Abstract
Polycyclics containing biaryls have been prepared via application of cross-enyne metathesis and the Diels −Alder reaction. Here, ethylene and 1,5-hexadiene were used as a cross-coupling partners to generate key diene intermediates.
Polycyclics containing biaryls have been prepared via application of cross-enyne metathesis and the Diels-Alder reaction. Here, ethylene and 1,5- hexadiene were used as a cross-coupling partners to generate key diene intermediates.
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† Major portion of the work was taken from Seema V, Ph.D. thesis, IIT-Bombay 2011
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Acknowledgements
We would like to acknowledge the DST for the financial support. We also thank, SAIF-Mumbai for recording the spectral data. S.V. thanks IIT-Bombay and UGC-New Delhi for the award of a research fellowship. We thank Dr. D. Deodhar for his help in preparing the manuscript. S. K. thanks DST for the award of J C Bose Fellowship.
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1H and 13C NMR (Figures S1 to S10) are given in Supplementary Information available free of charge in www.ias.ac.in/chemsci.
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KOTHA, S., SEEMA, V., BANERJEE, S. et al. Diversity oriented approach to polycyclics via cross-enyne metathesis and Diels–Alder reaction as key steps. J Chem Sci 127, 155–162 (2015). https://doi.org/10.1007/s12039-015-0765-6
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DOI: https://doi.org/10.1007/s12039-015-0765-6