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Silver(I) based dinuclear metallacycles with free thiophenyl/thiomethyl units

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Abstract

Three dinuclear, ionic and homoleptic metallacycles decorated with free thiophenyl or thiomethyl units were synthesized using AgOS(O 2)CF 3 and benzimidazole derived ditopic N-donor ligands at ambient condition. The complexes were characterized by analytical and spectroscopic (IR and 1H NMR) techniques and two of the complexes were structurally characterised through single crystal X-ray diffraction.

A new type of silver metallacycles with covalently attached free thiophenyl/thiomethyl units was synthesized using AgOS(O)2CF3 and ditopic ligands and characterized by using crystallographic and spectroscopic techniques.

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Figure 1
Scheme 1
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Acknowledgements

We thank USIC & Department of Chemistry, University of Delhi, and School of Chemistry, University of Hyderabad for financial support and instrumentation facilities. SY thanks UGC for Junior Research fellowship.

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Authors and Affiliations

  1. Department of Chemistry, University of Delhi, Delhi, 110 007, India

    SARITA YADAV, DEEPAK GUPTA & MALAICHAMY SATHIYENDIRAN

  2. School of Chemistry, University of Hyderabad, Hyderabad, 500 046, India

    MALAICHAMY SATHIYENDIRAN

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  1. SARITA YADAV
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  2. DEEPAK GUPTA
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Correspondence to MALAICHAMY SATHIYENDIRAN.

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Supplementary Information

Copies of NMR, mass spectra and crystallographic data table are available at www.ias.ac.in/chemsci. CCDC 1400518 and 1400519, contain the supplementary crystallographic data for 1 and 3. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html, or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: (+ 44) 1223-336 033; or e-mail: deposit@ccdc.cam.ac.uk.

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YADAV, S., GUPTA, D. & SATHIYENDIRAN, M. Silver(I) based dinuclear metallacycles with free thiophenyl/thiomethyl units. J Chem Sci 128, 177–184 (2016). https://doi.org/10.1007/s12039-015-1027-3

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  • DOI: https://doi.org/10.1007/s12039-015-1027-3

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