Abstract
Nanopowders of La 1−x Bi x Co0.6Fe0.4O3 (x = 0, 0.1, 0.2) and La 1−2x Bi x Sr x Co0.6Fe0.4O3 (x = 0.1) multinary perovskites were synthesized by citrate sol–gel autocombustion method. Crystalline phase and the lattice parameters were obtained from X-ray diffraction pattern. The XRD result shows that all compounds have rhombhohedral crystal structure with \(\bar {\mathbf {R}\mathbf {3}}\)c space group and Bi (x = 0.2) have the presence of secondary peaks. Crystallite size, dislocation density, specific area and strain were calculated from XRD. The elemental composition and micrographs of grain were obtained from EDAX (energy dispersive X-ray analysis) and SEM (scanning electron microscopy), with an average grain size below 400 nm. Surface morphological studies using XPS (X-ray photoelectron spectroscopy) were used to find out the chemical states and surface proportion of oxygen present in samples. Finally, using the vibrating sample magnetometer the room temperature magnetic behaviour of compounds was studied and it was observed that the ferromagnetic behaviour of LaCo0.6Fe0.4O3 was reduced by Bi and Sr doping.
Similar content being viewed by others
References
Joonghoe Dho and Hur N H 2006 Solid State Commun. 138 152
Yu J, Kamazawa K and Despina Louca 2010, Phys. Rev. B 82 224101
Yoshii K, Abe H and Nakamura A 2001 Mater. Res. Bull. 36 1447
Knizek K, Jirak Z, Hejtmanek J and Novak P 2006 J. Phys. Condens. Matter 18 3285
Senaris Rodriguez M A and Goodenough J B 1995 J. Solid State Chem. 118 323
Anderson P W and Hasegawa H 1955 Phys. Rev. 100 675
Klencsar Z, Nemeth Z, Kuzmann E, Homonnay Z, Vertes A, Hakl J, Vad K, Meszaros S, Simopoulos A, Devlin E, Kallias G, Greneche J M, Cziraki A and De S K 2008 J. Magn. Magn. Mater. 320 651
Troyanchuk I O, Karpinskii D V, Dobryanskii V M, Fedotova Y. A and Szymczak H 2005 J. Exp. Theor. Phys. 100 1121
Karpinskii D V, Troyanchuk I O, Barner K, Szymczak H and Tovar M 2005 J. Phys.: Condens. Matter 17 7219
Vulchev V, Vassilev L, Harizanova S, Khristov M, Zhecheva E and Stoyanova R 2012 J. Phys. Chem. C 116 13507
Bin F, Song C, Lv G, Song J, Gong C and Huang Q 2011 Ind. Eng. Chem. Res. 50 6660
Xiutao Ge, Yafei Liu and Xingqin Liu 2001, Sens. Actuators B 79 171
Royer S, Van Neste A, Davidson R, McIntyre S and Kaliaguine S 2004 Ind. Eng. Chem. Res. 43 5670
Megha U, Shijina K and Varghese G 2014 Process. Appl. Ceramics 8 87
Ravindran P, Vidya R, Kjekshus A, Fjellvag H and Eriksson O 2006 Phys. Rev. B 74 224412
Melo D S, Marinho E P, Soledade L B, Melo D A, Lima S G, Longo E, Garcia Santos I M and Souza A G 2008 J. Mater. Sci. 43 551
Liu X, Gao F and Tian C 2008 Mater. Res. Bull. 43 693
Kumar A, Verma A S and Bhardwaj S R 2008 Open Appl. Phys. J. 1 11
Rita John and Rajaram Rajakumari 2012, Nano-Micro Lett. 4 65
R W M Kwok available from: http://www.phys.cuhk.edu.hk/∼surface/ XPSPEAK
Shirley D A 1972 Phys. Rev. B 5 4709
Vegh J 2006 J. Electron Spectrosc. Rel. Phenom. 151 159
Galenda A, Natile M M, Krishnan V, Bertagnolli H and Glisenti A 2007 Chem. Mater. 19 2796
Tie Li, Jianfeng Shen, Na Li and Mingxin Ye 2013, J. Alloys Comp. 548 89
Worayingyong A, Kangvansura P, Ausadasuk S and Praserthdam P 2008 Colloids Surf. A: Physicochem., Eng. Asp. 315 217
Natile M M, Fabio Poletto, Alessandro Galenda, Antonella Glisenti, Tiziano Montini, Loredana De Rogatis and Paolo Fornasiero 2008, Chem. Mater. 20 2314
Zhao Y D, Park J, Jung R-J, Noh H-J and Oh S-J 2004, J. Magn. Magn. Mater. 280 404
Acknowledgement
Megha U and Shijina K acknowledge the University Grant Commission, Government of India, for the BSR–RFSMS Fellowship.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
MEGHA, U., VARGHESE, G. & SHIJINA, K. Effect of Bi and Sr doping on morphological and magnetic properties of LaCo0.6Fe0.4O3 nanosized perovskites. Bull Mater Sci 39, 125–131 (2016). https://doi.org/10.1007/s12034-015-1149-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12034-015-1149-8