Abstract
Titanium and its alloys are recognized for their attractive properties. However, high-performance Ti alloys are often alloyed with rare or noble-metal elements. In the present study, Ti alloys doped with only ubiquitous elements were produced via powder metallurgy. The experimental results showed that pure Ti with 1.5 wt.% AlN incorporated exhibited excellent tensile properties, superior to similarly extruded Ti-6Al-4V. Further analysis revealed that its remarkably advanced strength could primarily be attributed to nitrogen solid-solution strengthening, accounting for nearly 80% of the strength increase of the material. In addition, despite the ultrahigh nitrogen concentration up to 0.809 wt.%, the Ti-1.5AlN sample showed elongation to failure of ~ 10%. This result exceeds the well-known limitation for nitrogen (over 0.45 wt.%) that causes embrittlement of Ti alloys.
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References
D. Banerjee and J.C. Williams, Acta Mater. 61, 844 (2013).
A.M. Khorasani, M. Goldberg, E.H. Doeven, and G. Littlefair, J. Biomater. Tissue Eng. 5, 593 (2015).
D. Kuroda, M. Niinomi, M. Morinaga, Y. Kato, and T. Yashiro, Mater. Sci. Eng. A 243, 244 (1998).
M. Geetha, A.K. Singh, R. Asokamani, and A.K. Gogia, Prog. Mater. Sci. 54, 397 (2009).
G. Lütjering and J.C. Williams, Titanium, 2nd ed. (Berlin: Springer, 2007).
B. Sun, S. Li, H. Imai, T. Mimoto, J. Umeda, and K. Kondoh, Mater. Sci. Eng. A 563, 95 (2013).
X.X. Ye, B. Chen, J.H. Shen, J. Umeda, and K. Kondoh, J. Alloys Compd. 709, 381 (2017).
X.X. Ye, H. Imai, J.H. Shen, B. Chen, G.Q. Han, J. Umeda, M. Takahashi, and K. Kondoh, Mater. Sci. Eng. A 684, 165 (2017).
K. Kondoh, B. Sun, S. Li, H. Imai, and J. Umeda, Int. J. Powder Metall. 50, 35 (2014).
T. Mimoto, J. Umeda, and K. Kondoh, Mater. Trans. 56, 1153 (2015).
Y. Zheng, X. Yao, Y. Su, and D.L. Zhang, Mater. Sci. Eng. A 686, 11 (2017).
B. Chen, J. Shen, X. Ye, J. Umeda, and K. Kondoh, J. Mater. Res. 32, 3769 (2017).
S.C. Tjong and Z.Y. Ma, Mater. Sci. Eng. R Rep. 29, 49 (2000).
D.J. Lloyd, Int. Mater. Rev. 39, 1 (1994).
I.A. Ibrahim, F.A. Mohamed, and E.J. Lavernia, J. Mater. Sci. 26, 1137 (1991).
K. Ma, T. Hu, H. Yang, T. Topping, A. Yousefiani, E.J. Lavernia, and J.M. Schoenung, Acta Mater. 103, 153 (2016).
K. Ma, H. Wen, T. Hu, T.D. Topping, D. Isheim, D.N. Seidman, E.J. Lavernia, and J.M. Schoenung, Acta Mater. 62, 141 (2014).
R. Jamaati, M.R. Toroghinejad, and H. Edris, Mater. Des. 54, 168 (2014).
Ö. Balcı, D. Ağaoğulları, H. Gökçe, İ. Duman, and M.L. Öveçoğlu, J. Alloys Compd. 586, S78 (2014).
K.K. Deng, J.Y. Shi, C.J. Wang, X.J. Wang, Y.W. Wu, K.B. Nie, and K. Wu, Compos. Part A Appl. S 43, 1280 (2012).
J.E. Mogonye, A. Srivastava, S. Gopagoni, R. Banerjee, and T.W. Scharf, Tribol. Lett. 64, 12 (2016).
J. Shen, W. Yin, Q. Wei, Y. Li, J. Liu, and L. An, J. Mater. Res. 28, 1835 (2013).
H. Conrad, Prog. Mater Sci. 26, 123 (1981).
M. Yan, W. Xu, M.S. Dargusch, H.P. Tang, M. Brandt, and M. Qian, Powder Metall. 57, 251 (2014).
J. Shen, B. Chen, X. Ye, H. Imai, J. Umeda, and K. Kondoh, Mater. Des. 116, 99 (2017).
R.I. Jaffee, H.R. Ogden, and D.J. Maykuth, Trans. AIME 188, 1261 (1950).
Y. Estrin and A. Vinogradov, Acta Mater. 61, 782 (2013).
R.J. Lederich, S.M.L. Sastry, J.E. O’Neal, and B.B. Rath, Mater. Sci. Eng. 33, 183 (1978).
Y.K. Li, F. Liu, G.P. Zheng, D. Pan, Y.H. Zhao, and Y.M. Wang, Mater. Sci. Eng. A 573, 141 (2013).
R.L. Fleischer, Acta Metall. 10, 835 (1962).
R.L. Fleischer, Acta Metall. 11, 203 (1963).
J.H. Shen, Y.L. Li, and Q. Wei, Mater. Sci. Eng. A 582, 270 (2013).
H.W. Rosenberg and W.D. Nix, Metall. Trans. 4, 1333 (1973).
Acknowledgements
This work was partially supported by the Japan Science and Technology Agency (JST) under Industry–Academia Collaborative R&D Program “Heterogeneous Structure Control: Towards Innovative Development of Metallic Structural Materials.”
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Shen, J., Chen, B., Umeda, J. et al. Advanced Mechanical Properties of a Powder Metallurgy Ti-Al-N Alloy Doped with Ultrahigh Nitrogen Concentration. JOM 70, 626–631 (2018). https://doi.org/10.1007/s11837-018-2780-9
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DOI: https://doi.org/10.1007/s11837-018-2780-9