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Environment-friendly UV-curable alkyd-based non-isocyanate urethanes

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Abstract

Two non-isocyanate polyurethanes (NIPUs) were used as reactive diluents for an alkyd to obtain eco-friendly new UV-curable alkyd-polyurethane coatings. A linseed-based alkyd resin was prepared and formulated with the reactive diluents (NIPUs) and free radical photoinitiator, and then UV-cured. NMRs were used to characterize the alkyd and NIPUs and glass transition temperature (Tg) of cured alkyd-polyurethanes were evaluated by using DSC. Further, spectroscopy and thermal stability of the coatings were evaluated by using ATR-IR spectroscopy and thermogravimetric analysis (TGA), respectively. Moreover, coating properties such as pencil hardness, cross-cut adhesion, pull-off adhesion, impact resistance, and reverse impact resistance were also evaluated. It was found that crosslink density, pencil hardness, adhesion, and Tg were dependent and proportional to the amount of the NIPUs (reactive diluents) showing significant improvement in mechanical and thermal properties compared to the linseed-based alkyd resin.

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Authors and Affiliations

  1. School of Polymer Science and Polymer Engineering, University of Akron, Akron, OH, 44325, USA

    Ilknur Babahan-Bircan, Jomin Thomas & Mark D. Soucek

  2. Department of Chemistry, Faculty of Arts and Sciences, Aydin Adnan Menderes University, Aydın, 09010, Turkey

    Ilknur Babahan-Bircan

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  1. Ilknur Babahan-Bircan
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Correspondence to Ilknur Babahan-Bircan.

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Babahan-Bircan, I., Thomas, J. & Soucek, M.D. Environment-friendly UV-curable alkyd-based non-isocyanate urethanes. J Coat Technol Res 19, 1507–1522 (2022). https://doi.org/10.1007/s11998-022-00623-z

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