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A novel fluorescent turn-on probe for bisulfite based on NBD chromophore

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Abstract

A novel fluorescent turn-on probe (compound 1) for bisulfite based on 7-nitrobenz-2-oxa-1,3-diazole (NBD) chromophore has been developed. Its sensing behavior toward various anions was investigated by absorption and fluorescence techniques. This probe shows a selective, turn-on fluorescent response and ratiometric colorimetric response toward bisulfite in aqueous acetonitrile solutions. The possible recognition mechanism of probe 1toward bisulfite was illustrated by MS spectra analysis and DFT calculations Probe 1 was used to determine bisulfite in real-life samples with good recoveries.

A novel fluorescent turn-on probe (compound 1) for bisulfite based on 7-nitrobenz-2-oxa-1,3-diazole (NBD) chromophore has been developed. Probe 1 shows a selective, turn-on fluorescent response and ratiometric colorimetric response toward bisulfite in aqueous acetonitrile solutions.

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Acknowledgement

This project was supported by the National Natural Science Foundation of China (NSFC, No.21102037).

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    Authors and Affiliations

    1. College of Sciences, Henan Agricultural University, Zhengzhou, 450002, P. R. China

      PUHUI XIE, GUANGQIN GAO, WENJIE ZHANG, GUOYU YANG & QIU JIN

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    1. PUHUI XIE
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    2. GUANGQIN GAO
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    Correspondence to PUHUI XIE.

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    Supplementary Information

    All additional information about 1H NMR (figure S1), 13C NMR (figure S2), MS spectrum (figure S3) of compound 1, Benesi-Hildebrand plot (figure S4), MS spectrum of 1 HSO\(_{\mathrm {3}}^{\mathrm {-}}\) (figure S5) and the standard curve in figure S6 are given in the supplementary information. Supplementary information is available at www.ias.ac.in/chemsci.

    Puhui Xie and Guangqin Gao are contributed equally to this work.

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    XIE, P., GAO, G., ZHANG, W. et al. A novel fluorescent turn-on probe for bisulfite based on NBD chromophore. J Chem Sci 127, 1267–1273 (2015). https://doi.org/10.1007/s12039-015-0881-3

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