Abstract
In the vanadium metallurgical industry, massive amounts of ammonia hydroxide or ammonia salt are added during the precipitation process to obtain V2O5; therefore, wastewater containing a high level of NH4+ is generated, which poses a serious threat to environmental and hydrologic safety. In this article, a novel process was developed to recycle ammonia wastewater based on a combination of ammonia wastewater leaching and crystallization during vanadium extraction from shale. The effects of the NH4+ concentration, temperature, time and liquid-to-solid ratio on the leaching efficiencies of vanadium, aluminum and potassium were investigated, and the results showed that 93.2% of vanadium, 86.3% of aluminum and 96.8% of potassium can be leached from sulfation-roasted shale. Subsequently, 80.6% of NH4+ was separated from the leaching solution via cooling crystallization. Vanadium was recovered via a combined method of solvent extraction, precipitation and calcination. Therefore, ammonia wastewater was successfully recycled during vanadium extraction from shale.
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Acknowledgements
This work was supported by the Project of National Science Foundation of China (Nos. 51474162, 51774215, and 51574216).
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Shi, Q., Zhang, Y., Liu, T. et al. Recycling of Ammonia Wastewater During Vanadium Extraction from Shale. JOM 70, 1991–1996 (2018). https://doi.org/10.1007/s11837-018-2800-9
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DOI: https://doi.org/10.1007/s11837-018-2800-9