Abstract
The mixtures of alkylpyridinium chloride (C n PC, n=14, 16) and Triton X-100 were studied over the entire mole fractions at 298.15 K. For each mixture, CMC was obtained from surface tension measurements. To estimate the interaction parameter values (β), the calculation of the monomer concentrations and the mole fractions of the individual surfactants in the mixed micelles, the CMC data were used by applying the regular solution theory. The obtained results showed that the increase of the chain length of C n PC led to the stronger preferential incorporation of cationic surfactant in mixed micelle. The large values of |ΔGo| confirmed that mixed micelle of C16PC and Triton X-100 was significantly favorable.
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D.E. Mohamed, N.A. Negm and M.R. Mishrif, J. Surf. Deterg., 16, 723 (2013).
M. S. Sheikh, D. A. A. Kabir-ud-Din and A. A. Dar, Colloids Surf., A, 378, 60 (2011).
M. A. Rub, A. M. Asiri, N. Azuma, A. Khan, A.A. P. Khan, S.B. Khan, M.M. Rahman and Kabir-ud-Din, J. Ind. Eng. Chem., 19, 1774 (2013).
P. M. Holland and D. N. Rubingh, J. Phys. Chem., 87, 1984 (1983).
M. Bergström and J. C. Eriksson, Langmuir, 16, 7173 (2000).
M. Bergström, Langmuir, 17, 993 (2001).
A. F. Olea and C. Gamboa, J. Colloid Interface Sci., 257, 321 (2003).
M. J. Rosen, Surfactants and interfacial phenomena, Wiley, New York (1989).
J. Asadoorian and K.B Williams, J. Dental Hygiene, 82, 42 (2008).
C. M. Dejan, M. M. Posa and V. S. Krstonosic, Chemistry Central Journal, 5, 89 (2011).
D.N. Rubingh and K.L. Mittal (Ed.), In Solution Chemistry of Surfactants, 1, 337 (1979).
P. M. Holland, Adv. Colloid Interface Sci., 26, 111 (1986).
H. Maeda, J. Colloid Interface Sci., 172, 98 (1995).
J. H Clint, J. Chem. Soc. Faraday Trans., 71, 1327 (1975).
A. A. Rafati and H. Maleki, J. Mol. Liq., 135, 128 (2007).
K. Motomura and M. Aratono, In Mixed Surfactant Systems, Edited by K. Ogino, M. Abe, Marcel Dekker, New York (1993).
A. Randall Slagle, PhD Thesis, University of Oklahoma, USA (1998).
A. Munster, Statistical Thermodynamics, Springer-Verlag, Berlin (1974).
P.M. Holland, Modeling mixed surfactant systems, ACS Symposium Series; Chapter 2. American Chemical Society, Washington, DC (1992).
M. J. Rosen and X.Y. Hua, J. Colloid Interface Sci., 86, 164 (1982).
M. Bergström and J. C. Eriksson, Langmuir, 16, 7173 (2000).
M. Bergström, Langmuir, 17, 993 (2001).
M. A. Rub, A. M. Asiri, N. Azum and Kabir-ud-Din, J. Ind. Eng. Chem. (2013), DOI:10.1016/j.jiec.2013.09.027.
M. A. Rub, M. S. Sheikh, A. M. Asiri, N. Azum, A. Khan, A. A. P. Khan, S. B. Khan and Kabir-ud-Din, J. Chem. Thermodynamics, 64, 28 (2013).
M. A. Rub, A. M. Asiri, A. Z. Naqvi, M. M. Rahman, S.B. Khan and Kabir-ud-Din, J. Mol. Liq., 177, 19 (2013).
Q. Zhou and M. J. Rosen, Langmuir, 19, 4555 (2003).
M, Otto, Chemometrics: Statistics and computer application in analytical chemistry, Weinheim, WILEY-VCH (2007).
C. Sarmoria, S. Puvvada and D. Blankschtein, Langmuir, 8, 2690 (1992).
D.R. Cox and D.V. Hinkley, Theoretical Statistics, Chapman & Hall, London (1974).
B. M. Razavizadeh, M. Mousavi-Khoshdel, H. Gharibi, R. Behjatmanesh-Ardakani, S. Javadian and B. Sohrabi, J. Colloid Interface Sci., 276, 197 (2004).
R. Palepu, H. Gharibi, D. M. Bloor and E. Wyn-Jones, Langmuir, 9, 110 (1993).
R. Sandeep Patil, N. Buchavzov, E. Careya and C. Stubenrauch, Soft Matter, 4, 840 (2008).
K.D. Danov, S.D. Kralchevska, P.A. Kralchevsky, K. P. Ananthapadmanabhan and A. Lips, Langmuir, 20, 5445 (2004).
S. Ikeda, M. Tsunoda and H. Maeda, J. Colloid Interface Sci., 67, 336 (1987).
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Bagheri, A., Abolhasani, A. Binary mixtures of cationic surfactants with triton X-100 and the studies of physicochemical parameters of the mixed micelles. Korean J. Chem. Eng. 32, 308–315 (2015). https://doi.org/10.1007/s11814-014-0232-y
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DOI: https://doi.org/10.1007/s11814-014-0232-y