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Antioxidant Activity of Soybean Oil Containing 4-Vinylsyringol Obtained from Decarboxylated Sinapic Acid

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Journal of the American Oil Chemists' Society

Abstract

4-Vinylsyringol was produced by decarboxylation from sinapic acid. To evaluate the antioxidant activity of 4-vinylsyringol, 500 ppm of 4-vinylsyringol, sinapic acid, or α-tocopherol was added to soybean oil and the oxidation processes were monitored by the peroxide value (PV), the thiobarbituric acid reactive substances value (TBARS) assay, and 1H-NMR spectroscopy. The results obtained by PV and TBARS indicated that soybean oil containing 4-vinylsyringol (SBO-VS) showed the highest oxidative stability. 1H-NMR analysis also showed concurring results. After 19 days of oxidation, the degradation rates of linoleic acid (4.2 %) and linolenic acid (4.4 %) in SBO-VS were significantly lower than those in other oils. Secondary oxidation products (i.e. aldehydes) were undetectable in SBO-VS by 1H NMR, whereas concentrations of such compounds in soybean oils containing α-tocopherol or sinapic acid were 38.0 ± 0.4 and 2.75 ± 0.2 mM oil, respectively. In addition, synergistic antioxidant effect between any two antioxidants was not observed.

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Acknowledgments

This work was carried out with the support of “The Cooperative Research Program for Agriculture Science & Technology Development (Project No.PJ 009164)” Rural Development Administration, Republic of Korea.

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Authors and Affiliations

  1. Department of Food Science and Technology, Chungnam National University, Daejeon, 305-764, Republic of Korea

    Xiang-Yu Wang, Dan Yang, Cai-Hua Jia, Jung-Ah Shin, Soon Taek Hong & Ki-Teak Lee

  2. Department of Food Science and Engineering, Yanbian University, Yanji, China

    Hua Zhang

  3. Bioenergy Crop Research Center, National Institute of Crop Science, Rural Development Administration, Muan, 533-834, Republic of Korea

    Yong-Hwa Lee & Young-Seok Jang

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  1. Xiang-Yu Wang
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  2. Dan Yang
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  3. Hua Zhang
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Correspondence to Ki-Teak Lee.

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Wang, XY., Yang, D., Zhang, H. et al. Antioxidant Activity of Soybean Oil Containing 4-Vinylsyringol Obtained from Decarboxylated Sinapic Acid. J Am Oil Chem Soc 91, 1543–1550 (2014). https://doi.org/10.1007/s11746-014-2492-4

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  • DOI: https://doi.org/10.1007/s11746-014-2492-4

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