Skip to main content
SpringerLink
Log in

Anti-corrosive performance of epoxy coatings containing various nano-particles for splash zone applications

  • Materials (Organic, Inorganic, Electronic, Thin Films)
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

Various formulations of epoxy nano-composites coating were developed by incorporating the nanoparticles (NPs) of ZnO, ZrO2, and SiO2 (2 wt%) in commercially available epoxy resin as the matrix phase. Direct incorporation method was used for the addition of NPs in epoxy matrix. High-speed mechanical stirring and ultra-sonication were carried out to facilitate the dispersion of NPs in the presence of acetone used as a solvent. Coating of neat epoxy and NPs (ZnO, ZrO2, SiO2) doped coating was applied on mild steel substrate for corrosion analysis. The effect of the incorporation of various NPs on anti-corrosive properties of the epoxy/nano-composite coatings was investigated by electrochemical impedance spectroscopy technique. The experimental results showed an improvement in the anticorrosive properties for EZr coatings as compared with pristine and other nanocomposite coating samples.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. E. Bardel, Corrosion and Protection, Springer, London (2003).

    Google Scholar 

  2. E. S. Ferreira, C. Giacomelli, F.C. Giacomelli and A. Spinelli, Mater. Chem. Phys., 83, 129 (2004).

    Article  CAS  Google Scholar 

  3. M. M. Popovic, B. N. Grgur and V.B. Miškovic-Stankovic, Prog. Org. Coat., 52, 359 (2005).

    Article  CAS  Google Scholar 

  4. B.D. Pennington, J. C. Grunlan and M.W. Urban, J. Coating. Technol., 71, 135 (1999).

    Article  CAS  Google Scholar 

  5. M. Ates, J. Adhes. Sci. Technol., 30, 1510 (2016).

    Article  CAS  Google Scholar 

  6. H. Leidheiser Jr., Corrosion., 38, 374 (1982).

    Article  CAS  Google Scholar 

  7. G. A. Walter, Corros. Sci., 26, 27 (1986).

    Article  CAS  Google Scholar 

  8. E. P. M. Van Westing, G. M. Ferrari and J. H.W. De Wit, Corros. Sci., 34, 1511 (1993).

    Article  CAS  Google Scholar 

  9. S. E. Hörnström, J. Karlsson, W. J. Van Ooij, N. Tang and H. Klang, J. Adhes. Sci. Technol., 10, 883 (1996).

    Article  Google Scholar 

  10. W. G. Ji, J. M. Hu, L. Liu, J.Q. Zhang and C. N. Cao, J. Adhes. Sci. Technol., 22, 77 (2008).

    CAS  Google Scholar 

  11. N.C. Rosero-Navarro, S.A. Pellice, A. Durán and M. Aparicio, Corros. Sci., 20, 1283 (2008).

    Article  Google Scholar 

  12. T.C. Huang, Y. A. Su, T. C. Yeh, H.Y. Huang, C.P. Wu, K.Y. Huang, Y.C. Chou, J.M. Yeh and Y. Wei, Electrochim. Acta, 56, 6142 (2011).

    Article  CAS  Google Scholar 

  13. L. Ma, F. Chen, Z. Li, M. Gan, J. Yan, S. Wei, Y. Bai and J. Zeng, Compos. Part B-Eng., 58, 54 (2014).

    Article  CAS  Google Scholar 

  14. H. Shi, F. Liu, L. Yang and E. Han, Prog. Org. Coat., 62, 359 (2008).

    Article  CAS  Google Scholar 

  15. P. P. Mahulikar, R. S. Jadhav and D. G. Hundiwale, Iran. Polym. J., 20, 367 (2011).

    CAS  Google Scholar 

  16. A.C. Balaskas, I. A. Kartsonakis, L.A. Tziveleka and G. Kordas, Prog. Org. Coat., 74, 418 (2012).

    Article  CAS  Google Scholar 

  17. N. Kouloumbi, G.M. Tsangaris, C. Vourvahi and F. Molnar, J. Coat. Technol., 69, 53 (1997).

    Article  CAS  Google Scholar 

  18. L. Veleva, J. Chin and B. Del Amo, Prog. Org. Coat., 36, 211 (1999).

    Article  CAS  Google Scholar 

  19. M. Rashvand, Z. Ranjbar and S. Rastegar, J. Electrochem. Soc., 159, C129 (2012).

    Article  CAS  Google Scholar 

  20. S.K. Dhoke, A. Khanna and T. J.M. Sinha, Prog. Org. Coat., 64, 371 (2009).

    Article  CAS  Google Scholar 

  21. A. Ehsani, M. Ghasem Mahjani, M. Nasseri and M. Jafarian, Anti-Corros. Method. M., 61, 146 (2014).

    Article  CAS  Google Scholar 

  22. S.K. Dhoke, T. J.M. Sinha and A. Khanna, J. Coat. Technol. Res., 6, 353 (2009).

    Article  CAS  Google Scholar 

  23. G. Gusmano, G. Montesperelli, M. Rapone, G. Padeletti, A. Cusmà, S. Kaciulis and A. Mezzi, Surf. Coat. Technol., 201, 5822 (2007).

    Article  CAS  Google Scholar 

  24. M. Alexandre and P. Dubois, Mat. Sci. Eng. R., 28, 1 (2000).

    Article  Google Scholar 

  25. D. J. Chaiko and A.A. Leyva, Chem. Mater., 17, 19 (2005).

    Article  Google Scholar 

  26. M. Sabzi, S. Mirabedini, J. Zohuriaan-Mehr and M. Atai, Prog. Org. Coat., 65, 222 (2009).

    Article  CAS  Google Scholar 

  27. M. Gerosa, A. Sacco, A. Scalia, F. Bella, A. Chiodoni, M. Quaglio, E. Tresso and S. Bianco, IEEE J. Photovolt., 6, 498 (2016).

    Article  Google Scholar 

  28. F. Bella, A. Sacco, G. Massaglia, A. Chiodoni, C. F. Pirri and M. Quaglio, Nanoscale., 7, 12010 (2015).

    Article  CAS  Google Scholar 

  29. F. Bella, G. Leftheriotis, G. Griffini, G. Syrrokostas, S. Turri, M. Grätzel and C. Gerbaldi, Adv. Funct. Mater., 26, 1127 (2016).

    Article  CAS  Google Scholar 

  30. P. Im, Y. J. Choi, W. J. Yoon, D. G. Kang, M. Park, D.Y. Kim, C.R. Lee, S. Yang, J. H. Lee, K. Jeong, Sci. Rep., 6, 36472 (2016).

    Article  CAS  Google Scholar 

  31. D. Pintossi, G. Iannaccone, A. Colombo, F. Bella, M. Välimäki, K. L. Väisänen, J. Hast, M. Levi, C. Gerbaldi, C. Dragonetti, S. Turri and G. Griffni, Adv. Electron. Mater., 2, 1600288 (2016).

    Article  Google Scholar 

  32. M. Nakagawa, A. Nakaya, Y. Hoshikawa, S. Ito, N. Hiroshiba and T. Kyotani, ACS Appl. Mater. Interfaces., 8, 30628 (2016).

    Article  CAS  Google Scholar 

  33. B. Ramezanzadeh, M. M. Attar and M. Farzam, Prog. Org. Coat., 72, 410 (2011).

    Article  CAS  Google Scholar 

  34. B. Ramezanzadeh and M. M. Attar, Prog. Org. Coat., 71, 242 (2011).

    Article  CAS  Google Scholar 

  35. Z.M. Huang, Mater. Sci. Technol., 16, 81 (2000).

    Article  CAS  Google Scholar 

  36. B. Ramezanzadeh, M. M. Attar and M. Farzam, J. Therm. Anal. Calorim., 103, 731 (2011).

    Article  CAS  Google Scholar 

  37. B. Ramezanzadeh and M. M. Attar, Mater. Chem. Phys., 130, 1208 (2011).

    Article  CAS  Google Scholar 

  38. B. Ramezanzadeh, M. M. Attar and M. Farzam, Prog. Org. Coat., 72, 410 (2011).

    Article  CAS  Google Scholar 

  39. R. Khan, M.R. Azhar, A. Anis, M. A. Alam, M. Boumaza and S.M. Al-Zahrani, J. Coat. Technol. Res., 13, 159 (2016).

    Article  CAS  Google Scholar 

  40. J. Wu, J. Xie, L. Ling, G. Ma and B. Wang, J. Coat. Technol. Res., 10, 849 (2013).

    Article  CAS  Google Scholar 

  41. J. Choi, S. G. Kim and R. M. Laine, Macromolecules., 37, 99 (2004).

    Article  CAS  Google Scholar 

  42. J.W. Gilman, C. L. Jackson, A. B. Morgan, R. Harris, E. Manias, E. P. Giannelis, M. Wuthenow, D. Hilton and S. H. Phillips, Chem. Mater., 12, 1866 (2000).

    Article  CAS  Google Scholar 

  43. Z. Peng, L. X. Kong and S.D. Li, J. Appl. Polym. Sci., 96, 1436 (2005).

    Article  CAS  Google Scholar 

  44. S.C. Hsu, W.T. Whang, C. H. Hung, P. C. Chiang and Y. N. Hsiao, Macromol. Chem. Phys., 206, 291 (2005).

    Article  CAS  Google Scholar 

  45. S.M. Mirabedini, G. E. Thompson, S. Moradian and J.D. Scantlebury, Prog. Org. Coat., 46, 112 (2003).

    Article  CAS  Google Scholar 

  46. M. Niknahad, S. Moradian and S. M. Mirabedini, Corros. Sci., 52, 1948 (2010).

    Article  CAS  Google Scholar 

  47. G.W. Walter, Corros. Sci., 26, 681 (1986).

    Article  CAS  Google Scholar 

  48. S.M. Mirabedini, M. Behzadnasab and K. Kabiri, Compos. Part A Appl. S., 43, 2095 (2012).

    Article  CAS  Google Scholar 

  49. M. Salmerón Sánchez, J. Molina Mateo, F. J. Romero Colomer and J. L. Gómez Ribelles, Eur. Polym. J., 42, 1378 (2006).

    Article  Google Scholar 

  50. D.K. Chattopadhyay, A. J. Muehlberg and D.C. Webster, Prog. Org. Coat., 63, 405 (2008).

    Article  CAS  Google Scholar 

  51. S.W. Kim, Korean J. Chem. Eng., 25, 1195 (2008).

    Article  CAS  Google Scholar 

  52. S.W. Kim, Korean J. Chem. Eng., 28, 298 (2011).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Center of Excellence for Research in Engineering Materials (CEREM), Advanced Manufacturing Institute (AMI), King Saud University, P. O. Box 800, Riyadh, 11421, Saudi Arabia

    Mohammad Asif Alam & Ubair Abdus Samad

  2. Chemical Engineering Department, King Saud University, P. O. Box 800, Riyadh, 11421, Saudi Arabia

    Rawaiz Khan & Saeed Mohammed Al-Zahrani

  3. Research Centre-College of Science, King Saud University, P. O. Box 2455, Riyadh, 11451, Saudi Arabia

    Manawwer Alam

Authors
  1. Mohammad Asif Alam
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ubair Abdus Samad
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Rawaiz Khan
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Manawwer Alam
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Saeed Mohammed Al-Zahrani
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Manawwer Alam.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Alam, M.A., Samad, U.A., Khan, R. et al. Anti-corrosive performance of epoxy coatings containing various nano-particles for splash zone applications. Korean J. Chem. Eng. 34, 2301–2310 (2017). https://doi.org/10.1007/s11814-017-0114-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-017-0114-1

Keywords

Search

Navigation