Abstract
Utilizing the self-organization of materials to make systematic and ordered wrinkled patterns can be very useful for optical, electronic, adhesives and many other applications. In this work, we have demonstrated the fabrication of a self-organized, linearly ordered, wrinkled pattern developed in the polystyrene (PS) thin film by controlled buckling in the film. Buckling was induced in the thin film by bending an elastic polydimethylsiloxane (PDMS) substrate along the two sides producing variable stress along both sides of the bending axis. Controlling of the self-organized patterns in the PS thin film was obtained by varying stress in the elastic PDMS substrate and thin-film thickness of PS. Theoretical analysis and experimental results were compared, and the developed structure was demonstrated to be used as a smart optical filter giving different intensities of diffused light for different positions of the substrate.
Similar content being viewed by others
References
Dai Z, Liu L and Zhang Z 2019 Adv. Mater. 31 1
Wang M C, Leem J, Kang P, Choi J, Knapp P, Yong K et al 2017 2D Materials 4 044001
Pandurangi S S and Kulkarni S S 2015 Int. J. Solids Struct. 62 124
Chen Y F, Hong J W, Chang J H, Junisu B A and Sun Y S 2021 Polymers 13 2480
Singh N, Verma A, Sachan P, Sharma A and Kulkarni M M 2021 ACS Appl. Polym. Mater. 3 6198
Wu K, Sun Y, Yuan H, Zhang J, Liu G and Sun J 2020 Nano Lett. 20 4129
Moon M-W and Vaziri A S 2011 Procedia Eng. 10 224
Chan E P, Smith E J, Hayward R C and Crosby A J 2008 Adv. Mater. 20 711
Baetens R, Jelle B P and Gustavsen A 2010 Sol. Energy Mater. Sol. Cells 94 87
Cannavale A, Ayr U, Fiorito F and Martellotta F 2020 Energies 13 1
Lampert C M 2004 Mater. Today 7 28
Lee G, Bae G Y, Son J H, Lee S, Kim S W, Kim D et al 2020 Adv. Sci. 7 1
Wang Y, Runnerstrom E L and Milliron D J 2016 Annu. Rev. Chem. Biomol. Eng. 7 283
Stoney G G 1909 Proc. R. Soc. Lond. Ser. A 82 172
Carmen M G H, Dallits H S O, Mauricio A S V and Juan R H 2016 Polymer 101 24
Kim P, Hu Y, Alvarenga J, Kolle M, Suo Z and Aizenberg J 2013 Adv. Opt. Mater. 1 381
Lee S G, Lee D Y, Lim H S, Lee D H, Lee S and Cho K 2010 Adv. Mater. 22 5013
Mei Y, Kiravittaya S, Harazim S and Schmidt O G 2010 Mater. Sci. Eng. R: Reports 70 209
Li Z, Liu Y, Marin M and Yin Y 2020 Nano Res. 13 1882
Wang J, Zheng Y, Li L, Liu E, Zong C, Zhao J et al 2019 ACS Appl. Mater. Interfaces 11 25595
Jiang H, Khang D Y, Song J, Sun Y, Huang Y and Rogers J A 2007 Proc. Natl. Acad. Sci. USA 104 15607
Mishra S, Kulkarni M M and Verma A 2021 Micron 151 103148
Sun J, Xia S, Moon M, Oh K H and Kim K 2018 Proc. R. Soc. A 468 932
Bowden N, Brittain S, Evans A G, Hutchinson J W and Whiteside G M 1998 Nature 393 146
Groenewold J 2001 Physica A: Stat. Mech. Appl. 298 32
Tsapis N, Dufresne E R, Sinha S S, Riera C S, Hutchinson J W, Mahadevan L et al 2005 Phys. Rev. Lett. 94 018302
Pradhan S C 2009 Phys. Lett. A 373 4182
Chen H-P 1991 AIAA J. 29 813
Cheng H and Song J 2014 J. Appl. Mech. Trans. 81 1
Song J, Jiang H, Liu Z J, Khang D Y, Huang Y, Rogers J A et al 2008 Int. J. Solids Struct. 45 3107
Wang Z, Volinsky A A and Gallant N D 2014 J. Appl. Polym. Sci. 131 41050
Swalowe G M and Lee S F 2006 J. Mater. Sci. 41 6280
Yu L, Shi Z Z, Fang C, Zhang Y Y, Liu Y S and Li C M 2015 Biosens. Bioelectron. 69 307
Contreras-Naranjo J C, Wei Q and Ozcan A 2016 IEEE J. Se. Top. Quantum Electron. 22 1
Ohzono T, Suzuki K, Yamaguchi T and Fukuda N 2013 Adv. Opt. Mater. 1 374
Lin I T, Choi Y S, Wojcik C, Wang T, Kar-Narayan S and Smoukov S K 2020 Mater. Today 41 51
Acknowledgments
We gratefully acknowledge the Centre of Nanosciences, IIT Kanpur, for the access to some of the experimental facilities. This work is supported by the SERB early career grant (ECR/2015/000434).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Mishra, S., Verma, A. Variable density wrinkling in polymer thin film by gradient stress induced in the elastomeric substrate. Bull Mater Sci 47, 94 (2024). https://doi.org/10.1007/s12034-024-03156-w
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s12034-024-03156-w