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Microstructure and Corrosion Behaviors of High-Strength and High-Elasticity Cu-20Ni-20Mn-xGa Alloys

  • Recent Advances in Multicomponent Alloys and Ceramics
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Abstract

Cu-20Ni-20Mn-xGa (x = 1, 5 wt.%) alloys with high strength and elasticity were prepared and tested for corrosion properties in 3.5 wt.% NaCl solution. The hardness, tensile strength, elongation, and annual corrosion rate of the Cu-20Ni-20Mn-1 Ga alloy reached 1368 MPa, 442 HV, 8.63%, and 0.0262 mm/year, respectively, while those of Cu-20Ni-20Mn-5 Ga alloy were 1278 MPa, 428 HV, 2.5%, and 0.0119 mm/year, respectively. The excellent mechanical properties were attributed to the nanoscale NiMn phase which can strengthen the copper matrix. In addition to grain refinement, the addition of Ga also reduced the cathodic current. Also, the corrosion products of the two alloys in 3.5 wt.% NaCl solution were mainly oxides and chlorides. The Cu-20Ni-20Mn-5 Ga showed better corrosion resistance with more gallium-rich oxides in the corrosion product film to resist corrosion.

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Acknowledgements

This work is supported by the National Key R&D Program of China (No. 2021YFB3501000), National Natural Science Foundation of China (No. 51701241), National Defense Pre-Research Foundation of China (No. 61402100105), the China Postdoctoral Science Foundation (No. 2018T110838) and Natural Science Foundation of Hunan Province (No. 2018JJ3647).

Funding

Funding was provided by National Key R&D Program of China, (Grant No. 2021YFB3501000), Shen Gong.

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Authors and Affiliations

  1. School of Materials Science and Engineering, Central South University, Changsha, 410083, Hunan, China

    Yin Xiong, Deyu Jiang, Zuojie Xu, Shen Gong & Xiaojun Zhao

  2. State Key Laboratory of Powder Metallurgy, Changsha, 410083, China

    Shen Gong

  3. Shanghai Aerospace Control Technology Institute, Shanghai, 201109, China

    Jiajun Li & Jiali Guo

  4. State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing, 100083, People’s Republic of China

    Guoliang Xie

  5. State Key Laboratory of Nonferrous Metals and Processes, GRIMAT Engineering Institute Co Ltd., Beijing, 101417, China

    Lijun Peng

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  1. Yin Xiong
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Xiong, Y., Jiang, D., Xu, Z. et al. Microstructure and Corrosion Behaviors of High-Strength and High-Elasticity Cu-20Ni-20Mn-xGa Alloys. JOM 74, 4258–4270 (2022). https://doi.org/10.1007/s11837-022-05445-3

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