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Characterization and Separation Behavior of Multi-layers in Aluminum-Rich Waste Pharmaceutical Blisters

  • Recycling End of Life Products Containing Aluminium
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Abstract

Al-rich waste pharmaceutical blisters (WPBs) have a multi-layer structure that contains aluminum and polymer-based fractions. Although the aluminum mass in WPBs is less than typical aluminum packaging products such as beverage cans, establishing a feasible recycling procedure is possible by separating the fractions to recover both metal and plastic. Hydrometallurgical methods are mostly preferred for the separation of aluminum and plastic in multi-layered structures. This work reports the characterization of Al-rich WPBs and the separation behavior of aluminum and plastic layers. The effects of hydrochloric acid, acetic acid, formic acid, sulfuric acid, ethanol, acetone, and organic solvent (benzene–ethanol–water) on the separation behavior of layers were studied at different temperatures. Furthermore, the recycling yield of the aluminum fraction was experimentally assessed.

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References

  1. J. Gerber, (International aluminium institute, 2009), https://international-aluminium.org/. Accessed 12 Sept 2022.

  2. R. Pilchick, Chem. Eng. News Arch. 24(11), 68–78 (2000).

    Google Scholar 

  3. M. M. S. M. Sabee, N. T. T. Uyen, N. Ahmad, and Z. A. A. Hamid, Encyclopedia of materials: plastics and polymers. (Elsevier, 2022), pp. 316–329. https://doi.org/10.1016/b978-0-12-820352-1.00088-2

  4. J. Nieminen, I. Anugwom, M. Kallioinen, and M. Mänttäri, Waste Manag. 107, 20 (2020).

    Article  Google Scholar 

  5. D. Allen, Pharm. Med. Packag. News 4, 24 (1999).

    Google Scholar 

  6. İY. Çapkın, and M. Gökelma, Cleaner Waste Syst. 4, 100082 https://doi.org/10.1016/j.clwas.2023.100082 (2023).

    Article  Google Scholar 

  7. C.H. Park, H.S. Jeon, and J.K. Park, J. Hazard. Mater. 144, 470 (2007).

    Article  Google Scholar 

  8. M. Lungu, Miner. Eng. 17, 69 (2004).

    Article  Google Scholar 

  9. M.F. Ali, and M.N. Sıddıquı, Anal. Appl. Pyroly. 74, 282 (2005).

    Article  Google Scholar 

  10. K. Pikoń, W. Ścierski, K. Klejnowska, Ł Myćka, A. Janoszka, and A. Sinek, Energies (Basel) 14, 1782 https://doi.org/10.3390/en14061782 (2021).

    Article  Google Scholar 

  11. A.U. Zaman, and S. Lehmann, J. Clean. Prod. 50, 123 (2013).

    Article  Google Scholar 

  12. K. Klejnowska, K. Pikoń, W. Ścierski, K. Skutil, and M. Bogacka, Appl. Sci. (Switzerland) 10, 737 (2020).

    Google Scholar 

  13. H. Rossel, Light Metals 1, 721 (1990).

    Google Scholar 

  14. C. Wang, H. Wang, and Y. Liu, J. Clean. Prod. 102, 378 (2015).

    Article  Google Scholar 

  15. A. Rimšaitė, T. Mumladze, and G. Denafas, Int. J. Agric. Environ. Sci. 6, 103 (2019).

    Google Scholar 

  16. S.F. Zhang, L.L. Zhang, K. Luo, Z.X. Sun, and X.X. Mei, Waste Manag. Res. 32, 317–322 (2014).

    Article  Google Scholar 

  17. Syvertsen, A. Kvithyld, S. Kubowicz, B. Vågenes, and R. Gaarder, Light Metals pp. 727–734 (2021)

  18. C. Wang, H. Wang, G. Gu, J. Fu, and Y. Liu, J. Cent. South Univ. 22, 4545 (2015).

    Article  Google Scholar 

  19. S. Yousef, T. Mumladze, M. Tatariants, R. Kriukien, V. Makarevicius, R. Bendikiene, and G. Denafas, J. Clean. Prod. 197, 379 (2018).

    Article  Google Scholar 

  20. V. Agarwal, P. Halli, S. Helin, F. Tesfaye, and M. Lundström, ACS Sustain. Chem. Eng. 8, 4137 (2020).

    Article  Google Scholar 

  21. S. Eggen, K. Sandaunet, L. Kolbeinsen, and A. Kvithyld, Light Metals. https://doi.org/10.1007/978-3-030-36408-3_148 (2020).

    Article  Google Scholar 

  22. R. D. Peterson, Second International Symposium-recycling of metals and engineered materials, Alabama, USA: the minerals, metals & materials society, 1990, pp 69–84

  23. T. Zhu, X. Yang, X. He, Y. Zheng, and J. Luo, High Perform Polym. 30, 821 (2018).

    Article  Google Scholar 

  24. A.Y. Feldman, E. Wachtel, G.B.M. Vaughan, A. Weinberg, and G. Marom, Macromolecules 39, 4455 (2006).

    Article  Google Scholar 

  25. G. Rusu, and E. Rusu, Mater. Des. 31, 4601 (2010).

    Article  Google Scholar 

  26. J. Zieba-Palus, Foren. Sci. Criminol. 2, 1 (2017).

    Google Scholar 

  27. S. Ramesh, K.H. Leen, K. Kumutha, and A.K. Arof, Spectrochim. Acta A. Mol. Biomol. Spectrosc. 66, 1237 (2007).

    Article  Google Scholar 

  28. M.R. Jung, et al., Mar. Pollut. Bull. 127, 704 (2018).

    Article  Google Scholar 

  29. O.E. Fayemi, A.S. Adekunle, and E.E. Ebenso, J. Nanomater. https://doi.org/10.1155/2016/4049730 (2016).

    Article  Google Scholar 

  30. N.N. Greenwood and A. Earnshaw, Second Edition, Chemistry of Elements. 1984, pp. 107–136.

  31. J. Oskar, United States Patent Office 2, 415 (1935).

    Google Scholar 

  32. H.A. Evans, D. Mullangi, Z. Deng, Y. Wang, S.B. Peh, F. Wei, J. Wang, C.M. Brown, D. Zhao, P. Canepa, and A.K. Cheetham, Sci. Adv. https://doi.org/10.1126/sciadv.ade1473 (2022).

    Article  Google Scholar 

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Acknowledgement

This research was funded by the Scientific and Technological Research Council of Turkey (TÜBITAK) under the BIDEB-2232 program with grant number 118C311. Center for Materials Research at İzmir Institute of Technology is gratefully acknowledged for the sample analyses.

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  1. Department of Materials Science and Engineering, İzmir Institute of Technology, 35430, Izmir, Türkiye

    İrem Yaren Çapkın & Mertol Gökelma

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  1. İrem Yaren Çapkın
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Correspondence to Mertol Gökelma.

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Çapkın, İ.Y., Gökelma, M. Characterization and Separation Behavior of Multi-layers in Aluminum-Rich Waste Pharmaceutical Blisters. JOM 75, 4672–4679 (2023). https://doi.org/10.1007/s11837-023-06072-2

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  • DOI: https://doi.org/10.1007/s11837-023-06072-2

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