Skip to main content
Log in

Functionalization of cotton fabric with nanosized TiO2 coating for self-cleaning and antibacterial property enhancement

  • Published:
Journal of Coatings Technology and Research Aims and scope Submit manuscript

Abstract

In this study, titanium dioxide (TiO2) was used as coating compound to add self-cleaning and antibacterial functionality properties to the cotton fabric. TiO2-consisting coating compounds were prepared at four different processing temperatures (20, 40, 60, and 80°C) in order to examine the influence of process temperature on average particle size. Among the prepared solutions, the one prepared at 80°C process temperature was selected for the dip coating application of the 100% cotton fabric, which formed a transparent nanosized TiO2 film on the fibrous structure of fabric. Dip coating trials were done at five coating temperatures of 20, 40, 60, 80, and 100°C. TiO2-coated and uncoated fabric samples were then tested to evaluate their self-cleaning and antibacterial activities. A self-cleaning activity test was conducted using uncoated and TiO2-coated fabric samples which were stained with hot tea solution via dipping method. Stained fabric samples were illuminated under a solar simulator for the color changes to measure photocatalytic degradation of stain colors. Antibacterial performance of TiO2-coated and uncoated fabric samples was determined against pure cultures of Escherichia coli ATCC 25922 and Staphylococcus aureus ATCC 29213.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Benedix, R, Quaas, FJD, Orgass, M, “Application of Titanium Dioxide Photocatalysis to Create Self-Cleaning Building Materials.” Lacer, 5 157–167 (2000)

    Google Scholar 

  2. Beringer, J, Nanotechnology in Textile Finishing, State of the Art and Future Prospects. MRS Fall Meeting, Boston, MA (2005)

    Google Scholar 

  3. Mills, A, Hunte, SL, “An Overview of Semiconductor Photocatalysis.” J. Photoch. Photobio. A, 108 1–35 (1997)

    Article  Google Scholar 

  4. Arslan, I, Balcioglu, I, Bahnemann, DW, “Advanced Chemical Oxidation of Reactive Dyes in Simulated Dyehouse Effluents by Ferrioxalate-Fenton/UV-A and TiO2/UV-A Processes.” Dyes Pigm., 47 207–218 (2000)

    Article  Google Scholar 

  5. Selcuk, H, “Disinfection and Disinfection By-products Formation in a Photoelectrocatalytic System.” Water Res., 44 3966–3972 (2010)

    Article  Google Scholar 

  6. Selcuk, H, Sene, JJ, Bekbolet, M, et al., “Photocatalytic and Photoelectrocatalytic Performance of 1% Pt Doped TiO2 for the Detoxification of Water.” J. Appl. Electrochem., 34 653–658 (2004)

    Article  Google Scholar 

  7. Folli, A, Campbell, SB, Anderson, JA, et al., “Role of TiO2 Surface Hydration on NO Oxidation Photo-activity.” J. Photoch. Photobio. A, 220 85–93 (2011)

    Article  Google Scholar 

  8. Zhou, J, Cheng, Y, Yu, J, “Preparation and Characterization of Visible-Light-Driven Plasmonic Photocatalyst Ag/AgCl2/TiO2 Nanocomposite Thin Films.” J. Photoch. Photobio. A., 223 82–87 (2011)

    Article  Google Scholar 

  9. Hyett, G, Green, MA, Parkin, IP, “Ultra-Violet Light Activated Photocatalysis in Thin Films of the Titanium Oxynitride, Ti3−δO4N.” J. Photoch. Photobio. A, 203 199–203 (2009)

    Article  Google Scholar 

  10. Slimen, H, Houas, A, Nogier, JP, “Elaboration of Stable Anatase TiO2 Through Activated Carbon Addition with High Photocatalytic Activity Under Visible Light.” J. Photoch. Photobio. A, 221 13–21 (2011)

    Article  Google Scholar 

  11. In, S-I, Vesborg, PCK, Abrams, BL, Hou, Y, Chorkendorff, I, “A Comparative Study of Two Techniques for Determining Photocatalytic Activity of Nitrogen Doped TiO2 Nanotubes Under Visible Light Irradiation: Photocatalytic Reduction of Dye and Photocatalytic Oxidation of Organic Molecules.” J. Photoch. Photobio. A, 222 258–262 (2011)

    Article  Google Scholar 

  12. Asapu, R, Palla, VM, Wang, B, et al., “Phosphorus-Doped Titania Nanotubes with Enhanced Photocatalytic Activity.” J. Photoch. Photobio. A, 225 81–87 (2011)

    Article  Google Scholar 

  13. Wen, B, Liu, C, Liu, Y, “Optimization of the Preparation Methods: Synthesis of Mesostructured TiO2 with High Photocatalytic Activities.” J. Photoch. Photobio. A, 173 7–12 (2005)

    Article  Google Scholar 

  14. Hennes-Morgan, EC, de Oude, NT, “Detergents.” In: Calow, P (ed.) Handbook of Ecotoxicology, pp. 130–154. Blackwell Scientific, Oxford (1994)

    Google Scholar 

  15. Bozzi, A, Yuranova, T, Guasaquillo, I, et al., “Self-cleaning of Modified Cotton Textiles by TiO2 at Low Temperatures Under Daylight Irradiation.” J. Photoch. Photobio. A, 174 156–164 (2005)

    Article  Google Scholar 

  16. Veronovski, N, Sfiligoj-Smole, M, Viota, JL, “Characterization of TiO2/TiO2–SiO2 Coated Cellulose Textiles.” Text. Res. J., 80 55–62 (2010)

    Article  Google Scholar 

  17. Uddin, MJ, Cesano, F, Scarano, D, Bonino, F, Agostini, G, Spoto, G, Bordiga, S, Zecchina, A, “Cotton Textile Fibres Coated by Au/TiO2 Films: Synthesis, Characterization and Self Cleaning Properties.” J. Photochem. Photobio. A, 199 64–72 (2008)

    Article  Google Scholar 

  18. Zhang, H, Zhu, H, Sun, R, “Fabrication of Photocatalytic TiO2 Nanoparticle Film on PET Fabric by Hydrothermal Method.” Text. Res. J., 82 747–754 (2012)

    Article  Google Scholar 

  19. Chenh-Chi, C, Chyung-Chyung, W, Jen Taut, Y, “Improvement of Odor Elimination and Anti-bacterial Activity of Polyester Fabrics Finished with Composite Emulsions of Nanometer Titanium Dioxide-Silver Particles-Water-Borne Polyurethane.” Text. Res. J., 80 291–300 (2010)

    Article  Google Scholar 

  20. Kiwi, J, Pulgarin, C, “Innovative self-cleaning and Bactericide Textiles.” Catal. Today, 151 1–2 (2010)

    Article  Google Scholar 

  21. Palamutcu, S, Acar, G, Con, AH, Gultekin, T, Aktan, B, Selcuk, H, “Innovative Self-cleaning and Antibacterial Cotton Textile: No Water and no Detergent for Cleaning.” Des. Wat. Treat., 26 178–184 (2011)

    Article  Google Scholar 

  22. Oekerman, T, Zhang, D, Yoshida, T, et al., “Electron Transport and Back Reaction in Nanocrystalline TiO2 Films Prepared by Hydrothermal Crystallization.” J. Phys. Chem. B., 108 2227–2235 (2004)

    Article  Google Scholar 

  23. Pichot, F, Pitts, JR, Gregg, BA, “Low Temperature Sintering of TiO2 Colloids: Application to Flexible Dye-Sensitized Solar Cells.” Langmuir, 16 5626–5630 (2000)

    Article  Google Scholar 

  24. Langlet, M, Kim, A, Guillard, M, et al., “Transparent Photocatalytic Films Deposited on Polymer Substrates from Sol-Gel Processed Titaina Sols.” Thin Solid Films, 429 13–21 (2003)

    Article  Google Scholar 

  25. Shimizu, K, Imai, H, Hirashima, H, et al., “Low-Temperature Synthesis of Anatase Thin Films on Glass and Organic Substrates by Direct Deposition from Aqueous Solutions.” Thin Solid Films, 351 220–224 (1999)

    Article  Google Scholar 

  26. Atyaoui, A, Bousselmi, L, Cachet, H, et al., “Influence of Geometric and Electronic Characteristics of TiO2 Electrodes with Nanotubular Array on Their Photocatalytic Efficiencies.” J. Photoch. Photobio. A, 224 71–79 (2011)

    Article  Google Scholar 

  27. Sansiviero, MTC, dos Santos, DS, Job, AE, et al., “Layer by Layer TiO2 Thin Films and Photodegradation of Congo Red.” J. Photoch. Photobio. A, 220 20–24 (2011)

    Article  Google Scholar 

  28. Li, G, Lv, L, Fan, H, Ma, J, Li, Y, Wan, Y, Zhao, XS, “Effect of the Agglomeration of TiO2 Nanoparticles on Their Photocatalytic Performance in the Aqueous Phase.” J. Colloid. Interf. Sci., 348 342–347 (2010)

    Article  Google Scholar 

  29. Yu, J, Zhao, X, Zhao, Q, “Effect of Surface Structure on Photocatalytic Activity of TiO2 Thin Films Prepared by Sol-Gel Method.” Thin Solid Films, 379 7–14 (2000)

    Article  Google Scholar 

  30. AATCC Test Method 100-1999, Antibacterial Finishes on Textile Materials: Assessment of AATCC Technical Manual, 2004

  31. Yu, J, Yu, H, Cheng, B, Zhou, M, Zhao, X, “Enhanced Photocatalytic Activity of TiO2 Powder (P25) by Hydrothermal Treatment.” J. Mol. Catal. A-Chem., 253 112–118 (2006)

    Article  Google Scholar 

  32. Verran, J, Sandoval, G, Allen, NS, Edge, M, Stratton, J, “Variables Affecting the Antibacterial Properties of Nano and Pigmentary Titania Particles in Suspension.” Dyes Pigm., 73 298–304 (2007)

    Article  Google Scholar 

Download references

Acknowledgments

The authors would like to thank to the Scientific and Technological Research Council of Turkey (TÜBİTAK) for the research grant 108M211.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Sema Palamutcu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Doganli, G., Yuzer, B., Aydin, I. et al. Functionalization of cotton fabric with nanosized TiO2 coating for self-cleaning and antibacterial property enhancement. J Coat Technol Res 13, 257–265 (2016). https://doi.org/10.1007/s11998-015-9743-7

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11998-015-9743-7

Keywords

Navigation