Skip to main content
Log in

The 1300 °C Isothermal Section in the Al2O3-Y2O3-Nb2O5 System

  • Published:
Journal of Phase Equilibria and Diffusion Aims and scope Submit manuscript

Abstract

Phase stability in the Al2O3-Nb2O5-Y2O3 ceramic system at 1300 °C was experimentally investigated. Disks samples fabricated from homogenized powders were uniaxially pressed at room temperature and heat treated at 1300 °C for 222 hours under laboratory atmosphere to achieve thermodynamic equilibrium. As results, the microstructures of the heat-treated samples did not exhibit pseudo-ternary phases and the phase relations confirmed nine three-phase fields in the proposed isothermal section at 1300 °C.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. O.F. Lopes, V.R. De Mendonça, F.B.F. Silva, E.C. Paris, and C. Ribeiro, Niobium Oxides: An Overview of the Synthesis of Nb2O5 and its Application in Heterogeneous Photocatalysis, Quim. Nova., 2015, 38, p 106–117. https://doi.org/10.5935/0100-4042.20140280

    Article  Google Scholar 

  2. X. Zhang, J.E. Zhou, Y. Jiang, C. Wu, and C. Lin, Preparation and Characterization of Nb2O5-Al2O3 System Ceramics with Different Al2O3 Additions, Key Eng. Mater., 2012, 544, p 60–63. https://doi.org/10.4028/www.scientific.net/KEM.544.60

    Article  Google Scholar 

  3. W.N. Dos-Santos, P.I. Paulin-Filho, and R. Taylor, Effect of Addition of Niobium Oxide on the Thermal Conductivity of Alumina, J. Eur. Ceram. Soc., 1998, 18, p 807–811. https://doi.org/10.1016/s0955-2219(98)80010-1

    Article  Google Scholar 

  4. R.F. Cabral, L.H.L. Louro, M.H. Prado da Silva, J.B. Campos, and E.S. Lima, Synthesis and Characterization of Al2O3 -YAG Composite and Al2O3 -YAG and Al2O3 with Nb2O5 Additives, Cerâmica, 2012, 58, p 14–19. https://doi.org/10.1590/s0366-69132012000100004

    Article  Google Scholar 

  5. O. Fabrichnaya, T. Ludwig, and A. Navrotsky, Phase Equilibria and Thermodynamics in the Y2O3-Al2O3-SiO2 System, Z. Metallkd., 2001, 92, p 1083–1097.

    Google Scholar 

  6. V. Swamy, H.J. Seifert, and F. Aldinger, Thermodynamic Properties of Y2O3 Phases and the Yttrium–Oxygen Phase Diagram, J. Alloys Compd., 1998, 269, p 201–207.

    Article  Google Scholar 

  7. O. Fabrichnaya, and F. Aldinger, Assessment of Thermodynamic Parameters in the System ZrO2–Y2O3–Al2O3, Z. Metallkd., 2004, 95, p 27–39.

    Article  Google Scholar 

  8. R. Norin, R.G. Hazell, J. Sletten, P.H. Nielsen, A.A. Lindberg, G. Jansen, B. Lamm, and B. Samuelsson, On the Crystal Structures of Some Phases in the Al2O3-Nb2O5-System, Acta Chem. Scand., 1969, 23, p 1210–1214. https://doi.org/10.3891/acta.chem.scand.23-1210

    Article  Google Scholar 

  9. G.K. Layden, The system Al2O3-Nb2O5, J. Ceram. Soc., 1963, 46, p 506–506.

    Article  Google Scholar 

  10. B.T. Pedersen, The Crystal Strucuture of Aluminum Niobium Oxide (AlNbO4), Acta Chem. Scand., 1962, 16, p 421–430.

    Article  Google Scholar 

  11. E.K. Muller, and B.J. Nicholson, Concerning the Phase Diagram and Dieletric Behavior of the Oxide System Al2O3-Nb2O5, J. Am. Ceram. Soc., 1962, 45, p 250–251.

    Article  Google Scholar 

  12. J.-H. Lee, M. Yashima, M. Kakihana, and M. Yoshimura, Phase diagram and Oxygen-Ion Conductivity in the Y2O3–Nb2O5 System, J. Am. Ceram. Soc., 1998, 81, p 894–900.

    Article  Google Scholar 

  13. N. Ishizawa, T. Miyata, I. Minato, F. Marumo, and S. Iwai, A Structural Investigation of α-Al2O3 at 2170 K, Acta Crystallogr, Sect. B Struct. Crystallogr. Cryst. Chem., 1980, 36, p 228–230. https://doi.org/10.1107/s0567740880002981

    Article  Google Scholar 

  14. E.N. Maslen, V.A. Streltsov, and N. Ishizawa, A Synchrotron X-Ray Study of the Electron Density in C-Type Rare Earth Oxides, Acta Crystallogr. Sect. B Struct. Sci., 1996, 52, p 414–422. https://doi.org/10.1107/S0108768195013371

    Article  Google Scholar 

  15. K. Kato, Structure Refinement of H-Nb2Os, Acta Crystallogr, Sect. B Struct. Crystallogr. Cryst. Chem., 1976, B32, p 764–767.

    Article  Google Scholar 

  16. R. Diehl, and G. Brandt, Crystal Structure Refinement of YAlO3, a Promising Laser Material, Mater. Res. Bull., 1975, 10, p 85–90. https://doi.org/10.1016/0025-5408(75)90125-7

    Article  Google Scholar 

  17. Ł Dobrzycki, E. Bulska, D.A. Pawlak, Z. Frukacz, and K. Woźniak, Structure of YAG Crystals Doped/Substituted with Erbium and Ytterbium, Inorg. Chem., 2004, 43, p 7656–7664. https://doi.org/10.1021/ic049920z

    Article  Google Scholar 

  18. H. Yamane, M. Shimada, and B.A. Hunter, High-Temperature Neutron Diffraction Study of Y4Al2O9, J. Solid State Chem., 1998, 141, p 466–474. https://doi.org/10.1006/jssc.1998.7998

    Article  ADS  Google Scholar 

  19. S.A. Mather, and P.K. Davies, Nonequilibrium Phase Formation in Oxides Prepared at Low Temperature: Fergusonite-Related Phases, J. Am. Ceram. Soc., 1995, 78, p 2737–2745. https://doi.org/10.1111/j.1151-2916.1995.tb08049.x

    Article  Google Scholar 

  20. H.P. Rooksby, and E.A.D. White, Rare-Earth Niobates and tantaiates of Defect Fluorite- and Weberite-Type Structures, J. Am. Ceram. Soc., 1964, 47, p 94–96. https://doi.org/10.1111/j.1151-2916.1964.tb15663.x

    Article  Google Scholar 

  21. M. Ardit, M. Dondi, and G. Cruciani, Structural Stability, Cation Ordering, and Local Relaxation Along the AlNbO4-Al0.5Cr0.5NbO4 Join, Am. Mineral., 2012, 97, p 910–917.

    Article  ADS  Google Scholar 

Download references

Acknowledgment

Authors thank the FAPEMIG-, FAPERJ-, CAPES-, CNPq- and FINEP-Brazil for financial support.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Alfeu Saraiva Ramos.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zaidan, D.W., de Freitas, B.X., Coelho, G.C. et al. The 1300 °C Isothermal Section in the Al2O3-Y2O3-Nb2O5 System. J. Phase Equilib. Diffus. 43, 393–400 (2022). https://doi.org/10.1007/s11669-022-00973-6

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11669-022-00973-6

Keywords

Navigation