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Spray synthesis of rapid recovery ZnO/polyaniline film ammonia sensor at room temperature

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Abstract

As an excellent room temperature sensing material, polyaniline (PANI) needs to be further investigated in the field of high sensitivity and sustainable gas sensors due to its long recovery time and difficulty to complete recovery. The ZnO/PANI film with p–n heterogeneous energy levels have successfully prepared by spraying ZnO nanorod synthesized by hydrothermal method on the PANI film rapidly synthesized at the gas—liquid interface. The presence of p–n heterogeneous energy levels enables the ZnO/PANI film to detect 0.1–100 ppm (1 ppm = 10−6) NH3 at room temperature with the response value to 100 ppm NH3 doubled (12.96) and the recovery time shortened to 1/5 (31.2 s). The ability of high response and fast recovery makes the ZnO/PANI film to be able to detect NH3 at room temperature continuously. It provides a new idea for PANI to prepare sustainable room temperature sensor and promotes the development of room temperature sensor in public safety.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant Nos. 21771060 and 61271126), the International Science & Technology Cooperation Program of China (Grant No. 2016YFE0115100), the Program for Science and Technology Project of Heilongjiang Province (Grant No. JQ2021B002), the Heilongjiang Provincial Natural Science Foundation of China (Grant No. 2019LH0320), the Reform and Development Fund Project of Local University supported by the Central Government, Heilongjiang Touyan Innovation Team Program.

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Authors and Affiliations

  1. Key Laboratory of Functional Inorganic Material Chemistry, School of Chemistry and Materials Science, Heilongjiang University, Harbin, 150080, China

    Yingze Bai, Xin Dong, Chuanyu Guo, Yingming Xu, Bin Wang & Xiaoli Cheng

  2. State Key Laboratory of Optoelectronic Materials and Technologies, Key Laboratory for Polymeric Composite and Functional Materials, School of Chemistry, Sun Yat-sen University, Guangzhou, 510275, China

    Xin Dong

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  1. Yingze Bai
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  2. Xin Dong
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  3. Chuanyu Guo
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  4. Yingming Xu
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  5. Bin Wang
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  6. Xiaoli Cheng
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Correspondence to Xin Dong, Bin Wang or Xiaoli Cheng.

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Bai, Y., Dong, X., Guo, C. et al. Spray synthesis of rapid recovery ZnO/polyaniline film ammonia sensor at room temperature. Front. Mater. Sci. 16, 220620 (2022). https://doi.org/10.1007/s11706-022-0620-x

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