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Spin-Polarized Transport and Optoelectronic Properties of a Novel-Designed Architecture with a Porphyrin-Based Wheel and Organometallic Multidecker Sandwich Complex-Based Axle

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Abstract

A novel “wheel-and-axle” architecture (c-P6)m/(FeBz)n, with (c-P6) denoting the wheel formed by six porphyrin-based segments and (FeBz)n the axle formed by the 1D iron benzene multidecker complex, is designed, and its electronic structure, transport property, and linear photoresponse are investigated. (c-P6)m/(FeBz)n shows a spin-polarized transport property. The spin filter efficiency of (c-P6)m/(FeBz)n can be > 90%, suggesting it is a very good candidate for spin filters. Furthermore, a distinct NDR feature is observed for (c-P6)m/(FeBz)n so it is can be used for making electronic switches and oscillators. Under linear light, both the wheel and axle of (c-P6)m/(FeBz)n exhibit a distinct polarized photoresponse character. The magnitude of the photoresponse can be tuned by the photon energy or by the l bias voltage. An off–on–off switch is observed within the considered photon energy range, showing potential application for optical switches. All these fascinating properties of (c-P6)m/(FeBz)n make the new 1D material especially attractive for electronic and optoelectronic devices.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant No. 51973046), Nature Science Foundation of Heilongjiang Province of China (Grant No. B2018007), and Harbin Foundation for Leaders of Disciplines (Grant No. 2017RAXXJ002).

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Authors and Affiliations

  1. School of Materials Science and Engineering, Harbin University of Science and Technology, Harbin, 150080, China

    Shengnan Gao, Zhaodi Yang, Yuxiu Wang, Guiling Zhang & Yangyang Hu

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  1. Shengnan Gao
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Gao, S., Yang, Z., Wang, Y. et al. Spin-Polarized Transport and Optoelectronic Properties of a Novel-Designed Architecture with a Porphyrin-Based Wheel and Organometallic Multidecker Sandwich Complex-Based Axle. JOM 72, 3149–3159 (2020). https://doi.org/10.1007/s11837-020-04153-0

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