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Experimental Investigations of Phase Equilibria in the Ta-V-Cr Ternary System

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Abstract

The phase equilibria and microstructure of the Ta-V-Cr ternary system at 1200 and 1300 °C were studied by x-ray diffraction and electron probe microanalysis. The isothermal section at 1200 °C consists four single-phase regions, four two-phase regions and one three-phase region. In addition, the C15 phases of αV2Ta and Cr2Ta(LT) exhibit complete mutual solid solubility at 1200 °C, while the C15(Cr2Ta(LT)) phase containing a large solubility of V is identified at 1300 °C.

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References

  1. J. Livingston, Laves-Phase Superalloys?, Phys. Status Solidi A, 1992, 131(2), p 415-423

    Article  ADS  Google Scholar 

  2. C. Radhakrishna and K.P. Rao, The Formation and Control of Laves Phase in Superalloy 718 Welds, J. Mater. Sci., 1997, 32(8), p 77-84 (in English)

    Article  Google Scholar 

  3. A.V. Kazantzis, M. Aindow, I.P. Jones, G.K. Triantafyllidis, and J.T.M. De Hosson, The Mechanical Properties and the Deformation Microstructures of the C15 Laves Phase Cr2Nb at High Temperatures, Acta Mater., 2007, 55(6), p 1873-1884

    Article  ADS  Google Scholar 

  4. I. Fedorova, A. Belyakov, P. Kozlov, V. Skorobogatykh, I. Shenkova, and R. Kaibyshev, Laves-Phase Precipitates in a Low-Carbon 9% Cr Martensitic Steel During Aging and Creep at 923 K, Mater. Sci. Eng. A, 2014, 615, p 153-163

    Article  Google Scholar 

  5. H. Okaniwa, D. Shindo, M. Yoshida, and T. Takasugi, Determination of Site Occupancy of Additives X (X = V, Mo, W and Ti) in the Nb-Cr-X Laves Phase by ALCHEMI, Acta Mater., 1999, 47(6), p 1987-1992

    Article  ADS  Google Scholar 

  6. Q. Yao, J. Sun, D. Lin, S. Liu, and B. Jiang, First-Principles Studies of Defects, Mechanical Properties and Electronic Structure of Cr-Based Laves Phases, Intermetallics, 2007, 15(5-6), p 694-699

    Article  Google Scholar 

  7. F. Chu, D.J. Thoma, P.G. Kotula, S. Gerstl, T.E. Mitchell, I.M. Anderson, and J. Bentley, Phase Stability and Defect Structure of the C15 Laves Phase Nb(Cr, V)2, Acta Mater., 1998, 46(5), p 1759-1769

    Article  ADS  Google Scholar 

  8. A. Bhowmik, S. Neumeier, J.S. Barnard, C.H. Zenk, M. Göken, C.M.F. Rae, and H.J. Stone, Microstructure and Mechanical Properties of Cr-Ta-Si Laves Phase-Based Alloys at Elevated Temperatures, Philos. Mag., 2014, 94(34), p 3914-3944

    Article  ADS  Google Scholar 

  9. M.P. Brady, J.H. Zhu, C.T. Liu, P.F. Tortorelli, L.R. Walker, C.G. McKamey, J.L. Wright, C.A. Carmichael, D.J. Larson, M.K. Miller, and W.D. Porter, Intermetallic Reinforced Cr Alloys for High-Temperature Use, Mater. High Temp., 2014, 16(4), p 189-193

    Article  Google Scholar 

  10. K.S. Kumar, L. Pang, C.T. Liu, J. Horton, and E.A. Kenik, Structural Stability of the Laves Phase Cr2Ta in a Two-Phase Cr-Cr2Ta Alloy, Acta Mater., 2000, 48(4), p 911-923

    Article  ADS  Google Scholar 

  11. M.C. Gao, Y. Suzuki, H. Schweiger, O.N. Dogan, J. Hawk, and M. Widom, Phase Stability and Elastic Properties of Cr-V Alloys, J. Phys. Condens. Matter, 2013, 25(7), p 075402 (in English)

    Article  ADS  Google Scholar 

  12. Y. Matsumoto, J. Fukumori, M. Morinaga, M. Furui, T. Nambu, and T. Sakaki, Alloying Effect of 3D Transition Elements on the Ductility of Chromium, Scr. Mater., 1996, 34(11), p 1685-1689

    Article  Google Scholar 

  13. S. Shibuya, Y. Kaneno, M. Yoshida, and T. Takasugi, Dual Multi-phase Intermetallic Alloys Composed of Geometrically Close Packed Ni3X (X: Al, Ti and V) Type Structures—II. Mechanical Properties, Acta Mater., 2006, 54(3), p 861-870

    Article  ADS  Google Scholar 

  14. P.F. Schippnick and A.C. Lawson, Superconductivity of TaV2, Solid State Commun., 1974, 15(10), p 1643-1644

    Article  ADS  Google Scholar 

  15. Y.C. Chen, C.P. Wang, J.J. Ruan, T. Omori, R. Kainuma, K. Ishida, and X.J. Liu, High-Strength Co-Al-V-Base Superalloys Strengthened by Gamma γ’-Co3(Al, V) with High Solvus Temperature, Acta Mater., 2019, 170, p 62-74

    Article  ADS  Google Scholar 

  16. E.M. Savicky and J.V. Efimov, Superconducting Metallic Compounds and Their Alloys, Monatsh. Chem., 1972, 103(1), p 270-287

    Article  Google Scholar 

  17. J. Smith and O. Carlson, The Ta-V (Tantalum-Vanadium) System, Bull. Alloy Phase Diagr., 1983, 4(3), p 284-289

    Article  Google Scholar 

  18. C.A. Danon and C. Servant, A Thermodynamic Evaluation of the Ta-V System, J. Alloys Compd., 2004, 366(1-2), p 191-200

    Article  Google Scholar 

  19. R. Chinnappan, Phase Stability of V-Ta Alloy Using Cluster Expansion and Monte Carlo Techniques, Calphad-Comput. Coupling Phase Diagr. Thermochem., 2012, 39, p 33-36 (in English)

    Article  Google Scholar 

  20. M. Venkatraman and J. Neumann, The Cr-Ta (Chromium-Tantalum) System, J. Phase Equilibria, 1987, 8(2), p 112-116

    Article  Google Scholar 

  21. N. Dupin and I. Ansara, Thermodynamic Assessment of the Cr-Ta System, J. Phase Equilibria, 1993, 14(4), p 451-456

    Article  Google Scholar 

  22. J. Pavlu, J. Vrest’al, and M. Sob, Re-modeling of Laves Phases in the Cr-Nb and Cr-Ta Systems Using First-Principles Results, Calphad-Comput. Coupling Phase Diagr. Thermochem., 2009, 33(1), p 179-186

    Article  Google Scholar 

  23. J.F. Smith, Phase Diagrams of Binary Vanadium Alloys, ASM International, Materials Park, 1989

    Google Scholar 

  24. J.Y. Lee, J.H. Kim, S.I. Park, and H.M. Lee, Phase Equilibrium of the Ti-Cr-V Ternary System in the Non-burning β-Ti Alloy Region, J. Alloys Compd., 1999, 291(1-2), p 229-238

    Article  Google Scholar 

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (Grant No. 51831007) and National Key R&D Program of China (Grant No. 2017YFB0702901).

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Correspondence to C. P. Wang.

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Liu, X.J., Yang, P., Yang, S.Y. et al. Experimental Investigations of Phase Equilibria in the Ta-V-Cr Ternary System. J. Phase Equilib. Diffus. 41, 891–899 (2020). https://doi.org/10.1007/s11669-020-00853-x

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  • DOI: https://doi.org/10.1007/s11669-020-00853-x

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