Abstract
In this study, the electrical conductivity of polylactic acid (PLA)-based composites has been improved using polyaniline (PANI) with two different solvents: dodecylbenzene sulfonic acid and citric acid. The effects of various factors including PLA quantity, solvent concentration, type of solvent and thickness on the resistivity were investigated using the design of experiments. The experimental plan was based on irregular fraction design to develop the regression models. The results revealed that the proposed mathematical models were sufficient and could describe the performance of resistivity of PLA within the limits of a factor. The findings also indicated that thickness had the most significant effect on the resistivity of PLA, while the effect of the type of solvent was of least significance. Moreover, it was illustrated that, by incorporating two different solvents into PANI, the resistivity could be changed for further applications.
Similar content being viewed by others
References
P.K. Bajpai, I. Singh, and J. Madaan, Wear 297, 829 (2013).
M. Murariu and P. Dubois, Adv. Drug Deliv. Rev. 107, 17 (2016).
R.N. Salaway and L.V. Zhigilei, Int. J. Heat Mass Transf. 70, 954 (2014).
S.M.S. Murshed and C.A. Nieto de Castro, Renew. Sustain. Energy Rev. 37, 155 (2014).
M.M. Taheri, M. Rezazadeh Shirdar, A. Keyvanfar, and A. Shafaghat, J. Exp. Nanosci. 12, 83 (2016).
M. Rezazadeh Shirdar, I. Sudin, M.M. Taheri, A. Keyvanfar, M.Z.M. Yusop, and M.R.A. Kadir, Vacuum 122, 82 (2015).
H. Yoshikawa, T. Hino, and N. Kuramoto, Synth. Met. 156, 1187 (2006).
A.A. Athawale, S.V. Bhagwat, and P.P. Katre, Sensors Actuators B Chem. 114, 263 (2006).
L. Tarachiwin, P. Kiattibutr, L. Ruangchuay, A. Sirivat, and J. Schwank, Synth. Met. 129, 303 (2002).
P.K. Kahol, A.J. Dyakonov, and B.J. McCormick, Synth. Met. 89, 17 (1997).
S.R. White, Phys. Rev. B 53, 52 (1996).
Z. Han and A. Fina, Prog. Polym. Sci. 36, 914 (2011).
P. Zhang, W. Hong, J.F. Wu, G.Z. Liu, J. Xiao, Z.B. Chen, and H.B. Cheng, Energy Procedia 69, 699 (2015).
M. Xing, J. Yu, and R. Wang, Int. J. Heat Mass Transf. 88, 609 (2015).
M.M. Taheri, M.R. Abdul Kadir, N.K. Ahmad Shafiai, T. Shokuhfar, M. Assadian, and M.R. Shirdar, Trans. Nonferrous Met. Soc. China 25, 3286 (2015).
A. Habibolahzadeh, A. Hassani, E. Bagherpour, and M. Taheri, J. Compos. Mater. 48, 1049 (2014).
M.T. Byrne and Y.K. Gun’ko, Adv. Mater. 22, 1672 (2010).
D.C. Montgomery, Design and Analysis of Experiments (Hoboken: Wiley, 2008).
E. Rozet, P. Lebrun, P. Hubert, B. Debrus, and B. Boulanger, TrAC. Trends Anal. Chem. 42, 157 (2013).
M.R. Shirdar, A. Golshan, S. Izman, and D. Ghodsiyeh, J. Mater. Eng. Perform. 23, 13 (2014).
G.D. Khuspe, D.K. Bandgar, S. Sen, and V.B. Patil, Synth. Met. 162, 1822 (2012).
M. Assadian, M.R. Shirdar, M.H. Idris, S. Izman, D. Almasi, M.M. Taheri, and M.R.A. Kadir, Arab. J. Sci. Eng. 40, 923 (2015).
M.R. Shirdar, S. Izman, M.M. Taheri, M. Assadian, and M.R. Abdul Kadir, Arab. J. Sci. Eng. 41, 591 (2015).
M.Y. Noordin, V.C. Venkatesh, S. Sharif, S. Elting, and A. Abdullah, J. Mater. Process. Technol. 145, 46 (2004).
M. Rezazadeh Shirdar, M.M. Taheri, H. Moradifard, A. Keyvanfar, A. Shafaghat, T. Shokuhfar, and S. Izman, Ceram. Int. 42, 6942 (2016).
S.U.S. Choi, Z.G. Zhang, W. Yu, F.E. Lockwood, and E.A. Grulke, Appl. Phys. Lett. 79, 2252 (2001).
M. Farbod, A. Ahangarpour, and S.G. Etemad, Particuology 22, 59 (2015).
A.M. Youssef, S.A. Mohamed, M.S. Abdel-Aziz, M.E. Abdel-Aziz, G. Turky, and S. Kamel, Carbohydr. Polym. 147, 333 (2016).
A.M. Youssef, RSC Adv. 4, 6811 (2014).
M.A.A. El-Ghaffar, A.M. Youssef, and A.A.A. El-Hakim, Arab. J. Chem. 8, 771 (2015).
L.H.C. Mattoso, E.S. Medeiros, D.A. Baker, J. Avloni, D.F. Wood, and W.J. Orts, J. Nanosci. Nanotechnol. 9, 2917 (2009).
A.M. Youssef, M.A. El-Samahy, and M.H. Abdel, Rehim. Carbohydr. Polym. 89, 1027 (2012).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Shah, A.M., Kadir, M.R.A. & Razak, S.I.A. Novel PLA-Based Conductive Polymer Composites for Biomedical Applications. JOM 69, 2838–2843 (2017). https://doi.org/10.1007/s11837-017-2577-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11837-017-2577-2