II) coordination polymers derived from two different bis-pyridyl-bis-amide ligands and two aromatic polycarboxylates. J Chem Sci 129, 9–20 (2017). https://doi.org/10.1007/s12039-016-1213-y

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