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Investigating Chemical Properties and Oxidative Stability of Kernel Oil from Pistacia khinjuk Growing Wild in Iran

  • Original Paper
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Journal of the American Oil Chemists' Society

Abstract

In this study in order to introduce a new vegetable oil, oxidative stability and chemical characteristics of Pistacia khinjuk kernel oil (PKKO) as compared with P. atlantica kernel oil (PAKO) and extra virgin olive oil (EVOO) were investigated. Oxidative stability of studied oils was considered based on the conjugated diene value (CDV), carbonyl value (CV) and oil/oxidative stability index (OSI) through an 8-h thermal process at 170 °C. Also, chemical characteristics [fatty acid composition, unsaponifiable matter (USM), total tocopherols (TT), total phenolics (TP) and total sterols (TS), iodine value, saponification number and waxes] of these oils were analyzed. The ratio of polyunsaturated fatty acids to saturated fatty acids and the oxidizability (Cox) value of PKKO (1.14 and 2.78; respectively) were between those of PAKO (2.37 and 4.23; respectively) and EVOO (1.14 and 2.78; respectively). USM content of the three studied oils was between 1.1 and 1.51 %. TT and TP contents of PKKO (619.4 and 26.6 ppm) were lower than those of PAKO (845.33 and 75.22 ppm) and higher than those of EVOO (365.23 and 19.78 ppm). TS contents of PKKO, PAKO and EVOO were 2,500, 2,150 and 3,800 ppm, respectively. Oxidative stability data indicated that PKKO is the most resilient oil against lipid oxidation, followed by PAKO and EVOO. CDV significantly increased by the lowest speed for PKKO, followed by PAKO and EVOO. Increase of CV and reduction of OSI for PKKO, PAKO and EVOO were 29.2, 128 and 338.7 and 32.8, 67.9 and 79.3 %; respectively.

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Abbreviations

ANOVA:

Analysis of variance

AV:

Acid value

CDV:

Conjugated diene value

Cox:

Calculated oxidizability

CV:

Carbonyl value

EVOO:

Extra-virgin olive oil

FAME:

Fatty acid methyl ester(s)

IV:

Iodine value

MUFA:

Monounsaturated fatty acids

OSI:

Oil/oxidative stability index

PAKO:

Pistacia atlantica kernel oil

PKKO:

P. khinjuk kernel oil

PUFA:

Polyunsaturated fatty acid(s)

PV:

Peroxide value

SFA:

Saturated fatty acid(s)

SN:

Saponification number

TP:

Total phenolics

TS:

Total sterols

TT:

Total tocopherols

USFA:

Unsaturated fatty acid(s)

USM:

Unsaponifiable matter

References

  1. Dunford NT (2015) Oxidative stability of sunflower seed oil. In: Martínez-Force E, Dunford NT, Salas JJ (eds) Sunflower: chemistry, production, processing, and utilization. AOCS Press, Urbana, pp 465–489

    Chapter  Google Scholar 

  2. Frankel EN (1998) Lipid oxidation. The Oily Press Ltd, Buckinghamshire

    Google Scholar 

  3. Durmaz G, Gokmen V (2011) Changes in oxidative stability, antioxidant capacity and phytochemical composition of Pistacia terebinthus oil with roasting. J Food Chem 128:410–414

    Article  CAS  Google Scholar 

  4. Tomaino A, Martorana M, Arcoraci T, Monteleone D, Giovinazzo C, Saija A (2010) Antioxidant activity and phenolic profile of pistachio (Pistacia vera L., variety Bronte) seeds. J Biochim 92:1115–1122

    Article  CAS  Google Scholar 

  5. Farhoosh R, Haddad Khodaparast MH, Sharif A (2009) Bene hull oil as a highly stable and antioxidative vegetable oil. Eur J Lipid Sci Technol 111:1259–1265

    Article  CAS  Google Scholar 

  6. Browiczb K (1988) Chorology of trees and shrubs in south-west Asia and adjacent regions. Polish Scientific, Warszawa-Poznan

    Google Scholar 

  7. Atli HS, Arpaci S (1998) Improvement of rootstocks for irrigated pistachio trees trough h controlled hybridization with some Pistacia species. Annual report, Pistachio Research Institute, Gaziantep, Turkey

  8. Tavakoli J, Haddad Khodaparast MH, Esmaeilzadeh Kenari R, Aminlari M, Sharif A (2013) Introducing Pistacia khinjuk (Kolkhoung) fruit hull oil as a vegetable oil with special chemical composition and unique oxidative stability. J Chem Nat Compd 5:803–810

    Article  Google Scholar 

  9. Farhoosh R, Tavakoli J, Haddad Khodaparast MH (2008) Chemical composition and oxidative stability of kernel oils from two current subspecies of Pistacia atlantica in Iran. J Am Oil Chem Soc 85:723–729

    Article  CAS  Google Scholar 

  10. Fatemi SH, Hammond EG (1980) Analysis of oleate, linoleate and linolenate hydroperoxides in oxidized ester mixtures. J Lipids 15:379–385

    Article  CAS  Google Scholar 

  11. Lozano YF, Mayer CD, Bannon C, Gaydou EC (1993) Unsaponifiable matter, total sterol and tocopherol contents of avocado oil varieties. J Am Oil Chem Soc 70:561–565

    Article  CAS  Google Scholar 

  12. Capannesi C, Palchetti I, Mascini M, Parenti A (2000) Electrochemical sensor and biosensor for polyphenols detection in olive oils. J Food Chem 71:553–562

    Article  CAS  Google Scholar 

  13. Wong ML, Timms RE, Goh EM (1988) Colorimetric determination of total tocopherols in palm oil, olein and stearin. J Am Oil Chem Soc 65:258–261

    Article  CAS  Google Scholar 

  14. Sabir SM, Hayat I, Gardezi SDA (2003) Estimation of sterols in edible fats and oils. Pak J Nutr 2:178–181

    Article  Google Scholar 

  15. Mezouari S, Parkash kochhar S, Schwarz K, Eichner K (2006) Effect of dewaxing pretreatment on composition and stability of rice bran oil: potential antioxidant activity of wax fraction. Eur J Lipid Sci Technol 108:679–686

    Article  CAS  Google Scholar 

  16. AOAC (2005) Official methods of analysis. Association of Official Analytical Chemists, Washington, DC

    Google Scholar 

  17. Shantha NC, Decker EA (1994) Rapid, sensitive, iron-based spectrophotometric methods for determination of peroxide values of food lipids. J Am Oil Chem Soc 77:421–424

    CAS  Google Scholar 

  18. Saguy IS, Shani A, Weinberg P, Garti N (1996) Utilization of jojoba oil for deep-fat frying of foods. LWT Food Sci Technol 29:573–577

    Article  CAS  Google Scholar 

  19. Endo Y, Li CM, Tagiri-Endo M, Fugimoto K (2001) A modified method for the estimation of total carbonyl compounds in heated and frying oils using 2-propanol as a solvent. J Am Oil Chem Soc 10:1021–1024

    Article  Google Scholar 

  20. Shahidi F (2005) Bailey’s industrial oil and fat products, 6th edn. Wiley Interscience, New York

    Book  Google Scholar 

  21. Martini S, Anon MC (2005) Storage of sunflower-seeds: variation on the wax content of the oil. Eur J Lipid Sci Technol 107:74–79

    Article  CAS  Google Scholar 

  22. Ito M (2003) Characterization of natural waxes and their application to cosmetic foundations. Fragr J 31:38–46

    CAS  Google Scholar 

  23. Malecka M (2002) Antioxidant properties of the unsaponifiable matter isolated from tomato seeds, oat grains and wheat germ oil. J Food Chem 79:327–330

    Article  CAS  Google Scholar 

  24. Elmadfa I (1995) Physiological importance of unsaponifiable components in dietary fats. J Fat Sci Technol 97:85–90

    CAS  Google Scholar 

  25. Lagarda MJ, Garcia-Llatas G, Farre R (2006) Analysis of phytosterols in foods. J Pharm Biomed Anal 41:1486–1496

    Article  CAS  Google Scholar 

  26. Clark JP (1996) Tocopherols and sterols from soybeans. J Lipid Technol 8:111–114

    Google Scholar 

  27. Crane S, Aurore G, Joseph H, Mouloungui Z, Bourgeois P (2005) Composition of fatty acids triacylglycerols and unsaponifiable matter in Calophyllum calaba L. oil from Guadeloupe. Phytochemistry 66:1825–1831

    Article  CAS  Google Scholar 

  28. Robards K, Prenzler PD, Tucker G, Swatsing P, Glover W (1999) Phenolic compounds and their role in oxidative processes in fruits. J Food Chem 66:401–436

    Article  CAS  Google Scholar 

  29. Ryan D, Robards K (1998) Phenolic compounds in olives. J Anal 123:31–44

    Article  Google Scholar 

  30. Robards K, Antolovich M (1997) Analytical chemistry of fruit bioflavonoids. J Anal 122:11–34

    Article  Google Scholar 

  31. Gunstone FD (2005) Vegetable oils. In: Shahidi F (ed) Bailey’s industrial oil and fat products. Wiley, New Jersey

    Google Scholar 

  32. Antolovich M, Prenzler PD, Patsalides E, Mcdonald S, Robards K (2002) Methods for testing antioxidant activity. J Anal 127:183–198

    Article  CAS  Google Scholar 

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Correspondence to Javad Tavakoli.

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Tavakoli, J., Hamedani, F. & Haddad Khodaparast, M.H. Investigating Chemical Properties and Oxidative Stability of Kernel Oil from Pistacia khinjuk Growing Wild in Iran. J Am Oil Chem Soc 93, 681–687 (2016). https://doi.org/10.1007/s11746-016-2817-6

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  • DOI: https://doi.org/10.1007/s11746-016-2817-6

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