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Deep extractive desulfurization of oil over 12-molibdophosphoric acid encapsulated in metal-organic frameworks

  • Catalysis, Reaction Engineering
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Abstract

A desulfurization process for model oil and real oil was investigated based on the chemical oxidation of mixed sulfur containing compounds in the presence of nitrogen compounds (indole and quinoline) using hydrogen peroxide as oxidizing agent and dodecamolibdophosphoric acid (H3PMo12O40) encapsulated in a kind of metal-organic framework (HKUST-1) as PMo@HKUST-1. The effect of isopropanol, ethanol and acetonitrile as extractive solvent and 1-ring (toluene, xylene and mesitylene) and 2-ring (naphthalene) aromatic hydrocarbons in desulfurization of model oil was studied. The desulfurization of sulfur-containing compounds was accelerated in the presence of aromatic hydrocarbons. In fact, a higher desulfurization efficiency of the heterogeneous catalyst could be achieved with system containing a polar solvent in contact with an aromatic hydrocarbon. Quinoline had no effect on oxidative desulfurization (ODS) reaction, whereas indole had a slightly negative effect. Presence of aromatic compounds had slightly positive effect on ODS reaction.

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Authors and Affiliations

  1. Faculty of Chemistry, Razi University, Kermanshah, 67149, Iran

    Ezzat Rafiee

  2. Institute of Nano Science and Nano Technology, Razi University, Kermanshah, 67149, Iran

    Ezzat Rafiee & Narges Nobakht

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  1. Ezzat Rafiee
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  2. Narges Nobakht
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Correspondence to Ezzat Rafiee.

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Rafiee, E., Nobakht, N. Deep extractive desulfurization of oil over 12-molibdophosphoric acid encapsulated in metal-organic frameworks. Korean J. Chem. Eng. 33, 132–139 (2016). https://doi.org/10.1007/s11814-015-0109-8

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  • DOI: https://doi.org/10.1007/s11814-015-0109-8

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