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Adsorption of strontium (II) metal ions using phosphonate-functionalized polymer

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Abstract

Diethyl[3-(methoxydimethylsilyl)propyl]phosphonate (DMPP) polymer was synthesized for the strontium (II) metal ion recovery using diethylallylphosphonate as staring material. Diethylallylphosphonate was reacted with poly(methylhydro)siloxane (MW 1900–2000 g mol−1) in the presence of Speier’s catalyst. The synthesized monomer was characterized by IR,1H NMR,13C NMR and FT-IR spectroscopy techniques, and the synthesized polymers were characterized by IR and NMR spectroscopy, differential scanning calorimetry, thermogravimetric analysis and solubility. The synthesized polymer was used for sequestering strontium metal from the aqueous solution. The metal binding was examined by the energy dispersive spectroscopy and scanning electron microscopy for the adsorbed Sr(II). Batch adsorption studies were performed by varying three parameters, namely initial pH, adsorbent dose and the contact time. The reaction kinetics was determined by the Langmuir, Freundlich, and pseudo-first- and second-order models. Results of this study indicate that the synthesized polymer DMPP has been effective in removing Sr(II) from the aqueous solution.

Metal chelation using phosphonate based polymer.

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Acknowledgements

We express our gratitude towards CSIR for the award of research fellowship (Fellowship Award No. 31/11(741)/ 2012-EMR-I). We would like to thank the Department of Science and Technology, New Delhi, India, for the financial support of this research under the Program No. SR/S3/ CE/0049/2010.

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Authors and Affiliations

  1. Polymer Science and Engineering Division, CSIR-National Chemical Laboratory, Pune, 411008, India

    S M BHOSLE, S PONRATHNAM & N N CHAVAN

  2. Chemical Engineering and Process Development Division, CSIR-National Chemical Laboratory, Pune, 411008, India

    S S TAMBE

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  1. S M BHOSLE
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  2. S PONRATHNAM
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  3. S S TAMBE
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  4. N N CHAVAN
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Correspondence to N N CHAVAN.

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BHOSLE, S.M., PONRATHNAM, S., TAMBE, S.S. et al. Adsorption of strontium (II) metal ions using phosphonate-functionalized polymer. Bull Mater Sci 39, 1541–1556 (2016). https://doi.org/10.1007/s12034-016-1295-7

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