Abstract
The effects of amino acids (dl-glycine, dl-alanine, dl-phenylalanine, dl-serine, l-leucine, l-aspartic acid, l-lysine) on the micellization, surface activity, viscometric and aggregation properties of hexadecyl alcohol polyethoxylate (25EO) in aqueous solution were studied. The critical micelle concentration and free energy of micellization were evaluated and discussed. The surface excess concentration, the minimum area per molecule, the surface pressure at the critical micelle concentration and the standard free energy of adsorption were obtained from surface activity studies. On the basis of the determination of the relative viscosities on concentration, the viscosity B-coefficients of the Jones–Dole semiempirical equation were calculated for the premicellar and postmicellar regions. The method of fluorescence quenching was used for determination of the micellar aggregation number of hexadecyl alcohol polyethoxylate (25EO) in aqueous solution in the presence of amino acids. It was found that among studied amino acids serine shows behavior that is different from that of the other neutral amino acids.
Similar content being viewed by others
References
Banpial TS, Singh K, Banipal PK (2007) Volumetric investigation of interaction of acidic/basic amino acids with sodium acetate, sodium propionate and sodium butyrate in aqueous solutions. J Solut Chem 36:1635–1667
Yan Z, Wang J, Kong W, Lu J (2004) Effect of temperature on volumetric and viscosity properties of some α-amino acids in aqueous calcium chloride solutions. Fluid Phase Equilib 215:143–150
Badarayani R, Kumar A (2003) Effect of temperature on the volumetric properties of the l-alanine (1) + KCl (2) + H2O (3) system. J Chem Eng Data 48:664–668
Badarayani R, Kumar A (2004) Effect of tetra-n-alkylammonium bromide on the volumetric properties of glycine, l-alanine and glycylglycine at T = 298.15 K. J Chem Thermodyn 36:49–58
Badarayani R, Kumar A (2004) Viscometric study of glycine, l-alanine, glycylglycine in aqueous tetra-n-alkylammonium bromide Solutions at 298.15 K. J Chem Thermodyn 36:983–991
Singh SK, Kundu A, Kishore N (2004) Interaction of some amino acids and glycine peptides with aqueous sodium dodecyl sulfate and cetyltrimethylammonium bromide at T = 298.15 K: a volumetric approach. J Chem Thermodyn 36:7–16
Carnero-Ruiz C, Hierrezuelo JM, Molina-Bolívar JA (2008) Effect of glycine on the surface activity and micellar properties of N-decanoyl-N-methylglucamide. Colloid Polym Sci 286:1281–1289
Adamson AW (1976) Physical chemistry of surfaces. Wiley, New York
Luethi P, Luisi PL (1984) Enzymatic synthesis of hydrocarbon-soluble peptides with reverse micelles. J Am Chem Soc 106:7285–7286
Touitou E, Levi-Schaffer F, Dayan N, Alhaiquem F, Riccieri F (1994) Modulation of caffeine skin delivery by carrier design: liposomes versus permeation enhancers. Int J Pharm 103:131–136
Jansen J, Treiner C, Vaution C, Puisieux F (1994) Surface modification of alumina particles by nonionic surfactants: adsorption of steroids, barbiturates and pilocarpine. Int J Pharm 103:19–26
Chen J, Shimura S, Kirimura K, Usami S (1994) Lipase production from hydrocarbons by Trichosporon fermentans WU-C12 in the presence of surfactants. Biosci Biotechnol Biochem 58:773–775
Forney CE, Glatz CE (1995) Extraction of charged fusion proteins in reversed micelles: comparison between different surfactant systems. Biotechnol Prog 11:260–264
Rosen MJ (2004) Surfactants and interfacial phenomena, 3rd edn. Wiley, New York
Shivaji SK, Hassan PA, Rakshit AK (2007) Surface activity and association behavior of nonaoxyethylene n-Dodecylether in aquo amino acid medium: tensiometry, small-angle neutron scattering, dynamic light scattering and viscosity studies. Colloid Surf A 308:100–110
Dash U, Meher J, Mirsa PK (2013) Organization of amphiphiles, Part XII: studies on the interaction of glycine with aqueous micelles of polyoxyethylated nonylphenols. J Mol Liq 177:317–324
Ali A, Tariq M, Patel R, Ittoo FA (2008) Interaction of glycine with cationic, anionic, and nonionic surfactants at different temperatures: a volumetric, viscometric, refractive index, conductometric, and fluorescence probe study. Colloids Polym Sci 286:183–190
Maltesh C, Somasundaran P (1992) Aggregation behavior of octyl-β-thioglucopyranoside in the presence of glycine. Colloids Surf A 69:167–172
Rakshit AK, Sharma B (2003) The effect of amino acids on the surface and thermodynamic properties of poly[oxyethelene(10)] lauryl ether in aqueous solution. Colloid Polym Sci 281:45–51
Nevolin FV (1966) Methods of surfactants purification. Chem J 11:445–448 (in Russian)
Vardanyan AH, Aghaganyan AE, Avetisova GE, Melqonyan LH, Chakhalyan AKh, Sagiyan AS (2008) “The method of synthesis of amino acids”. Patent of RA, No 2239, (in Armenian)
Turro NJ, Yekta A (1978) Luminescent probes for detergent solutions. A simple procedure for determination of the mean aggregation number of micelles. J Am Chem Soc 100:5951–5953
Pandey S, Acree WE Jr, Fetzer JC (1997) Cetylpyridinium chloride micelles as a selective fluorescence quenching solvent media for discriminating between alternant versus non-alternant polycyclic aromatic hydrocarbons. Talanta 45:39–45
Tringali AE, Kim SK, Brenner HC (1999) ODMR and fluorescence studied of pyrene solubilized in anionic and cationic micelles. J Lumin 81:85–100
Harutyunyan LR, Lachinyan ML, Harutyunyan RS (2013) Effect of ascorbic acid on the colloidal and micellar properties of anionic, cationic and nonionic surfactants: conductivity, volumetric, viscometric and fluorescence study. J Chem Eng Data 58:2998–3008
Zana R (1996) Critical micellization concentration of surfactants in aqueous solutions and free energy of micellization. Langmuir 12:1208–1211
Hoeiland HKS, Blokhus AM (2009) Handbook of Surface and Colloid Chemistry, 3rd ed., Taylor and Frances Group LLC London
Nagarajan R, Wang C (2000) Theory of surfactant aggregation in water/ethylene glycol mixed solvents. Langmuir 16:5242–5251
Das S, Mondal S, Ghosh S (2013) Physicochemical studies on the micellization of cationic, anionic and nonionic surfactants in water-polar organic solvent mixtures. J Chem Eng Data 58:2586–2595
Sahoo L, Mirsa PK, Somasundaran P (2002) Organization of amphiphiles, Part-II—surface activity of polyoxyethylated alkyl phenols at air-water interface. Indian J Chem 41A:1402–1405
Mirsa PK, Panigrahi S, Dash U, Mondal AB (2010) Organization of amphiphiles. Part XI: physico-chemical aspects of mixed micellization involving normal conventional surfactant and a non-ionic gemini surfactant. J Colloid Interface Sci 345:392–401
Myers D (1992) Surfactants science and technology, 2nd edn. VCH, New York
Dash U, Mirsa PK (2011) Organization of amphiphiles: XII. Evidence in favor of formation of hydrophobic complexes in aqueous solution. J Colloid Interface Sci 357:407–418
Yuan HZ, Zhao S, Cheng GZ, Zhang L, Miao XJ, Mao SZ, You JY, Shen LF, Du YR (2001) Mixed micelles of Triton X-100 and cetyl trimethylammonium bromide in aqueous solution studied by 1H NMR. J Phys Chem B 105:4611–4615
Makoto I, Yasushi M, Hiromo K (1997) Effect of hydrophobicity of amino acids on the structure of water. J Phys Chem B 101:7022–7026
Harutyunyan NG, Harutyunyan LR, Harutyunyan RS (2010) Volumetric properties of amino acids in aqueous solution of nonionic surfactant. Thermochim Acta 498:124–127
Jones G, Dole M (1929) The viscosity of aqueous solutions of strong electrolytes with special reference to barium chloride. J Am Chem Soc 51:2950–2960
Falkenhagen H, Dole M (1992) Die innere Reibung von Elektrolytischen und ihre Deutung nach der Debeschen Theorie. Z Physik 30:611–622
Erdey-Gruz T (1974) Transport phenomena in aqueous solutions. Akademiai Kiado, Budapest
Feakins D, Freemantle DJ, Lawrence KG (1974) Transition state treatment of the relative viscosity of electrolytic solutions. Applications to aqueous, non-aqueous and methanol + water systems. J Am Chem Soc Faraday Trans 70:795–806
D’Errico G, Ciccarelli D, Ortona D (2005) Effect of glycerol on micelle formation by ionic and nonionic surfactants at 25 degree C. J Colloid Interface Sci 286:747–754
Tanford C (1980) The hydrophobic effect. Wiley, New York
Das D, Ismail K (2008) Aggregation and adsorption properties of sodium dodecyl sulfate in water-acetamide mixtures. J Colloid Interface Sci 327:198–203
Israelachvili JN (1991) Intermolecular and surface force, 2nd edn. Academic Press, London, pp 370–378
Author information
Authors and Affiliations
Corresponding author
About this article
Cite this article
Harutyunyan, L.R. Effect of Amino Acids on Micellization, Surface Activity and Micellar Properties of Nonionic Surfactant Hexadecyl Alcohol Ethoxylate (25EO) in Aqueous Solutions. J Surfact Deterg 18, 73–81 (2015). https://doi.org/10.1007/s11743-014-1609-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11743-014-1609-y