Abstract
The precipitation behavior of Mg-Al alloys during isothermal ageing has been investigated by dilatometry. Only continuous precipitation was observed in Mg-5.5Al during ageing at 175°C, 200°C, or 225°C, while both discontinuous and continuous precipitation occurred in Mg-8.9Al at the same ageing temperatures. Dilatometry curves showed that Mg-8.9Al expanded when aged at 225°C or 250°C. These results demonstrate that high content of Al is beneficial for discontinuous precipitation in binary Mg-Al alloys. Additional analyses indicated that the expansion of Mg-8.9Al during isothermal ageing can be attributed to the increment of the Mg cell lattice parameters. Moreover, continuous precipitation could suppress the discontinuous precipitation by reducing the driving force for growth of discontinuous precipitates.
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References
A.A. Nayeb-Hashemi and J.B. Clark, Phase Diagrams of Binary Magnesium Alloys (Metals Park: ASM International, 1988), pp. 17–42.
J.-F. Nie, Metall. Mater. Trans. A 43, 3891 (2012).
X.-F. Sun, C.-J. Wang, K.-K. Deng, J.-W. Kang, Y. Bai, K.-B. Nie, and S.-J. Shang, J. Alloys Compd. 727, 1263 (2017).
J.-H. Jun, J. Alloys Compd. 725, 237 (2017).
D. Duly, J. Simon, and Y. Brechet, Acta Metall. Mater. 43, 101 (1995).
K.N. Braszczyńska-Malik, J. Alloys Compd. 477, 870 (2009).
J.D. Robson, Acta Mater. 61, 7781 (2013).
M. Hunkel, H. Surm, and M. Steinbacher, Dilatometry, ed. S. Vyazovkin, N. Koga, and C. Schick (Amsterdam: Elsevier, 2018), pp. 103–129.
C.G. de Andrés, F. Caballero, C. Capdevila, and L. Alvarez, Mater. Charact. 48, 101 (2002).
T. Kop, J. Sietsma, and S. Van Der Zwaag, J. Mater. Sci. 36, 519 (2001).
F. Lasagni, M. Dumont, C. Salamida, J.A. Acuña, and H.P. Degischer, Int. J. Mater. Res. 100, 1005 (2009).
W. Kasprzak, F. Czerwinski, M. Niewczas, and D.L. Chen, J. Mater. Eng. Perform. 24, 1365 (2015).
B. Milkereit, M. Reich, and O. Kessler, Mater. Sci. Forum 877, 147 (2017).
W. Gust, Int. Mater. Rev. 43, 70 (1998).
S.K. Pabi and W. Gust, Int. Mater. Rev. 46, 53 (2001).
G. Gottstein and L.S. Shvindlerman, Grain Boundary Migration in Metals: Thermodynamics, Kinetics, Applications (Boca Raton: CRC Press, 2009), pp. 135–149.
L. Priester, Grain Boundaries: From Theory to Engineering (Berlin: Springer, 2012), pp. 236–240.
R. Speyer, Thermal Analysis of Materials (Boca Raton: CRC Press, 1993), pp. 166–168.
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One of the authors (X.Z., CSC No. 201705290015) would like to thank the China Scholarship Council (CSC) for financial support.
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Zhang, X., Huang, Y., Li, X. et al. Unexpected Expansion Behavior of Mg-Al Alloys During Isothermal Ageing. JOM 71, 2906–2912 (2019). https://doi.org/10.1007/s11837-019-03516-6
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DOI: https://doi.org/10.1007/s11837-019-03516-6