Abstract
Two-step thermochemical water splitting (II-TWS), involving concentrating sunlight, has become prominent for green hydrogen production that does not require H2/O2 separation steps at high temperatures. The kinetics and thermodynamics of redox reactions are important factors that determine hydrogen production efficiency. This efficiency is strongly influenced by the structural properties of active materials used in II-TWS reactions. Perovskite oxides are one of the promising active materials for II-TWS due to their superior oxygen exchange abilities. In this study, La1-xCaxMn0.8Co0.2O3 (LCMC) type perovskites with a wide range of calcium substitution (x = 0, 0.2, 0.4, 0.6, 0.8) were examined for hydrogen production in terms of their structural properties, kinetics, O2/H2 production capacities, and cyclabilities. According to our test results, La0.8Ca0.2Mn0.8Co0.2O3 (LCMC8282) and La0.6Ca0.4Mn0.8Co0.2O3 (LCMC6482) displayed higher H2 production capacity with 256 μmol g−1 and 88 μmol g−1 as compared to the other selected perovskites. After three consecutive cycles, La0.8Ca0.2Mn0.8Co0.2O3 lost 83% of its H2 production capacity whereas La0.6Ca0.4Mn0.8Co0.2O3 preserved 61% of its H2 production capacity achieved in the first cycle.
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References
T.N. Veziroğlu and S. Şahin, Energy Convers. Manag. 49, 1820. (2008).
K. Mazloomi and C. Gomes, Renew. Sustain. Energy Rev. 16, 3024. (2012).
J.D. Holladay, J. Hu, D.L. King, and Y. Wang, Catal. Today 139, 244. (2009).
N.S. Lewis and D.G. Nocera, Proc. Natl. Acad. Sci. 103, 15729. (2006).
C.L. Muhich, B.D. Ehrhart, I. Al-Shankiti, B.J. Ward, C.B. Musgrave, and A.W. WeimerWiley Interdiscip. Rev. Energy Environ. 5, 261. (2016).
S. Abanades, Chem. Eng. (2019). https://doi.org/10.3390/chemengineering3030063.
F. Safari and I. Dincer, Energy Convers. Manag. 205, 112182. (2020).
P. Charvin, S. Abanades, G. Flamant, and F. Lemort, Energy 32, 1124. (2007).
H. Kaneko, H. Ishihara, S. Taku, Y. Naganuma, N. Hasegawa, and Y. Tamaura, J. Mater. Sci. 43, 3153. (2008).
N. Gokon, T. Yawata, S. Bellan, T. Kodama, and H.-S. Cho, Energy 171, 971. (2019).
E.N. Coker, A. Ambrosini, M.A. Rodriguez, and J.E. Miller, J. Mater. Chem. 21, 10767. (2011).
J.E. Miller, A.H. McDaniel, and M.D. Allendorf, Adv. Energy Mater. 4, 1. (2014).
W.C. Chueh and S.M. Haile, Philos Trans. R Soc. A Math. Phys. Eng. Sci. 368, 3269. (2010).
A. Le Gal and S. Abanades, Int. J. Hydrogen Energy 36, 4739. (2011).
R. Bader, L.J. Venstrom, J.H. Davidson, and W. Lipiński, Energy Fuels 27, 5533. (2013).
J.R. Scheffe and A. Steinfeld, Mater. Today 17, 341. (2014).
A. Haeussler, S. Abanades, J. Jouannaux, and A. Julbe, Catalysts (2018). https://doi.org/10.3390/catal8120611.
M. Kubicek, A.H. Bork, and J.L.M. Rupp, J. Mater. Chem. A 5, 11983. (2017).
N.F. Atta, A. Galal, and E.H. El-Ads, Perovskite nanomaterials – synthesis, characterization, and applications. In L. Pan, & G. Zhu (Eds.), Perovskite materials - synthesis, characterisation, properties, and applications. IntechOpen. (2016). https://doi.org/10.5772/61280.
A. Demont, S. Abanades, and E. Beche, J. Phys. Chem. C 118, 12682. (2014).
J.R. Scheffe, D. Weibel, and A. Steinfeld, Energy Fuels (2013). https://doi.org/10.1021/ef301923h.
A. Demont and S. Abanades, RSC Adv. 4, 54885. (2014).
M. Takacs, M. Hoes, M. Caduff, T. Cooper, J.R. Scheffe, and A. Steinfeld, Acta Mater. 103, 700. (2016).
S.B. Şanlı and B. Pişkin, Int. J. Hydrogen Energy. (2021). https://doi.org/10.1016/j.ijhydene.2021.12.047.
A. Demont and S. Abanades, J. Mater. Chem. A 3, 3536. (2015).
C.-K. Yang, Y. Yamazaki, A. Aydin, and S.M. Haile, J. Mater. Chem. A 2, 13612. (2014).
S. Dey, B.S. Naidu, and C.N.R. Rao, Chem. A Eur. J. 21, 7077. (2015).
S. Dey, B.S. Naidu, and C.N.R. Rao, Dalt. Trans. 45, 2430. (2016).
L. Wang, T. Ma, S. Dai, T. Ren, Z. Chang, L. Dou, M. Fu, and X. Li, Chem. Eng. J. 389, 124426. (2020).
M. Orfila, M. Linares, R. Molina, J.Á. Botas, R. Sanz, and J. Marugán, Int. J. Hydro. Energy. 41, 19329. (2016).
R.D. Shannon, Acta Crystallogr. Sect. A 32, 751. (1976).
L. Wang, M. Al-Mamun, P. Liu, Y.L. Zhong, Y. Wang, H.G. Yang, and H. Zhao, Acta Metall. Sin. (English Lett. 31, 431. (2018).
L. Wang, M. Al-Mamun, P. Liu, Y. Wang, H.G. Yang, and H. Zhao, J. Mater. Sci. 53, 6796. (2018).
M.M. Nair and S. Abanades, Sust. Energy Fuels 2, 843. (2018).
G. Tang, B. Wu, D. Bai, Y. Wang, R. Bodnar, and C.Q. Zhou, Int. J. Heat Mass Transf. 113, 1142. (2017).
Z. Chen, Q. Jiang, F. Cheng, J. Tong, M. Yang, Z. Jiang, and C. Li, J. Mater. Chem. A 7, 6099. (2019).
A.H. Bork, M. Kubicek, M. Struzik, and J.L.M. Rupp, J. Mater. Chem. A 3, 15546. (2015).
A.E. Danks, S.R. Hall, and Z. Schnepp, Mater. Horiz. 3, 91. (2016).
L. Lutterotti, S. Matthies, and H.R. Wenk, Newsl. CPD 21, 14. (1999).
D.A. Kumar, S. Selvasekarapandian, H. Nithya, J. Leiro, Y. Masuda, S.-D. Kim, and S.-K. Woo, Powder Technol. 235, 140. (2013).
F. He, J. Chen, S. Liu, Z. Huang, G. Wei, G. Wang, Y. Cao, and K. Zhao, Int. J. Hydro. Energy 44, 10265. (2019).
S. Harizanova, E. Faulques, B. Corraze, C. Payen, M. Zajac, D. Wilgocka-ślęzak, J. Korecki, G. Atanasova, and R. Stoyanova, Materials (Basel) (2021). https://doi.org/10.3390/ma14227019.
J.P.H. Li, X. Zhou, Y. Pang, L. Zhu, E.I. Vovk, L. Cong, A.P. Van Bavel, S. Li, and Y. Yang, Phys. Chem. Chem. Phys. 21, 22351. (2019).
M.M. Natile, A. Galenda, and A. Glisenti, Surf. Sci. Spectra 15, 1. (2008).
L. Dahéron, R. Dedryvère, H. Martinez, M. Ménétrier, C. Denage, and C. Delmas Chem. Mater. 20(2), 583–590. (2008). https://doi.org/10.1021/cm702546s.
H. Liu, G.C. Lin, X.D. Ding, and J.X. Zhang, J. Solid State Chem. 200, 305. (2013).
K. Watanabe, M. Yuasa, T. Kida, K. Shimanoe, Y. Teraoka, and N. Yamazoe, Solid State Ionics 179, 1377. (2008).
D. Mierwaldt, S. Mildner, R. Arrigo, A. Knop-Gericke, E. Franke, A. Blumenstein, J. Hoffmann, and C. Jooss, Catalysts 4, 129. (2014).
L. Baggetto, N.J. Dudney, and G.M. Veith, Electrochim. Acta. 90, 135. (2013).
E.S. Ilton, J.E. Post, P.J. Heaney, F.T. Ling, and S.N. Kerisit, Appl. Surf. Sci. 366, 475. (2016).
B. Pişkin, C. Savaş Uygur, and M.K. Aydınol, Int. J. Energy Res. 42, 3888. (2018).
M.C. Biesinger, B.P. Payne, A.P. Grosvenor, L.W.M. Lau, A.R. Gerson, and R.S.C. Smart, Appl. Surf. Sci. 257, 2717. (2011).
T. Vijayaraghavan, R. Sivasubramanian, S. Hussain, and A. Ashok, Chem. Select 2, 5570. (2017).
S. Thirumalairajan, K. Girija, V.R. Mastelaro, V. Ganesh, and N. Ponpandian, RSC Adv. 4, 25957. (2014).
R. Dudric, A. Vladescu, V. Rednic, M. Neumann, I.G. Deac, and R. Tetean, J. Mol. Struct. 1073, 66. (2014).
J.L.G. Fierro, Catal. Today 8, 153. (1990).
A.K. Opitz, C. Rameshan, M. Kubicek, G.M. Rupp, A. Nenning, T. Götsch, R. Blume, M. Hävecker, A. Knop-Gericke, G. Rupprechter, B. Klötzer, and J. Fleig, Top. Catal. 61, 2129. (2018).
Acknowledgements
The authors gratefully acknowledge TUBITAK (The Scientific and Technological Research Council of Turkey) for their support and funding (project number 119M420). The authors also wish to acknowledge Prof. Dr. Mehmet Öztürk and Prof. Dr. Mehmet Emin Duru for support with mass spectrometer analysis.
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Yiğiter, İ.E., Pişkin, B. Investigation into Ca-Doped LaMnCoO3 Perovskite Oxides for Thermochemical Water Splitting. JOM 74, 4682–4694 (2022). https://doi.org/10.1007/s11837-022-05493-9
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DOI: https://doi.org/10.1007/s11837-022-05493-9