Abstract
In the present study, an analytical method was developed for the sensitive determination of gold at trace levels by a slotted quartz tube flame atomic absorption spectrometry (SQT-FAAS) system after magnetic nanoparticle-assisted solid-phase microextraction (MNP-SPME). Amidosulfonic acid (ASA)-coated magnetic nanoparticles were used as adsorbent material in the extraction experiments. Parameters affecting the extraction efficiency of gold, including amount of magnetic nanoparticles, pH/volume of buffer solution, mixing type/period, volume of eluent and volume of sample were optimized with the univariate optimization approach to achieve the highest extraction efficiency. A neodymium magnet was used to separate the analyte-adsorbed MNPs from the liquid phase. Under the optimum experimental conditions, the limit of detection (LOD) and limit of quantitation (LOQ) values were found to be 0.3 and 1.1 µg L−1, respectively. In order to investigate the matrix effects on the proposed method, spike recovery experiments were carried out in gold coating wastewater samples. Using the matrix matching calibration strategy, percent recoveries were obtained between 99 and 105% with low percent relative standard deviations. The detection power of traditional FAAS system was improved by about 162-fold; thanks to ASA-MNP-SPME-SQT-FAAS method. All experimental results of the study demonstrated the applicability of the method for the determination of trace levels of gold in complex matrices with high accuracy and precision.
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References
Afzali D, Mostafavi A, Mirzaei M (2010) Preconcentration of gold ions from water samples by modified organo-nanoclay sorbent prior to flame atomic absorption spectrometry determination. J Hazard Mater 181:957–961. https://doi.org/10.1016/j.jhazmat.2010.05.106
Akkaya E, Aylin Kasa N, Çetin G, Bakirdere S (2017) A new method for the determination of cadmium at ultratrace levels using slotted quartz tube-flame atomic absorption spectrometry after preconcentration with stearic acid coated magnetite nanoparticles. J Anal at Spectrom 32:2433–2438. https://doi.org/10.1039/C7JA00303J
Bakirdere S, Aydin F, Bakirdere EG, Titretir S, Akdeniz İ, Aydin I, Yildirim E, Arslan Y (2011) From mg/kg to pg/kg levels: A story of trace element determination: a review. Appl Spectrosc Rev 46:38–66. https://doi.org/10.1080/05704928.2010.520179
Bodur S, Erarpat S, Bakırdere S (2020) Fe3O4/reduced graphene oxide nanocomposites based dispersive solid phase microextraction for trace determination of profenofos in white rice flour samples. J Food Compos Anal 91:103516. https://doi.org/10.1016/j.jfca.2020.103516
Choi J-W, Song M-H, Bediako JK, Yun Y-S (2020) Sequential recovery of gold and copper from bioleached wastewater using ion exchange resins. Environ Pollut 266:115167. https://doi.org/10.1016/j.envpol.2020.115167
Corti CW, Holliday RJ, Thompson DT (2002) Developing new industrial applications for gold: gold nanotechnology. Gold Bull 35:111–117. https://doi.org/10.1007/BF03214852
Dykman LA, Khlebtsov NG (2011) Gold nanoparticles in biology and medicine: recent advances and prospects. Acta Naturae 3:34–55
El-Naggar W, Lasheen T, Nouh E-S, Ghonaim A (2010) Cloud point extraction and preconcentration of gold in geological matrices prior to flame atomic absorption determination. Open Chem 8:34–40. https://doi.org/10.2478/s11532-009-0093-0
Elçi L, Hol A, Arslan Kartal A, Akdogan A, Elçi A, Arslan T (2015) Ion pair-dispersive liquid-liquid microextraction coupled to microsample injection system-flame atomic absorption spectrometry for determination of gold at trace level in real samples. Acta Chim Slov 62(1):196–203. https://doi.org/10.17344/acsi.2014.897
Elshahawi M, Bashammakh A, Bahaffi S (2007) Chemical speciation and recovery of gold(I, III) from wastewater and silver by liquid–liquid extraction with the ion-pair reagent amiloride mono hydrochloride and AAS determination. Talanta 72:1494–1499. https://doi.org/10.1016/j.talanta.2007.01.057
Garcia JC, Burleigh TD (2013) ECS classics: the beginnings of gold electroplating. Interface Mag 22:36–38. https://doi.org/10.1149/2.F02132if
Han YL, Wu JH, Cheng CL, Nagarajan D, Lee CR, Li YH, Lo YC, Chang JS (2017) Recovery of gold from industrial wastewater by extracellular proteins obtained from a thermophilic bacterium Tepidimonas fonticaldi AT-A2. Bioresour Technol 239:160–170. https://doi.org/10.1016/j.biortech.2017.05.038
Karimi M, Amani V, Aboufazeli F, Lotfi Zadeh Zhad HR, Sadeghi O, Najafi E (2013) Flame atomic absorption determination of gold ion in aqueous samples after preconcentration using 9-acridinylamine functionalized γ -alumina nanoparticles. J Chem 2013:1–6. https://doi.org/10.1155/2013/142845
Karlıdağ NE, Toprak M, Tekin Z, Bakırdere S (2020) Zirconium nanoparticles based ligandless dispersive solid phase extraction for the determination of antimony in bergamot and mint tea samples by slotted quartz tube-flame atomic absorption spectrophotometry. J Food Compos Anal 92:103583. https://doi.org/10.1016/j.jfca.2020.103583
Kaykhaii M, Noorinejad S (2014) Salt saturated single drop microextraction of gold from water samples and its determination by graphite furnace atomic absorption spectrometry. J Anal at Spectrom 29:875. https://doi.org/10.1039/c4ja00005f
Kazemi E, Dadfarnia S, Haji Shabani AM (2015) Dispersive solid phase microextraction with magnetic graphene oxide as the sorbent for separation and preconcentration of ultra-trace amounts of gold ions. Talanta 141:273–278. https://doi.org/10.1016/j.talanta.2015.04.024
Khezeli T, Daneshfar A (2017) Development of dispersive micro-solid phase extraction based on micro and nano sorbents. TrAC - Trends Anal Chem 89:99–118
Liu Y, Wang Z, Xue D, Yang Y, Li W, Cheng H, Patten C, Wan B (2020) An improved analytical protocol for the determination of sub-nanogram gold in 1–2 g rock samples using GFAAS after polyurethane foam pretreatment. At Spectrosc 41:131–140. https://doi.org/10.46770/AS.2020.03.006
Manzoori JL, Abdolmohammad-Zadeh H, Amjadi M (2007) Simplified cloud point extraction for the preconcentration of ultra-trace amounts of gold prior to determination by electrothermal atomic absorption spectrometry. Microchim Acta 159:71–78. https://doi.org/10.1007/s00604-006-0727-2
Marín-Luna M, Nieto Faza O, Silva López C (2019) Gold-catalyzed homogeneous (Cyclo)isomerization reactions. Front Chem 7:296. https://doi.org/10.3389/fchem.2019.00296
Medveď J, Bujdoš M, Matúš P, Kubová J (2004) Determination of trace amounts of gold in acid-attacked environmental samples by atomic absorption spectrometry with electrothermal atomization after preconcentration. Anal Bioanal Chem 379:60–65. https://doi.org/10.1007/s00216-004-2538-9
Öner M, Bodur S, Demir C, Yazıcı E, Erarpat S, Bakırdere S (2021) An effective and rapid magnetic nanoparticle based dispersive solid phase extraction method for the extraction and preconcentration of cadmium from edible oil samples before ICP OES measurement. J Food Compos Anal 101:103978. https://doi.org/10.1016/j.jfca.2021.103978
Ott I (2009) On the medicinal chemistry of gold complexes as anticancer drugs. Coord Chem Rev 253:1670–1681
Özzeybek G, Erarpat S, Chormey DS, Fırat M, Büyükpınar Ç, Turak F, Bakırdere S (2017) Sensitive determination of copper in water samples using dispersive liquid-liquid microextraction-slotted quartz tube-flame atomic absorption spectrometry. Microchem J 132:406–410. https://doi.org/10.1016/j.microc.2017.02.031
Sabermahani F, Taher MA, Bahrami H (2016) Separation and preconcentration of trace amounts of gold from water samples prior to determination by flame atomic absorption spectrometry. Arab J Chem 9:S1700–S1705. https://doi.org/10.1016/j.arabjc.2012.04.053
Tao D, Guo W, Xie W, Jin L, Guo Q, Hu S (2017) Rapid and accurate determination of gold in geological materials by an improved ICP-MS method. Microchem J 135:221–225. https://doi.org/10.1016/j.microc.2017.09.014
Tavakoli L, Yamini Y, Ebrahimzadeh H, Nezhadali A, Shariati S, Nourmohammadian F (2008) Development of cloud point extraction for simultaneous extraction and determination of gold and palladium using ICP-OES. J Hazard Mater 152:737–743. https://doi.org/10.1016/j.jhazmat.2007.07.039
Terzioğlu D, Fırat M, Chormey DS, Bakırdere S (2020) Determination of trace amounts of gold in electroplating rinsing bath by slotted quartz tube flame atomic absorption spectrometry with matrix matching calibration strategy after preconcentration with vortex assisted dispersive liquid-liquid microextractio. Anal Lett 53:2191–2201. https://doi.org/10.1080/00032719.2020.1732998
Tuzen M, Saygi KO, Soylak M (2008) Novel solid phase extraction procedure for gold(III) on Dowex M 4195 prior to its flame atomic absorption spectrometric determination. J Hazard Mater 156:591–595. https://doi.org/10.1016/j.jhazmat.2007.12.062
Yılmaz Ö, Durak BY, Tekin Z, Koçoğlu ES, Bakırdere S (2020) Accurate and precise determination of gold in plating bath solution: deep eutectic solvent based liquid phase microextraction – slotted quartz tube – flame atomic absorption spectrometry. Anal Lett 53:165–173. https://doi.org/10.1080/00032719.2019.1641718
Zaman BT, Erulaş AF, Chormey DS, Bakirdere S (2020) Combination of stearic acid coated magnetic nanoparticle based sonication assisted dispersive solid phase extraction and slotted quartz tube-flame atomic absorption spectrophotometry for the accurate and sensitive determination of lead in red pepper sampl. Food Chem 303:125396. https://doi.org/10.1016/j.foodchem.2019.125396
Zari N, Hassan J, Tabar-Heydar K, Ahmadi SH (2020) Ion-association dispersive liquid–liquid microextraction of trace amount of gold in water samples and ore using Aliquat 336 prior to inductivity coupled plasma atomic emission spectrometry determination. J Ind Eng Chem 86:47–52. https://doi.org/10.1016/j.jiec.2017.01.038
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This study is a chapter of author’s doctoral thesis for CoHE 100/2000 priority fields (100/2000 YÖK Doktora Bursu).
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Serbest, H., Bakırdere, S. & Keyf, S. Determination of gold at trace levels in gold plating wastewater samples by vortex-assisted amidosulfonic acid-coated magnetic nanoparticle-based solid-phase microextraction method prior to slotted quartz tube flame atomic absorption spectrometric measurements. Chem. Pap. 76, 3437–3445 (2022). https://doi.org/10.1007/s11696-022-02089-0
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DOI: https://doi.org/10.1007/s11696-022-02089-0