Abstract
Ni-Ti coatings with different Al contents were synthesized on SUS 316L stainless steel substrates by the mechanical alloying method. The effects of Al addition and annealing treatment on the microstructures, microhardness, wear and corrosion resistances of the coatings were investigated. The results showed that the as-synthesized coatings possessed composite structures of Ti particles as reinforcements and Ni-Al lamellas as matrix. Their thicknesses increased with the increase in the Al addition from 0 to 15 wt.%. Intermetallic phases were hardly detected in the coatings with Al content below 15 wt.%. The coating with 10 wt.% Al exhibited optimal microstructure, mechanical properties and favorable corrosion resistance. The subsequent annealing treatment promoted both diffusion in the coating and interdiffusion between the coating and the substrate, which was conductive to the alloying of the coating and the enhancement at the interface. The microhardness increased from about 520 HV0.1 to about 680 HV0.1 and both the friction coefficients and the wear weight loss decreased about 20% after annealing. The corrosion resistance of the coating decreased after annealing. The corrosion potential decreased slightly, but the corrosion current density was doubled. The as-synthesized Ni-Ti coatings had the potential to protect the substrate from being severely worn or corroded.
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References
C. Martins, J. Moreira, and J. Martins, Corrosion in water supply pipe stainless steel 304 and a supply line of helium in stainless steel 316, Eng. Fail. Anal., 2014, 39, p 65–71.
Y. Liu, Y. Zhao, and J. Yao, Synergistic erosion–corrosion behavior of X80 pipeline steel at various impingement angles in two-phase flow impingement, Wear, 2021, 466–467, p 203572.
Y. Yang and Y.F. Cheng, Electrolytic deposition of Ni–Co–SiC nano-coating for erosion-enhanced corrosion of carbon steel pipes in oilsand slurry, Surf. Coat. Tech., 2011, 205, p 3198–3204.
S. Ayata and W. Ensinger, Ion beam sputter coating in combination with sol-gel dip coating of Al alloy tube inner walls for corrosion and biological protection, Surf. Coat. Tech., 2018, 340, p 121–125.
X. Ji, C. Yan, H. Duan, and C. Luo, Effect of phosphorous content on the microstructure and erosion–corrosion resistance of electrodeposited Ni-Co-Fe-P coatings, Surf. Coat. Tech., 2016, 302, p 208–214.
M. Kumar, H. Singh, N. Singh, and R.S. Joshi, Erosion–corrosion behavior of cold-spray nanostructured Ni–20Cr coatings in actual boiler environment, Wear, 2015, 332, p 1035–1043.
J.A. Calderón, J.E. Henao, and M.A. Gómez, Erosion–corrosion resistance of Ni composite coatings with embedded SiC nanoparticles, Electrochim. Acta, 2014, 124, p 190–198.
M. Bitzer, N. Rauhut, G. Mauer, M. Bram, R. Vaßen, H. Buchkremer, D. Stöver, and M. Pohl, Cavitation-resistant NiTi coatings produced by low-pressure plasma spraying (LPPS), Wear, 2015, 328–329, p 369–377.
F. Liu, Y. Mao, X. Lin, B. Zhou, and T. Qian, Microstructure and high temperature oxidation resistance of Ti-Ni gradient coating on TA2 titanium alloy fabricated by laser cladding, Opt. Laser Technol., 2016, 83, p 140–147.
M.N. Mokgalaka, A.P.I. Popoola, and S.L. Pityana, In situ laser deposition of NiTi intermetallics for corrosion improvement of Ti–6Al–4V alloy, T. Nonferr. Metal. Soc., 2015, 25, p 3315–3322.
B.A. Obadele, M.L. Lepule, A. Andrews, and P.A. Olubambi, Tribocorrosion characteristics of laser deposited Ti–Ni–ZrO2 composite coatings on AISI 316 stainless steel, Tribol. Int., 2014, 78, p 160–167.
D.T. Waghmare, C. Kumar Padhee, R. Prasad, and M. Masanta, NiTi coating on Ti-6Al-4V alloy by TIG cladding process for improvement of wear resistance: microstructure evolution and mechanical performances, J. Mater. Process. Tech., 2018, 262, p 551–561.
F. Neves, F.M.B. Fernandes, I. Martins, and J.B. Correia, Parametric optimization of Ti–Ni powder mixtures produced by mechanical alloying, J. Alloys Compd., 2011, 509S, p S271–S274.
M. Shafeeq, G.K. Gupta, M.M.M. Hirshikesh, and O.P. Modi, Effect of milling parameters on processing, microstructure and properties of Cu–Al–Ni–Ti shape memory alloys, Powder Metall., 2015, 58, p 265–272.
C. Chen Suprianto, Microstructure and mechanical properties of AlCuNiFeCr high entropy alloy coatings by mechanical alloying, Surf. Coat. Tech., 2020, 386, p 125443.
J. Jiang, Y. Shen, and X. Feng, Microstructures evolution, formation mechanisms and properties of SiCp/Al composite coatings on Ti-6Al-4V substrate via mechanical alloying method, Surf. Interfaces, 2020, 19, p 100487.
C. Yan, D. Xiong, and J. Li, Synthesis of Ni-Al-Ta composite coatings on Al alloy plates and the transfer of Al powder via mechanical milling technique, Powder Technol., 2018, 340, p 234–242.
C. Chen, X. Feng, and Y. Shen, Microstructure and mechanical properties of Ti–Cu amorphous coating synthesized on pure Cu substrate by mechanical alloying method, Rare Met., 2020, 39(10), p 1222–1228.
M.R. Bafandeh, A. Omidi, and A. Irankhah, In situ coating of low carbon steel with Ni–Al–Fe powder mixture via mechanical alloying, Surf. Coat. Tech., 2017, 315, p 268–273.
C. Chen, X. Feng, and Y. Shen, Microstructures and properties of TiCp/Al coating synthesized on Ti–6Al–4V alloy substrate using mechanical alloying method, J. Alloys Compd., 2020, 813, p 152223.
Acknowledgment
This work was supported by the National College Students Innovation and Entrepreneurship Training Program (No. 201910291063Z), the Natural Science Foundation of Jiangsu Province (No. BK20190686), the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (No. 18KJB460017) and the Introduce Talent Special Funding for Scientific Research at Nanjing Tech University (No. 39802125).
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Chen, C., Yang, Z., Wang, J. et al. Effects of Al Addition and Annealing on Microstructure and Properties of Ni-Ti Coatings Synthesized on SUS 316L Stainless Steel Substrates Using Mechanical Alloying Method. J. of Materi Eng and Perform (2024). https://doi.org/10.1007/s11665-024-09378-7
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DOI: https://doi.org/10.1007/s11665-024-09378-7