Skip to main content
SpringerLink
Log in

Experimental Study of the 600 and 800 °C Isothermal Sections of the Al-Sb-Cr System

  • Published:
Journal of Phase Equilibria and Diffusion Aims and scope Submit manuscript

Abstract

The 600 and 800 °C isothermal sections of the Al-Sb-Cr ternary system were studied by scanning electron microscopy, energy dispersive x-ray spectroscopy, and x-ray diffraction. No ternary compound was found in this system at either 600 or 800 °C. AlSb can equilibrate with all phases in both the 600 and 800 °C isothermal sections except Cr. Ten three-phase regions were clearly identified in the Al-Sb-Cr ternary system at 600 °C and seven three-phase regions were confirmed in the 800 °C isothermal section.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13

Similar content being viewed by others

References

  1. H.C. Liu, F. Li, W. Shi, S. Swaminathan, Y.L. He, M. Rohwerder, and L. Li, Challenges in Hot-Dip Galvanizing of High Strength Dual Phase Steel: Surface Selective Oxidation and Mechanical Property Degradation, Surf. Coat. Technol., 2012, 206(16), p 3428-3436

    Article  Google Scholar 

  2. H.C. Liu, Y.L. He, S. Swaminathan, M. Rohwerder, and L. Li, Effect of Dew Point on the Surface Selective Oxidation and Subsurface Microstructure of Trip-Aided Steel, Surf. Coat. Technol., 2011, 206(6), p 1237-1243

    Article  Google Scholar 

  3. Y.I. Choi, E.S. Shin, K. Kuroda, M. Okido, and C.J. Park, Improved Surface Morphology and Corrosion Resistance for Galvannealed Coatings by Pre-electroplating Iron, Corros. Sci., 2012, 58(5), p 152-158

    Article  Google Scholar 

  4. F. Li, H.C. Liu, W. Shi, and L. Li, Thermodynamic Consideration on Selective Surface Oxidation of High Strength Steels Prior to Hot-Dip Galvanizing, J. Coat. Technol. Res., 2011, 8(5), p 639-647

    Article  Google Scholar 

  5. M. Auinger, V.G. Praig, B. Linder, and H. Danninger, Grain Boundary Oxidation in Iron-Based Alloys, Investigated by 18o Enriched Water Vapour—The Effect of Mixed Oxides in Binary and Ternary Fe-{Al, Cr, Mn, Si} Systems, Corros. Sci., 2015, 96, p 133-143

    Article  Google Scholar 

  6. M. Auinger, E.M. Müller-Lorenz, and M. Rohwerder, Modelling and Experiment of Selective Oxidation and Nitridation of Binary Model Alloys at 700 °C-the Systems Fe, 1 wt.%{Al, Cr, Mn, Si}, Corros. Sci., 2015, 90(5), p 503-510

    Article  Google Scholar 

  7. M. Arndt, J. Duchoslav, R. Steinberger, G. Hesser, C. Commenda, L. Samek, E. Arenholz, and D. Stifter, Nanoscale Analysis of the Influence of Pre-Oxidation on Oxide Formation and Wetting Behavior of Hot-Dip Galvanized High Strength Steel, Corros. Sci., 2015, 93, p 148-158

    Article  Google Scholar 

  8. C. Zeng, Y.K. Bai, Y.H. Ling, Z.Y. Xin, H. Liang, and X.K. Deng, Hydrogen Interaction Characteristic of Nanoscale Oxide Films Grown on Iron-Nickel Based Stainless Steel by Selective Thermal Oxidation, Int. J. Hydrogen Energy, 2017, 42(32), p 20910-20921

    Article  Google Scholar 

  9. P.R. Wilson and Z. Chen, The Effect of Manganese and Chromium on Surface Oxidation Products Formed During Batch Annealing of Low Carbon Steel Strip, Corros. Sci., 2007, 49(3), p 1305-1320

    Article  Google Scholar 

  10. H.H. Shu, C. Carteret, J. Angulo, and G. Fricout, Relation Between Emissivity Evolution During Annealing and Selective Oxidation of Trip Steel, Corros. Sci., 2017, 132, p 185-193

    Google Scholar 

  11. I. Cvijović, I. Parezanović, and M. Spiegel, Influence of H2-N2 Atmosphere Composition and Annealing Duration on the Selective Surface Oxidation of Low-Carbon Steels, Corros. Sci., 2006, 48(4), p 980-993

    Article  Google Scholar 

  12. Y.F. Gong, S. Birosca, H.S. Kim, and B.C. De Cooman, Oxide Formation and Alloying Elements Enrichment on Trip Steel Surface During Inter-Critical Annealing, J. Microsc., 2010, 230(3), p 424-434

    Article  MathSciNet  Google Scholar 

  13. E. Clauberg, J. Janověc, C. Uebing, H. Viefhaus, and H.J. Grabke, Surface Segregation on Fe-25%Cr-2%Ni-0.14%Sb-N,S (100) Single Crystal Surfaces, Appl. Surf. Sci., 2000, 161(1), p 35-46

    Article  ADS  Google Scholar 

  14. Z.T. Zhang, I.R. Sohn, F.S. Pettit, G.H. Meier, and S. Sridhar, Investigation of the Effect of Alloying Elements and Water Vapor Contents on the Oxidation and Decarburization of Transformation-Induced Plasticity Steels, Metall. Mater. Trans. B, 2009, 40(4), p 567-584

    Article  Google Scholar 

  15. Y.L. Zhang, Y.Y. Zhang, F.H. Yang, and Z.T. Zhang, Effect of Alloying Elements (Sb, B) on Recrystallization and Oxidation of Mn-Containing IF Steel, J. Iron. Steel Res. Int., 2013, 20(3), p 39-44

    Article  Google Scholar 

  16. T. Hou, Z.X. Zhu, Y.L. Zhao, F.C. Yin, Z. Li, and Y.X. Liu, 450 °C Isothermal Section of the Fe-Al-Sb Ternary Phase Diagram, J. Phase Equilib. Diffus., 2013, 34(3), p 188-195

    Article  Google Scholar 

  17. T. Hou, Z.X. Zhu, Y.L. Zhao, F.C. Yin, and M.X. Zhao, The 680 °C and 800 °C Isothermal Sections of The Fe-Al-Sb System, J. Alloys Compd., 2014, 586, p 295-301

    Article  Google Scholar 

  18. Y.K. Xia, Y. Liu, C.J. Wu, H.P. Peng, H. Tu, J.H. Wang, and X.P. Su, 650 and 750 °C Isothermal Sections of the Cr-Sb-Fe System, J. Phase Equilib. Diffus., 2018, 39(4), p 426-436

    Article  Google Scholar 

  19. K. Yamaguchi, K. Itagaki, and Y.A. Chang, Thermodynamic Analysis of the In-P, Ga-As, In-As And Al-Sb Systems. CALPHAD, 1996, 20(4), p 439-446

    Article  Google Scholar 

  20. H. Okamoto, Cr-Sb (Chromium-Antimony), J. Phase Equilib. Diffus., 1992, 13(4), p 438-439

    Article  Google Scholar 

  21. J.L. Murray, The Al-Cr (Aluminum-Chromium) System, J. Phase Equilib. Diffus., 1998, 19(4), p 367-375

    Article  MathSciNet  Google Scholar 

  22. H. Okamoto, Al-Cr (Aluminum-Chromium), J. Phase Equilib. Diffus., 2008, 29(1), p 112-113

    Article  Google Scholar 

  23. B. Grushko, E. Kowalska-Strzeciwilk, B. Przepiorzynski, and M. Surowiec, Investigation of the Al-Cr γ-Range, J. Alloys Compd., 2005, 402(1), p 98-104

    Article  Google Scholar 

  24. B. Grushko, B. Przepiorzynski, E. Kowalska-Strzeciwilk, and M. Surowiec, New Phase in the High-Al Region of Al-Cr, J. Alloys Compd., 2006, 420(1), p L1-L4

    Article  Google Scholar 

  25. B. Grushko, B. Przepiórzyński, and D. Pavlyuchkov, On the Constitution of the High-Al Region of the Al-Cr Alloy System, J. Alloys Compd., 2008, 454(1), p 214-220

    Article  Google Scholar 

  26. B. Grushko, and D. Pavlyuchkov, CALPHAD, 2016, 52, p 186 (abstract in pp.240-241).

  27. X.P. Su, N.Y. Tang, and J.M. Toguri, 450 °C Isothermal Section of the Fe-Zn-Si Ternary Phase Diagram, Can. Metall. Q., 2013, 40(3), p 377-384

    Article  Google Scholar 

  28. B. Hu, W.W. Zhang, Y.B. Peng, Y. Du, S.H. Liu, and Y.L. Zhang, Thermodynamic Reassessment of the Al-Cr-Si System with the Refined Description of the Al-Cr System, Thermochim. Acta, 2013, 561(37), p 77-90

    Article  Google Scholar 

  29. Z.B. He, B.S. Zou, and K.H. Kuo, The Monoclinic Al45Cr7 Revisited, J. Alloys Compd., 2006, 417(1), p L4-L8

    Article  Google Scholar 

  30. B.B. Cao and K.H. Kuo, Crystal Structure of the Monoclinic η-Al11Cr2, J. Alloys Compd., 2008, 458(1), p 238-247

    Article  Google Scholar 

  31. B. Grushko and B. Grushko, A Contribution to the Al-Cu-Cr Phase Diagram, J. Alloys Compd., 2017, 729, p 426-437

    Article  Google Scholar 

  32. B. Grushko, W. Kowalski, and S.B. Mi, A Study of the Al-Co-Cr Alloy System, J. Alloys Compd., 2018, 739, p 280-289

    Article  Google Scholar 

  33. G. Cai and L. Zeng, The Isothermal Section of the Cr-Pb-Sb Ternary System at 500 K, J. Alloys Compd., 2006, 403(1–2), p 127-130

    Google Scholar 

  34. D. Minić, M. Premović, V. Ćosović, D. Manasijević, D. Živković, A. Kostov, and N. Talijan, Experimental Investigation and Thermodynamic Calculations of the Al-Cu-Sb Phase Diagram, J. Alloys Compd., 2013, 555, p 347-356

    Article  Google Scholar 

Download references

Acknowledgments

Financial support from the National Science Foundation of China (Grant Nos. 51471037 and 51671036) and a project funded by the Priority Academic Program Development of Jiangsu higher education institutions are greatly acknowledged.

Author information

Authors and Affiliations

  1. Key Laboratory of Materials Surface Science and Technology of Jiangsu Province, Changzhou University, Changzhou, 213164, China

    Xuping Su, Yukuan Xia, Ya Liu, Changjun Wu, Haoping Peng, Hao Tu & Jianhua Wang

  2. Jiangsu Collaborative Innovation Center of Photovoltaic Science and Engineering, Changzhou University, Changzhou, 213164, China

    Xuping Su, Ya Liu & Hao Tu

  3. National Experimental Teaching Demonstration Center of Materials Science and Engineering, Changzhou University, Changzhou, 213164, China

    Xuping Su & Jianhua Wang

Authors
  1. Xuping Su
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yukuan Xia
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ya Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Changjun Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Haoping Peng
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Hao Tu
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Jianhua Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Xuping Su.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Su, X., Xia, Y., Liu, Y. et al. Experimental Study of the 600 and 800 °C Isothermal Sections of the Al-Sb-Cr System. J. Phase Equilib. Diffus. 40, 638–652 (2019). https://doi.org/10.1007/s11669-019-00750-y

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11669-019-00750-y

Keywords

Search

Navigation