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Measurement and modeling of transport properties of binary liquid mixtures containing oxygenates and n-alkanes

  • Separation Technology, Thermodynamics
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Abstract

Dynamic viscosities (η) of the binary liquid mixtures of 2-propanol (1)+n-alkanes (C6, C7, C9) (2) at T=288.15 K to 303.15 K and ethanol (1)+n-alkanes (C6, C7, C8) (2) at T=308.15 K to 318.15 K were experimentally measured over the whole composition range. Experimental values of η were used to compute the deviation in dynamic viscosity (Δη) and these Δη values were correlated with the Redlich-Kister equation. The η values of binary mixtures were also calculated using several empirical correlations and mixing rules like Grunberg-Nissan, Tamura-Kurata, Kati-Chaudhari and McLaughlin-Ubbelohde and found that the Grunberg-Nissan correlation gave the best estimation. The Δη values were also predicted by an approach given by Singh et al. [Indian J Chem 29, 263 (1990)].

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Acknowledgement

for the financial support, Pinki Kashyap acknowledges the University Grant Commission, New Delhi (as SRF).

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Authors and Affiliations

  1. Department of Chemical Engineering, Deenbandhu Chhotu Ram University of Science and Technology, Murthal, 131 039, India

    Pinki Kashyap, Manju Rani & Dinesh Pratap Tiwari

  2. Department of Chemical Engineering and Applied Chemistry, College of Engineering, Chungnam National University, Daejeon, 34134, Korea

    Manju Rani & So-Jin Park

  3. Rajiv Gandhi Government Engineering College, Kangra, 176047, Himachal Pradesh, India

    Dinesh Pratap Tiwari

Authors
  1. Pinki Kashyap
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  2. Manju Rani
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  3. Dinesh Pratap Tiwari
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  4. So-Jin Park
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Correspondence to Manju Rani or So-Jin Park.

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Kashyap, P., Rani, M., Tiwari, D.P. et al. Measurement and modeling of transport properties of binary liquid mixtures containing oxygenates and n-alkanes. Korean J. Chem. Eng. 36, 1922–1931 (2019). https://doi.org/10.1007/s11814-019-0380-1

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  • DOI: https://doi.org/10.1007/s11814-019-0380-1

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