Abstract
In this work, stearic acid (SA) was used to improve the dispersion and tribological performance of graphene oxide (GO). The results exhibited that the SA could improve the dispersion of GO in water by the typical steric hindrance effect. As water-based lubricating additives, the GO modified by SA showed good tribological performance and load-carrying capacity, which had a low coefficient of friction and no obvious wear scar even sliding under the load of 400 mN for 2 h, indicating a long lubricating life. These superior performances were ascribed to the good dispersion of SA-modified GO in water and the synergistic effect of the excellent anti-wear property of GO and the good lubricating performance of SA.
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L.L. Cui, H. Li, C.Y. Gong, J.W. Huang, and D.S. Xiong, A Biomimetic Bilayer Coating on Laser-Textured Ti6Al4V Alloy With Excellent Surface Wettability and Biotribological Properties for Artificial Joints, Ceram. Int., 2022, 48, p 26264–26273. https://doi.org/10.1016/j.ceramint.2022.05.309
Y.T. Peng and Z.H. Ni, Tribological Properties of Stearic Acid Modified Multi-Walled Carbon Nanotubes in Water, J. Tribol., 2013, 135, p 012001. https://doi.org/10.1115/1.4007676
H. Kinoshita, Y. Nishina, A.A. Alias, and M. Fujii, Tribological Properties of Monolayer Graphene Oxide Sheets as Water-Based Lubricant Additives, Carbon, 2014, 66, p 720–723. https://doi.org/10.1016/j.carbon.2013.08.045
H. Khanmohammadi, W. Wijanarko, and N. Espallargas, Ionic Liquids as Additives in Water-Based Lubricants: From Surface Adsorption to Tribofilm Formation, Tribol. Lett., 2020, 130, p 68. https://doi.org/10.1007/s11249-020-01377-8
R.B. Qiang, L.F. Hu, K.M. Hou, J.Q. Wang, and S.R. Yang, Water-Soluble Graphene Quantum Dots as High-Performance Water-Based Lubricant Additive for Steel/Steel Contact, Tribol. Lett., 2019, 64, p 67. https://doi.org/10.1007/s40544-014-0039-1
Y.Y. Bao, J.L. Sun, and L.H. Kong, Effects of Nano-SiO2 as Water-Based Lubricant Additive on Surface Qualities of Strips after Hot Rolling, Tribol. Int., 2017, 114, p 257–263. https://doi.org/10.1016/j.triboint.2017.04.026
J.H. Wang, J.L. Li, X.B. Wang, and W.M. Liu, Tribological Properties of Water-Soluble TiO2 Nanoparticles as Additives in Water, Ind. Lubr. Tribol., 2010, 62, p 292–297. https://doi.org/10.1108/00368791011064455
S. Xiong, B.S. Zhang, S. Luo, H. Wu, and Z. Zhang, Preparation, Characterization, and Tribological Properties of Silica-Nanoparticle-Reinforced B-N-co-Doped Reduced Graphene Oxide as a Multifunctional Additive for Enhanced Lubrication, Friction, 2021, 9, p 239–249. https://doi.org/10.1007/s40544-019-0331-1
Y. Wang, L.L. Cui, G.G. Cheng, N.Y. Yuan, J.N. Ding, and N.S. Pesika, Water-Based Lubrication of Hard Carbon Microspheres as Lubricating Additives, Tribol. Lett., 2018, 148, p 2–10. https://doi.org/10.1007/s11249-018-1102-2
P. Haghdadeh, M. Ghaffari, B. Ramezanzadeh, G. Bahlakeh, and M.R. Saeb, The Role of Functionalized Graphene Oxide on the Mechanical and Anti-Corrosion Properties of Polyurethane Coating, J. Taiwan. Inst. Chem. Eng., 2018, 86, p 199–212. https://doi.org/10.1016/j.jtice.2018.02.009
F.H. Su, G.F. Chen, and P. Huang, Lubricating Performances of Graphene Oxide and Onion-Like Carbon as Water-Based Lubricant Additives for Smooth and Sand-Blasted Steel Discs, Friction, 2020, 8(1), p 47–57. https://doi.org/10.1007/s40544-018-0237-3
Y. Wang, Z.P. Gu, J. Liu, J. Jiang, N.Y. Yuan, J.B. Pu, and J.N. Ding, An Organic/Inorganic Composite Multi-Layer Coating to Improve the Corrosion Resistance of AZ31B Mg Alloy, Surf. Coat. Tech., 2019, 360, p 276–284. https://doi.org/10.1016/j.surfcoat.2018.12.125
C.L. Gan, T. Liang, W. Li, X.Q. Fan, X. Li, D.S. Li, and M.H. Zhu, Hydroxyl-Terminated Ionic Liquids Functionalized Graphene Oxide with Good Dispersion and Lubrication Function, Tribol. Int., 2020, 148, p 106350. https://doi.org/10.1016/j.triboint.2020.106350
P.M. Harshal, G. Kanika, S. Raghuvir, P.S. Om, S. Hiroyuki, and P.K. Om, Alkylated Graphene Oxide and Reduced Graphene Oxide: Grafting Density, Dispersion Stability to Enhancement of Lubrication Properties, J. Colloid. Interf. Sci., 2019, 541, p 150–162. https://doi.org/10.1016/j.jcis.2019.01.064
Z.W. Dong, Y. Wan, S.Y. Yang, and J.Y. Zhang, Enhanced Friction-Reducing Behavior of Stearic Acid Film on Textured Steel, Tribol. Lett., 2013, 50, p 299–304. https://doi.org/10.1007/s11249-013-0124-z
F.P. Bowden and D. Tabor, Friction, Lubrication and Wear: a Survey of Work During the Last Decade, J. Appl. Phys., 1966, 17, p 1521. https://doi.org/10.1088/0508-3443/17/12/301
R.R. Sahoo and S.K. Biswas, Frictional Response of Fatty Acids on Steel, J. Colloid. Interf. Sci., 2009, 333, p 707–718. https://doi.org/10.1016/j.jcis.2009.01.046
S.M. Lundgren, M. Ruths, K. Danerlov, and K. Persson, Effects of Unsaturation on Flm Structure and Friction of Fatty Acids in a Model Base Oil, J. Colloid. Interf. Sci., 2008, 326, p 530–536. https://doi.org/10.1016/j.jcis.2008.05.068
M. Ruths, S. Lundgren, K. Danerlov, and K. Persson, Friction of Fatty Acids in Nanometer-Sized Contacts of Different Adhesive Strength, Langmuir, 2007, 24, p 1509–1516. https://doi.org/10.1021/la7023633
A. Zuin, T. Cousseau, A. Sinatora, S.H. Toma, K. Araki, and H.E. Toma, Lipophilic Magnetite Nanoparticles Coated with Stearic Acid: A Potential Agent for Friction and Wear Reduction, Tribol. Int., 2017, 112, p 10–19. https://doi.org/10.1016/j.triboint.2017.03.028
C. Tadokoro, S. Araya, M. Watanabe, H. Okubo, K. Nakano, and S. Sasaki, Synergy of Two Fatty Acids as Additives on Lubricity of a Nematic Liquid Crystal 5CB, Lubr. Sci., 2018, 30, p 83–90. https://doi.org/10.1002/ls.1406
J.S. Lin, L.W. Wang, and G.H. Chen, Modification of Graphene Platelets and their tribological properties as a Lubricant Additive, Tribol. Int., 2011, 41, p 209–215. https://doi.org/10.1007/s11249-010-9702-5
M.M. Yang, Z.Z. Zhang, X.T. Zhu, X.H. Men, and G.N. Ren, In Situ Reduction and Functionalization of Graphene Oxide to Improve the Tribological Behavior of a Phenol Formaldehyde Composite Coating, Friction, 2015, 3(1), p 72–81. https://doi.org/10.1007/s40544-015-0076-4
B.X. Li, T.X. Liu, L.Y. Hu, Y.F. Wang, and S.B. Nie, Facile Preparation and Adjustable Thermal Property of Stearic Acid-Graphene Oxide Composite as Shape-Stabilized Phase Change Material, Chem. Eng. J., 2013, 215–216, p 819–826. https://doi.org/10.1016/j.cej.2012.11.077
L. Zhang, Y. He, L. Zhu, Z.L. Jiao, W.Z. Deng, C.P. Pu, C.M. Han, and S. Tang, Alkyl Phosphate Modified Graphene Oxide as Friction and Wear Reduction Additives in Oil, J. Mater. Sci., 2019, 54, p 4526–4536. https://doi.org/10.1007/s10853-018-03216-7
J.W. Zhu, G.Y. Zeng, F.D. Nie, X.M. Xu, S. Cheng, Q.F. Han, and X. Wang, Decorating Graphene Oxide with CuO Nanoparticles in a Water-Isopropanol System, Nanoscale, 2010, 2, p 988–994. https://doi.org/10.1039/b9nr00414a
B.X. Li, T.X. Liu, Y.F. Wang, and Z.F. Wang, ZnO/Graphene-Oxide Nanocomposite with Remarkably Enhanced Visible-Light-Driven Photocatalytic Performance, J. Colloid. Interf. Sci., 2012, 377, p 114–121. https://doi.org/10.1016/j.jcis.2012.03.060
J.C. Meyer, A.K. Geim, M.I. Katsnelson, K.S. Novoselov, T.J. Booth, and S. Roth, The Structure of Suspended Graphene Sheets, Nature, 2007, 446, p 60–63. https://doi.org/10.1038/nature05545
B.J. Jiang, C.G. Tian, W. Zhou, J.Q. Wang, Y. Xie, Q.J. Pan, Z.Y. Ren, Y.Z. Dong, D. Fu, J.L. Han, and H.G. Fu, In Situ Growth of TiO2 in Interlayers of Expanded Graphite for the Fabrication of TiO2-graphene with Enhanced Photocatalytic Activity, Chem. Eur. J., 2011, 17, p 8379–8387. https://doi.org/10.1002/chem.201100250
Y. Wang, J.B. Pu, L. Xia, J.N. Ding, N.Y. Yuan, Y.Y. Zhu, and G.G. Cheng, Fabrication and Tribological Study of Graphene Oxide/Multiply-Alkylated Cyclopentanes Multilayer Lubrication Films on Si Substrates, Tribol. Lett., 2014, 53, p 207–214. https://doi.org/10.1007/s11249-013-0258-z
C.S. Chen, X.H. Chen, L.S. Xu, Z. Yang, and W.H. Li, Modification of Multi-Walled Carbon Nanotubes with Fatty Acid and Their Tribological Properties as Lubricant Additive, Carbon, 2005, 43, p 1660–1666. https://doi.org/10.1016/j.carbon.2005.01.044
Acknowledgments
This work is supported by the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (19KJA150002), the Changzhou science and technology support plan (CE20225060), the Topnotch Academic Programs Project of Jiangsu Higher Education Institutions and the Priority Academic Program Development of Jiangsu Higher Education Institutions.
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Wang, Y., Gu, Z., Cheng, G. et al. Stearic-Acid-Modified Graphene Oxide with High Dispersion Stability and Good Water-Lubricating Property. J. of Materi Eng and Perform 33, 2817–2823 (2024). https://doi.org/10.1007/s11665-023-08182-z
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DOI: https://doi.org/10.1007/s11665-023-08182-z