Skip to main content
Log in

Effect of Minor Titanium Addition on Copper/Diamond Composites Prepared by Hot Forging

  • Powder Metallurgy of Non-Ferrous Metals
  • Published:
JOM Aims and scope Submit manuscript

Abstract

Copper/diamond composites have great potential to lead the next generation of advanced heat sink materials for use in high-power electronic devices and high-density integrated circuits because of their potential excellent properties of high thermal conductivity and close thermal expansion to the chip materials (e.g., Si, InP, GaAs). However, the poor wettability between copper and diamond presents a challenge for synthesizing copper/diamond composites with effective metallurgical bonding and satisfied thermal performance. In this article, copper/diamond composites were successfully prepared by hot forging of elemental copper and artificial diamond powders with small amounts (0 vol.%, 3 vol.% and 5 vol.%) of titanium additives. Microstructure observation and mechanical tests showed that adding minor titanium additions in the copper/diamond composite resulted in fewer cracks in the composites’ microstructure and significantly improved the bonding between the copper and diamond. The strongest bonding strength was achieved for the copper/diamond composite with 3 vol.% titanium addition, and the possible reasons were discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. T. Schubert, A. Brendel, K. Schmid, T. Koeck, L. Ciupinski, W. Zielinski, T. Weissgarber, and B. Kieback, Compos. Part A Appl. Sci. Manuf. 38, 2398 (2007).

    Article  Google Scholar 

  2. J.M. Molina, M. Rheme, J. Carron, and L. Weber, Scr. Mater. 58, 393 (2008).

    Article  Google Scholar 

  3. R. Arpon, J.M. Molina, R.A. Saravanan, C.G. Cordovilla, E. Louis, and J. Narciso, Acta Mater. 51, 3145 (2003).

    Article  Google Scholar 

  4. M. Schobel, H.P. Degischer, S. Vaucher, M. Hofmann, and P. Cloetens, Acta Mater. 58, 6421 (2010).

    Article  Google Scholar 

  5. P.W. Ruch, O. Beffort, S. Kleiner, L. Weber, and P.J. Uggowitzer, Compos. Sci. Technol. 66, 2677 (2006).

    Article  Google Scholar 

  6. J. Grzonka, M.J. Kruszewski, M. Rosiński, L. Ciupiński, A. Michalski, and K.J. Kurzydłowski, Mater. Charact. 99, 188 (2015).

    Article  Google Scholar 

  7. K. Chu, Z.F. Liu, C.C. Jia, H. Chen, X.B. Liang, W.J. Gao, W.H. Tian, and H. Guo, J. Alloys Compd. 490, 453 (2010).

    Article  Google Scholar 

  8. Q.L. Che, X.K. Chen, Y.Q. Ji, Y.W. Li, L.X. Wang, S.Z. Cao, Y.G. Jiang, and Z. Wang, Mater. Sci. Semicond. Process. 30, 104 (2015).

    Article  Google Scholar 

  9. Y. Zhang, H.L. Zhang, J.H. Wu, and X.T. Wang, Scr. Mater. 65, 1097 (2011).

    Article  Google Scholar 

  10. L. Weber and R. Tavangar, Scr. Mater. 57, 988 (2007).

    Article  Google Scholar 

  11. W.P. Shen, W.J. Shao, Q.Y. Wang, and M.L. Ma, Fusion Eng. Des. 85, 2237 (2010).

    Article  Google Scholar 

  12. E.A. Ekimov, N.V. Suetin, A.F. Popovich, and V.G. Ralchenko, Diam. Relat. Mater. 17, 838 (2008).

    Article  Google Scholar 

  13. A.M. Abyzov, S.V. Kidalov, and F.M. Shakhov, Appl. Therm. Eng. 48, 72 (2012).

    Article  Google Scholar 

  14. S.B. Ren, X.Y. Shen, C.Y. Guo, N. Liu, J.B. Zang, X.B. He, and X.H. Qu, Compos. Sci. Technol. 71, 1550 (2011).

    Article  Google Scholar 

  15. J.L. Murray, Bull. Alloys Phase Diagr. 4, 81 (1983).

    Article  Google Scholar 

  16. T. Schubert, B. Trindade, T. Weißgärber, and B. Kieback, Mater. Sci. Eng. A 475, 39 (2008).

    Article  Google Scholar 

  17. S. Kleiner, F.A. Khalid, P.W. Ruch, S. Meier, and O. Beffort, Scr. Mater. 55, 291 (2006).

    Article  Google Scholar 

  18. Y.S. Liao and S.Y. Luo, J. Mater. Sci. 28, 1245 (1993).

    Article  Google Scholar 

  19. S. Nagarjuna, M. Srinivas, K. Balasubramanian, and D.S. Sarma, Mater. Sci. Eng. A 259, 34 (1999).

    Article  Google Scholar 

  20. K. Chu, C.C. Jia, H. Guo, and W.S. Li, Mater. Des. 45, 36 (2013).

    Article  Google Scholar 

Download references

Acknowledgements

We gratefully acknowledged the funding from the US Air Force Asian Office of Aerospace R&D (Grant No. FA2386-17-1-4025) and the University of Waikato, New Zealand (Grant No. 2017-SIF-F759) that supported this work.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Fei Yang.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Yang, F., Sun, W., Singh, A. et al. Effect of Minor Titanium Addition on Copper/Diamond Composites Prepared by Hot Forging. JOM 70, 2243–2248 (2018). https://doi.org/10.1007/s11837-018-2815-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11837-018-2815-2

Navigation