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Utillization of automobile shredder residue (ASR) as a reducing agent for the recovery of black copper

  • Environmental Engineering
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Abstract

The physicochemical characteristics of automobile shredder residue (ASR) and its melting slag were investigated: In particular, the applicability of ASR as a reducing agent to the black copper recovery process. ASR is classified into three types after the shredding process: heavy fluff, light fluff and glass and soil. In this study, the portions of heavy fluff, light fluff and glass and soil in the ASR were 89.2 wt%, 8.1 wt% and 2.7 wt%, respectively. Physicochemical analysis revealed that moisture and fixed carbon content were low in heavy and light fluffs, and combustible content was the highest. The higher heating value (HHV) of light fluff was 6,607 kcal/kg, and the HHV of heavy fluff was 5,312 kcal/kg. To sum up, the separation of black copper and discard slag mostly seems to be affected by the melting temperature. Therefore, if basicity and melting temperature are properly controlled, the ASR can be used as a reducing agent in the smelting process of black copper recovery. Moreover, the possibility of black copper recovery from ASR and heavy metal poisoning is evaluated.

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References

  1. G. Mancini, P. Viotti, A. Luciano, M. Raboni and D. Fino, Waste Manage., 34, 2347 (2014).

    Article  CAS  Google Scholar 

  2. K. H. You, Korea Society of Automotive Engineers, 29, 42 (2007).

    Google Scholar 

  3. S. Yoon, S. H. Shim and S. J. Cho, Korea Society of Waste Management, 21, 561 (2004).

    Google Scholar 

  4. I. Vermeulen, J. Van Caneghem, C. Block, J. Baeyens and C. Van-decasteele, Hazard. Mater., 190, 8 (2011).

    Article  CAS  Google Scholar 

  5. H. W. Jeong, J. H. Yun, H. C. Yi and Y. T. Sohn, Korea Society of Automotive Engineers, 34, 32 (2012).

    Google Scholar 

  6. H. T. Joung, K. H. Kim, H. Nam, Y. L. Kim, J. H. Hong, T. W. Yoo, J. H. Park and Y. C. Seo, Korea Society of Waste Management, 20, 415 (2003).

    Google Scholar 

  7. H. C. Lee and W. C Park, Korea Society of Waste Management, 26, 495 (2009).

    Google Scholar 

  8. R. Cossu, S. Fiore, T. Lai, A. Luciano, G. Mancini, B. Ruffino, P. Viotti and M. C. Zanetti, Waste Manage., 34, 1752 (2014).

    Article  CAS  Google Scholar 

  9. H. T. Joung, Y. C. Seo, K. H. Kim, J. H. Hong and T. W. Yoo, Korean J. Chem. Eng., 24, 996 (2007).

    Article  CAS  Google Scholar 

  10. H. T. Joung, A study on the pyrolysis characteristics of Automobile Shredder Residue, Master’s Thesis, Yonsei University, South Korea (2003).

    Google Scholar 

  11. H. T. Joung, A study on the characteristics of byproducts from a pyrolysis/gasification/melting process to recycle shredded polymer wastes from End-of-Life Vehicles, Doctor’s Thesis, Yonsei University, South Korea (2008).

    Google Scholar 

  12. G. Mancini, P. Viotti, A. Luciano and D. Fino, Waste Manage., 34, 448 (2014).

    Article  CAS  Google Scholar 

  13. G. Mancini, R. Tamma and P. Viotti, Waste Manage., 30, 1670 (2010).

    Article  CAS  Google Scholar 

  14. S. Fiore, B. Ruffino and M. C. Zanetti, Waste Manage., 32, 1548 (2012).

    Article  CAS  Google Scholar 

  15. I. H. Hwang, S. Yokono and T. Matsuto, Chemosphere, 71, 879 (2008).

    Article  CAS  Google Scholar 

  16. H. T. Joung, Y. C. Seo, K. H. Kim, J. H. Hong and T. W. Yoo, Korea Society of Waste Management, 22, 175 (2005).

    Google Scholar 

  17. S. J. Cho, Study on gasification and melting characteristics of waste and biomass, Doctor’s thesis. Yonsei University, South Korea (2012).

    Google Scholar 

  18. M. Nourreddine, Hazard. Mater., 139, 481 (2007).

    Article  CAS  Google Scholar 

  19. D. Mirabile, M. I. Pistelli, M. Marchesini, R. Falciani and L. Chiappelli, Waste Manage., 22, 841 (2002).

    Article  CAS  Google Scholar 

  20. M. Zolezzi, C. Nicolella, S. Ferrara, C. Iacobucci and M. Rovatti, Waste Manage., 24, 691 (2004).

    Article  CAS  Google Scholar 

  21. S. Galvagno, F. Fortuna, G. Cornacchia, S. Casu, T. Coppola and V. K. Sharma, Energy Convers. Manage., 42, 573 (2001).

    Article  CAS  Google Scholar 

  22. M. Day, J. D. Cooney and Z. Shen, Anal. Appl. Pyrol., 37, 49 (2001).

    Article  Google Scholar 

  23. R. Rausa and P. Pollesel, Anal. Appl. Pyrol., 40-41, 389 (1997).

    Article  Google Scholar 

  24. C. Roy and A. Chaala, Res. Conserv. Rec., 32, 1 (2001).

    Article  Google Scholar 

  25. M. Kondoh, M. Hamai, M. Yamaguchi and S. Mori, Technical Notes/JSAE Review, 22, 221 (2000).

    Google Scholar 

  26. Korea Automation Company, Republic of Korea, The caloric value of RDF. http://wwwkacrdfcokr (Accessed March 19, 2014).

  27. Q. Guo, X. Zhang, C. Li, X. Liu and J. Li, Hazard. Mater., 209-210, 443 (2012).

    Article  CAS  Google Scholar 

  28. M. R. Kim, J. G. Jang, S. K. Lee, B. Y. Hwang and J. K. Lee, Korean J. Chem. Eng., 27, 1028 (2010).

    Article  CAS  Google Scholar 

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Correspondence to Hang Seok Choi.

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Yang, WS., Lee, J.E., Seo, YC. et al. Utillization of automobile shredder residue (ASR) as a reducing agent for the recovery of black copper. Korean J. Chem. Eng. 33, 1267–1277 (2016). https://doi.org/10.1007/s11814-015-0258-9

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  • DOI: https://doi.org/10.1007/s11814-015-0258-9

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