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Interdiffusion and Atomic Mobilities in bcc Ti-Ga and Ti-Cu Alloys

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Abstract

On the basis of three groups of Ti/Ti-10 at.% Ga and Ti/Ti-7 at.% Cu diffusion couples, respectively, interdiffusion coefficients in the bcc Ti-Ga and Ti-Cu binary alloys in the temperature range of 1273-1573 K were evaluated by means of the den Broeder method. Based on various reported experimental and the present measured diffusion coefficients as well as the available thermodynamic information, accurate atomic mobilities in the bcc Ti-Ga and Ti-Cu alloys were assessed via the DICTRA simulation package. A semi-empirical correlation was employed in the present work for the self-diffusivities in the hypothetical bcc Ga and Cu. Comparision between the calculated and measured diffusion coefficients indicated that most of the experimental information can be reasonably reproduced. The developed diffusion mobilities were further validated by the prediction of the concentration-distance profiles.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (Grant Nos. 51471138 and 51171159) and the Ministry of Education of China (Grant No. 20120121130004) and the Natural Science Foundation of Fujian Province of China (Grant No. 2016J01256). The support from the Ministry of Science and Technology of China (Grant Nos. 2012CB825700 and 2014DFA53040), the Science and Technology Bureau of Xiamen City (Grant No. 3502Z20131153) are also acknowledged.

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Authors and Affiliations

  1. Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen, 361005, People’s Republic of China

    C. P. Wang, Y. S. Luo, Y. Lu, J. J. Han, Z. Shi, Y. H. Guo & X. J. Liu

  2. Fujian Key Laboratory of Materials Genome, Xiamen University, Xiamen, 361005, People’s Republic of China

    C. P. Wang, Y. Lu, J. J. Han, Z. Shi & X. J. Liu

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  1. C. P. Wang
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  2. Y. S. Luo
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  3. Y. Lu
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Correspondence to X. J. Liu.

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Wang, C.P., Luo, Y.S., Lu, Y. et al. Interdiffusion and Atomic Mobilities in bcc Ti-Ga and Ti-Cu Alloys. J. Phase Equilib. Diffus. 38, 84–93 (2017). https://doi.org/10.1007/s11669-016-0506-7

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  • DOI: https://doi.org/10.1007/s11669-016-0506-7

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