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Hydrophobic organic coating based water-solid TENG for water-flow energy collection and self-powered cathodic protection

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Abstract

Water-solid triboelectric nanogenerators (TENGs), as new energy collection devices, have attracted increasing attention in ocean energy harvesting and self-powered sensing. Polyacrylic acid (PAA) coating, usually used on the surface of marine equipment, has the property of anti-aging and anti-wear but limits triboelectrical output when used with TENGs. In this paper, polyacrylic acid coating was modified with fluorinated polyacrylate resin (F-PAA) to increase its triboelectrical output, by 6 times, and also to increase its anti-corrosion property. In addition, the corrosion resistance property can be further enhanced by cathodic protection using the electrical output generated by the water-flow triboelectrical energy transfer process. Given their easy fabrication, water-flow energy harvesting, and corrosion resistance, PAA/F-PAA coating-based TENGs have promising applications in river and ocean energy collection and corrosion protection.

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References

  1. Wen Z, Guo H, Zi Y, et al. Harvesting broad frequency band blue energy by a triboelectric-electromagnetic hybrid nanogenerator. ACS Nano, 2016, 10(7): 6526–6534

    Article  CAS  Google Scholar 

  2. Feng Y, Zheng Y, Zhang G, et al. A new protocol toward high output TENG with polyimide as charge storage layer. Nano Energy, 2017, 38: 467–476

    Article  CAS  Google Scholar 

  3. Zheng L, Cheng G, Chen J, et al. A hybridized power panel to simultaneously generate electricity from sunlight, raindrops, and wind around the clock. Advanced Energy Materials, 2015, 5(21): 1501152

    Article  Google Scholar 

  4. Yun B K, Kim H S, Ko Y J, et al. Interdigital electrode based triboelectric nanogenerator for effective energy harvesting from water. Nano Energy, 2017, 36: 233–240

    Article  CAS  Google Scholar 

  5. Tang N, Zheng Y, Yuan M, et al. High-performance polyimide-based water-solid triboelectric nanogenerator for hydropower harvesting. ACS Applied Materials & Interfaces, 2021, 13(27): 32106–32114

    Article  CAS  Google Scholar 

  6. Zhang Q, Jiang C M, Li X J, et al. Highly efficient raindrop energy-based triboelectric nanogenerator for self-powered intelligent greenhouse. ACS Nano, 2021, 15(7): 12314–12323

    Article  CAS  Google Scholar 

  7. Niu S, Wang X, Yi F, et al. A universal self-charging system driven by random biomechanical energy for sustainable operation of mobile electronics. Nature Communications, 2015, 6(1): 8975

    Article  CAS  Google Scholar 

  8. Lin Z H, Cheng G, Lee S, et al. Harvesting water drop energy by a sequential contact-electrification and electrostatic-induction process. Advanced Materials, 2014, 26(27): 4690–4696

    Article  CAS  Google Scholar 

  9. Zhao Z, Pu X, Du C, et al. Freestanding flag-type triboelectric nanogenerator for harvesting high-altitude wind energy from arbitrary directions. ACS Nano, 2016, 10(2): 1780–1787

    Article  CAS  Google Scholar 

  10. Zhang H, Yang Y, Zhong X, et al. Single-electrode-based rotating triboelectric nanogenerator for harvesting energy from tires. ACS Nano, 2014, 8(1): 680–689

    Article  CAS  Google Scholar 

  11. Zhong J, Zhang Y, Zhong Q, et al. Fiber-based generator for wearable electronics and mobile medication. ACS Nano, 2014, 8 (6): 6273–6280

    Article  CAS  Google Scholar 

  12. Zhu G, Zhou Y S, Bai P, et al. A shape-adaptive thin-film-based approach for 50% high-efficiency energy generation through micro-grating sliding electrification. Advanced Materials, 2014, 26(23): 3788–3796

    Article  CAS  Google Scholar 

  13. Zhu G, Su Y, Bai P, et al. Harvesting water wave energy by asymmetric screening of electrostatic charges on a nanostructured hydrophobic thin-film surface. ACS Nano, 2014, 8(6): 6031–6037

    Article  CAS  Google Scholar 

  14. Qin Y, Wang X, Wang Z L. Microfibre-nanowire hybrid structure for energy scavenging. Nature, 2008, 451(7180): 809–813

    Article  CAS  Google Scholar 

  15. Yang Y, Zhang H L, Wang Z L. Direct-current triboelectric generator. Advanced Functional Materials, 2014, 24(24): 3745–3750

    Article  CAS  Google Scholar 

  16. Lee K Y, Yoon H J, Jiang T, et al. Fully packaged self-powered triboelectric pressure sensor using hemispheres-array. Advanced Energy Materials, 2016, 6(11): 1502566

    Article  Google Scholar 

  17. Cheng G, Lin Z H, Du Z L, et al. Simultaneously harvesting electrostatic and mechanical energies from flowing water by a hybridized triboelectric nanogenerator. ACS Nano, 2014, 8(2): 1932–1939

    Article  CAS  Google Scholar 

  18. Henriques J C C, Gomes R P F, Gato L M C, et al. Testing and control of a power take-off system for an oscillating-water-column wave energy converter. Renewable Energy, 2016, 85: 714–724

    Article  Google Scholar 

  19. Bailey H, Robertson B R D, Buckham B J. Wave-to-wire simulation of a floating oscillating water column wave energy converter. Ocean Engineering, 2016, 125: 248–260

    Article  Google Scholar 

  20. Sheng W, Lewis T. Energy conversion: A comparison of fix- and self-referenced wave energy converters. Energies, 2016, 9(12): 1056

    Article  Google Scholar 

  21. Hou B, Li X, Ma X, et al. The cost of corrosion in China. NPJ Materials Degradation, 2017, 1(1): 4

    Article  Google Scholar 

  22. Qiang Y, Guo L, Li H, et al. Fabrication of environmentally friendly Losartan potassium film for corrosion inhibition of mild steel in HCl medium. Chemical Engineering Journal, 2021, 406: 126863

    Article  CAS  Google Scholar 

  23. Patrick J F, Robb M J, Sottos N R, et al. Polymers with autonomous life-cycle control. Nature, 2016, 540(7633): 363–370

    Article  CAS  Google Scholar 

  24. Zhou M J, Zhang N, Zhang L, et al. Photocathodic protection properties of NiP/TiO2 bilayer coatings by a combined electroless plating and sol-gel method. Materials and Corrosion-Werkstoffe und Korrosion, 2012, 63(8): 703–706

    Article  CAS  Google Scholar 

  25. Xiao K, Dong C F, Li X G, et al. Corrosion products and formation mechanism during initial stage of atmospheric corrosion of carbon steel. Journal of Iron and Steel Research International, 2008, 15 (5): 42–48

    Article  CAS  Google Scholar 

  26. Zhao L, Liu Q, Gao R, et al. One-step method for the fabrication of superhydrophobic surface on magnesium alloy and its corrosion protection, antifouling performance. Corrosion Science, 2014, 80: 177–183

    Article  CAS  Google Scholar 

  27. Li H, Wang X T, Liu Y, et al. Ag and SnO2 co-sensitized TiO2 photoanodes for protection of 304SS under visible light. Corrosion Science, 2014, 82: 145–153

    Article  CAS  Google Scholar 

  28. Christodoulou C, Glass G, Webb J, et al. Assessing the long term benefits of impressed current cathodic protection. Corrosion Science, 2010, 52(8): 2671–2679

    Article  CAS  Google Scholar 

  29. Cui S W, Yin X Y, Yu Q L, et al. Polypyrrole nanowire/TiO2 nanotube nanocomposites as photoanodes for photocathodic protection of Ti substrate and 304 stainless steel under visible light. Corrosion Science, 2015, 98: 471–477

    Article  CAS  Google Scholar 

  30. Cui S, Zheng Y, Liang J, et al. Conducting polymer PPy nanowire-based triboelectric nanogenerator and its application for self-powered electrochemical cathodic protection. Chemical Science, 2016, 7(10): 6477–6483

    Article  CAS  Google Scholar 

  31. Zhang H, Zhang S, Yao G, et al. Simultaneously harvesting thermal and mechanical energies based on flexible hybrid nanogenerator for self-powered cathodic protection. ACS Applied Materials & Interfaces, 2015, 7(51): 28142–28147

    Article  CAS  Google Scholar 

  32. Guo W X, Li X Y, Chen M X, et al. Electrochemical cathodic protection powered by triboelectric nanogenerator. Advanced Functional Materials, 2014, 24(42): 6691–6699

    Article  CAS  Google Scholar 

  33. Cui S W, Zheng Y B, Liang J, et al. Triboelectrification based on double-layered polyaniline nanofibers for self-powered cathodic protection driven by wind. Nano Research, 2018, 11(4): 1873–1882

    Article  CAS  Google Scholar 

  34. Zhu H R, Tang W, Gao C Z, et al. Self-powered metal surface anticorrosion protection using energy harvested from rain drops and wind. Nano Energy, 2015, 14: 193–200

    Article  CAS  Google Scholar 

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Acknowledgements

Thanks for the financial support of the Program for Taishan Scholars of Shandong Province (No. ts20190965), the National Key Research and Development Program of China (2020YFF0304600), the Key Research Program of the Chinese Academy of Sciences (Grant No. XDPB24), the National Natural Science Foundation of China (Grant No. 51905518), and the Innovation Leading Talents Program of Qingdao (19-3-2-23-zhc) in China.

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Correspondence to Ying Liu or Daoai Wang.

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Liu, Y., Sun, G., Liu, Y. et al. Hydrophobic organic coating based water-solid TENG for water-flow energy collection and self-powered cathodic protection. Front. Mater. Sci. 15, 601–610 (2021). https://doi.org/10.1007/s11706-021-0575-3

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  • DOI: https://doi.org/10.1007/s11706-021-0575-3

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