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A novel synthesis of ditrimethylolpropane biphosphoramide diethyleneamine as flame retardant and antistatic textiles

  • Polymer, Industrial Chemistry
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Abstract

A novel phosphorous- and nitrogen-containing flame retardant, ditrimethylolpropane biphosphoramide diethyleneamine (DBD), was synthesized. Its chemical structure is characterized by Fourier-transform infrared spectroscopy and 1H nuclear magnetic resonance spectroscopy. The effect of DBD on the physical, mechanical, and antistatic properties, thermal stability, and flame retardancy of wool fabric was systematically investigated. Thermogravimetric analysis showed that the initial decomposition temperature of DBD was 165 oC and 243 oC under nitrogen and air atmosphere, respectively. Furthermore, after 30 washes, the treated wool fabric exhibited excellent wash durability and good antistatic properties. Vertical burning tests indicated that both the burning time and char length of the treated wool fabric were lower than those of the flame-retardant standard, leading to a B1 flame retardant rating for the treated wool fabric. Compared to untreated wool fabric, the limiting oxygen index value of treated wool fabric increased significantly from 25.7% to 34.7%.

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Acknowledgements

This work was supported by the Technology Innovation Program (or Industrial Strategic Technology Development Program-Development of technology on materials and components) (20010106, Adhesives with low water permeability and low outgassing) funded By the Ministry of Trade, Industry & Energy (MOTIE, Korea) and supported by the Technological Innovation R&D Program (S2829590) funded by the Small and Medium Business Administration (SMBA, Korea).

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Authors and Affiliations

  1. Department of Polymer Materials, Jilin Institute of Chemical Technology, Jilin City, 132022, China

    Wei Jiang, Jin-Feng Li, Zi-Yuan Li & Fan-Long Jin

  2. Refinery of Jilin Petrochemical Company, Jilin City, 132022, China

    Xiao-Yan Zhang

  3. Department of Chemistry, Inha University, Incheon, 22212, Korea

    Soo-Jin Park

Authors
  1. Wei Jiang
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  2. Jin-Feng Li
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  3. Zi-Yuan Li
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  4. Xiao-Yan Zhang
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  5. Fan-Long Jin
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  6. Soo-Jin Park
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Correspondence to Fan-Long Jin or Soo-Jin Park.

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Jiang, W., Li, JF., Li, ZY. et al. A novel synthesis of ditrimethylolpropane biphosphoramide diethyleneamine as flame retardant and antistatic textiles. Korean J. Chem. Eng. 38, 872–884 (2021). https://doi.org/10.1007/s11814-021-0744-1

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  • DOI: https://doi.org/10.1007/s11814-021-0744-1

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