Abstract
Microscratch responses of four different thermoplastics including polytetrafluoroethylene, polyethylene, polyvinyl chloride, and polyetheretherketone were investigated under constant normal load by Berkovich indenter with the focus on quantifying effects of sliding speed and normal load on scratch variables such as penetration depth, elastic recovery rate, contact scratch hardness, residual scratch hardness, lateral hardness, width of residual groove, and scratch friction coefficient. The results show that penetration depth is more sensitive to sliding speed than lateral force, and power law functions are applicable to describe dependences of scratch variables on sliding speed and normal load. Correlations between scratch variables and mechanical properties such as yield strength and Meyer hardness are also discussed, and contact scratch hardness is linearly correlated with yield strength, Meyer hardness, and elastic recovery rate.
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Data Availability
The raw/processed data required to reproduce these findings cannot be shared at this time as the data also forms part of an ongoing study.
Abbreviations
- d p :
-
Penetration depth
- d r :
-
Residual depth
- d e/d p :
-
Elastic recovery rate
- v :
-
Sliding speed
- F n :
-
Normal load
- F t :
-
Lateral force
- μ :
-
Scratch friction coefficient
- E :
-
Elastic modulus
- σ y :
-
Yield strength
- H VM :
-
Meyer hardness
- σ b :
-
Tensile strength
- υ :
-
Poisson's ratio
- w c :
-
Contact scratch width
- w s :
-
Residual scratch width
- S h :
-
Horizontally projected contact area
- S v :
-
Vertically projected contact area
- δ :
-
Representative strain rate
- ε e :
-
Elastic strain
- ε p :
-
Irreversible plastic strain
- ε t :
-
Total strain
- H c :
-
Contact scratch hardness
- H s :
-
Residual scratch hardness
- H l :
-
Lateral hardness
- ψ :
-
Square of strain rate
- φ :
-
The effective cone angle of the indenter
- θ :
-
The angle between the axis and the pyramid surface of Berkovich indenter
References
J. Caro, N. Cuadrado, I. González, D. Casellas, J.M. Prado, A. Vilajoana, P. Artús, S. Peris, A. Carrilero, and J.C. Dürsteler, Microscratch Resistance of Ophthalmic Coatings on Organic Lenses, Surf. Coat. Technol., 2011, 205(21–22), p 5040–5052.
Liu Ming, Li. Shuo, and Gao Chenghui, Fracture Toughness Measurement by Micro-Scratch Tests with Conical Indenter, Tribology, 2019, 39(5), p 556–564.
A.T. Akono, N.X. Randall, and F.J. Ulm, Experimental Determination of the Fracture Toughness Via Microscratch Tests: Application to Polymers, Ceramics, and Metals, J. Mater. Res., 2012, 27(2), p 485–493.
D. Beegan, S. Chowdhury, and M.T. Laugier, Comparison between Nanoindentation and Scratch Test Hardness (Scratch Hardness) Values of Copper Thin Films on Oxidised Silicon Substrates, Surf. Coat. Technol., 2007, 201(12), p 5804–5808.
M.D. Manfrinato, L.S. de Almeida, L.S. Rossino, A.M. Kliauga, L. Melo-Máximo, D.V. Melo-Máximo, and R.C. Morón, Scratch Testing of Plasma Nitrided and Nitrocarburized AISI 321 Steel: Influence of the Treatment Temperature, Mater. Lett., 2022, 317, p 132083.
R.C. Morón, A.M. Delgado-Brito, and I. Campos-Silva, Scratch Resistance of Cobalt Boride Layer Subjected to a Diffusion Annealing Process, Mater. Lett., 2022, 309, p 131352.
M. Sundararajan, M. Devarajan, and M. Jaafar, A Novel Sealing and High Scratch Resistant Nanorod Ni-P Coating on Anodic Aluminum Oxide, Mater. Lett., 2021, 289, p 129425.
S. Lafaye, C. Gauthier, and R. Schirrer, A Surface Flow Line Model of a Scratching Tip: Apparent and True Local Friction Coefficients, Tribol. Int., 2005, 38(2), p 113–127.
K. Lee, K.P. Marimuthu, C.L. Kim, and H. Lee, Scratch-Tip-Size Effect and Change of Friction Coefficient in Nano/Micro Scratch Tests Using XFEM, Tribol. Int., 2018, 120, p 398–410.
F.X. Liu, F.Q. Yang, Y.F. Gao, W.H. Jiang, Y.F. Guan, P.D. Rack, O. Sergic, and P.K. Liaw, Micro-Scratch Study of a Magnetron-Sputtered Zr-Based Metallic-Glass Film, Surf. Coat. Technol., 2009, 203(22), p 3480–3484.
J. Liu, Y. Lao, and Y. Wang, Effects of Cu on Microstructure and Mechanical Properties of AlN/Tin-Cu Nanocomposite Multilayers, Acta Metall. Sin., 2017, 53(4), p 465–471.
B.K. Afornu, A.M. Lider, O.A. Ismail, and E.B. Agyekum, Sintered Silicon Carbide Composites Deposited on Zirconium Alloy Substrates in Air and Ar Atmosphere—Part I: Evaluation of Scratch Adhesion and Tribology Properties, Mater. Lett., 2022, 306, p 130963.
M. Storchak, I. Zakiev, V. Zakiev, and A. Manokhin, Coatings Strength Evaluation of Cutting Inserts Using Advanced Multi-Pass Scratch Method, Measurement, 2022, 191, p 110745.
F. Meng, J. Wang, E. Han, T. Shoji, and W. Ke, Microstructure near Scratch on Alloy 690TT and Stress Corrosion Induced by Scratching, Acta Metall. Sin., 2011, 47(7), p 839–846.
Z. Liu, J. Sun, and W. Shen, Study of Plowing and Friction at the Surfaces of Plastic Deformed Metals, Tribol. Int., 2002, 35(8), p 511–522.
T.A. Adler and R.P. Walters, Wear and Scratch Hardness of 304 Stainless-Steel Investigated with a Single Scratch Test, Wear, 1993, 162, p 713–720.
G. Zhang, C. Zhang, P. Nardin, W.Y. Li, H. Liao, and C. Coddet, Effects of Sliding Velocity and Applied Load on the Tribological Mechanism of Amorphous Poly-Ether–Ether–Ketone(PEEK), Tribol. Int., 2008, 41(2), p 79–86.
L.C.A. Van Breemen, L.E. Govaert, and H.E.H. Meijer, Scratching Polycarbonate: A Quantitative Model, Wear, 2012, 274–275, p 238–247.
P. Bandyopadhyay, A. Dey, and A.K. Mukhopadhyay, Novel Combined Scratch and Nanoindentation Experiments on Soda-Lime-Silica Glass, Int. J. Appl. Glas. Sci., 2012, 3(2), p 163–179.
K. Li, Y. Shapiro, and J.C.M. Li, Scratch Test of Soda-Lime Glass, Acta Mater., 1998, 46(15), p 5569–5578.
J. Schneider, S. Schula, and W.P. Weinhold, Characterisation of the Scratch Resistance of Annealed and Tempered Architectural Glass, Thin Solid Films, 2012, 520(12), p 4190–4198.
F. Petit, C. Ott, and F. Cambier, Multiple Scratch Tests and Surface-Related Fatigue Properties of Monolithic Ceramics and Soda Lime Glass, J. Eur. Ceram. Soc., 2009, 29(8), p 1299–1307.
J. Xu, X. Bao, and S. Jiang, In Vitro Corrosion Resistance of Ta2N Nanocrystalline Coating in Simulated Body Fluids, Acta Mech. Solida Sin., 2018, 54(3), p 443–456.
W. Kanematsu, Subsurface Damage in Scratch Testing of Silicon Nitride, Wear, 2004, 256(1–2), p 100–107.
M. Liu, Z. Xu, and R. Fu, Micromechanical and Microstructure Characterization of BaO-Sm2O3-5TiO2 Ceramic with Addition of Al2O3, Ceram. Int., 2022, 48(1), p 992–1005.
M. Liu, S. Yang, and C. Gao, Scratch Behavior of Polycarbonate by Rockwell C Diamond Indenter under Progressive Loading, Polym. Test., 2020, 90, p 106643.
S. Li, J. Zhang, M. Liu, R. Wang, and L. Wu, Influence of Polyethyleneimine Functionalized Graphene on Tribological Behavior of Epoxy Composite, Polym. Bull., 2021, 78(11), p 6493–6515.
O. Shikimaka and A. Prisacaru, Deformation Mechanisms under Nanoscratching of Si: Effect of Scratching Speed, Load and Indenter Orientation, Mater. Res. Express, 2019, 6(8), p 655.
M. Liu and W. Wang, Effects of Sliding Velocity on Microscratch Responses of Thermoplastics by Berkovich Indenter, Polym. Bull. (Berlin), 2022, 21, p 54.
L.P. Yu, D.X. Han, J.L. Ren, X.X. Guo, S.K. Guan, and G. Wang, Correlation between Jerky Flow and Jerky Dynamics in a Nanoscratch on a Metallic Glass Film, Sci. China-Phys. Mech. Astron., 2020, 63(7), p 277011.
C. Gao, H. Proudhon, and M. Liu, Three-dimensional Finite Element Analysis of Shallow Indentation of Rough Strain-hardening Surface, Friction, 2018, 7(6), p 587–602.
O. Reyes-Carcaño, J. Martínez-Trinidad, A. Meneses-Amador, G.A. Rodríguez-Castro, I. Campos-Silva, and U. Figueroa-López, Scratch Test in Boride Layers: Influence of Indenter Tip Radius on Failure Mechanisms, Mater. Lett., 2022, 315, p 131918.
M. Liu, F. Yan, and C. Gao, Effect of Normal Load on Microscratch Test of Copper, Acta. Metrol. Sin., 2020, 41(9), p 1095–1101.
P. Bandyopadhyay, A. Dey, A.K. Mandal, N. Dey, and A.K. Mukhopadhyay, New Observations on Scratch Deformations of Soda Lime Silica Glass, J. Non-Cryst. Solids, 2012, 358(16), p 1897–1907.
M. Liu, F. Yan, and C. Gao, Effect of Sliding Velocity of a Spherical Indenter on Microscratch Response of Materials, J. Fuzhou Univ. (Nat. Sci. Edition), 2021, 49(4), p 473–484.
M. Liu, F. Yan, and C. Gao, Influence of Sliding Velocity on Microscratch Response of Carbohydrate Polymers by Berkovich Indenter, Polym. Test., 2022, 109, p 107542.
J. Zhang, H. Jiang, C. Jiang, Q. Cheng, and G. Kang, In-Situ Observation of Temperature Rise During Scratch Testing of Poly(methylmethacrylate) and Polycarbonate, Tribol. Int., 2016, 95, p 1–4.
M. Liu, C. Huang, and C. Gao, Effect of Sample Tilt on Measurement of Friction Coefficient by Constant-Load Scratch Testing of Copper with a Spherical Indenter, Acta Metall. Sin., 2020, 41(10), p 1252–1259.
Y.Q. Geng, Y.D. Yan, Y. He, and Z.J. Hu, Investigation on Friction Behavior and Processing Depth Prediction of Polymer in Nanoscale Using AFM Probe-Based Nanoscratching Method, Tribol. Int., 2017, 114, p 33–41.
M. Liu, C. Huang, and C. Gao, Effect of Sample Tilt on Measurement of Friction Coefficient by Microscratch Test of Copper with a Spherical Indenter, Acta. Metrol. Sin., 2020, 41(10), p 1252–1259.
J. Caro, N. Cuadrado, I. Gonzalez, D. Casellas, J.M. Prado, A. Vilajoana, P. Artus, S. Peris, A. Carrilero, and J.C. Dusteler, Microscratch Resistance of Ophthalmic Coatings on Organic Lenses, Surf. Coat. Technol., 2011, 205(21–22), p 5040–5052.
C. Gauthier and R. Schirrer, Time and Temperature Dependence of the Scratch Properties of Poly(methylmethacrylate) Surfaces, J. Mater. Sci., 2000, 35(9), p 2121–2130.
Y.Q. Geng, Y.D. Yan, Z.J. Hu, and X.S. Zhao, Investigation of the Nanoscale Elastic Recovery of a Polymer Using an Atomic Force Microscopy-Based Method, Meas. Sci. Technol., 2016, 27(1), p 015001.
A. Krupicka, M. Johansson, and A. Hult, Use and Interpretation of Scratch Tests on Ductile Polymer Coatings, Prog. Org. Coat., 2003, 46(1), p 32–48.
K. Holl and T. Seul, Changes in the Mechanical Properties of Laser-Welded Polymer Specimens of Polypropylene and Polycarbonate through Different Sterilization Procedures, Polym. Eng. Sci., 2016, 56(5), p 536–540.
M.A. Samad and S.K. Sinha, Dry Sliding and Boundary Lubrication Performance of a UHMWPE/CNTs Nanocomposite Coating on Steel Substrates at Elevated Temperatures, Wear, 2011, 270(5), p 395–402.
X.Q. Pei, L.Y. Lin, A.K. Schlarb, and R. Bennewitz, Contact Area and Shear Stress in Repeated Single-Asperity Sliding of Steel on Polymer, Tribol. Lett., 2019, 67(1), p 30.
X. Gao, Z. He, and X. Yang, Ageing Research Review of Several Polymer Compounds, Synth. Mater. Aging Appl., 2005, 34(1), p 39–43.
S.V. Nemilov, Physical Ageing of Silicate Glasses at Room Temperature: General Regularities as a Basis for the Theory and the Possibility of a Priori Calculation of the Ageing Rate, Cerem. Int., 2000, 26(6), p 511–530.
L. Ma, X. Chen, and B. Su, Aging Mechanism of Perspex under the Typical Environment, Phys. Test. Chem. Anal. (Part A Phys. Test.), 2008, 44(2), p 64–67.
S.P. Denyer, S.L. Euans, and W.N. Ayre, Ageing and Moisture Uptake in Polymethyl Methacrylate (PMMA) Bone Cements, J. Mech. Behav. Biomed. Mater., 2014, 32, p 76–88.
E. Moghbelli, R. Banyay, and H.J. Sue, Effect of Moisture Exposure on Scratch Resistance of PMMA, Tribol. Int., 2014, 69(1), p 46–51.
N.K. Myshkin and A. Kovalev, Polymer Mechanics and Tribology, Ind. Lubr. Tribol., 2018, 70(4), p 764–772.
B. Lin, A.Y. Wang, T.Y. Sui, C.B. Wei, J.H. Wei, and S. Yan, Friction and Wear Resistance of Polytetrafluoroethylene-Based Composites Reinforced with Ceramic Particles under Aqueous Environment, Surf. Topogr.-Metrol. Prop., 2020, 8(1), p 015006.
Y.J. Nie, J.Q. Sun, W.X. Yin, L.C. Wang, Z.Y. Shi, and H. Schumann, Novel Diphenyl Thioether-Bridged Binuclear Metallocenes of Ti and Zr for Synthesis of Polyethylene with Broad Molecular Weight Distribution, J. Appl. Polym. Sci., 2011, 120(6), p 3530–3535.
J.W. Summers, A Review of Vinyl Technology, J. Vinyl Addit. Technol., 1997, 3(2), p 130–139.
H. Spece, T. Yu, A.W. Law, M. Marcolongo, and S.M. Kurtz, 3D Printed Porous PEEK Created Via Fused Filament Fabrication for Osteoconductive Orthopaedic Surfaces, J. Mech. Behav. Biomed. Mater., 2020, 109, p 103850.
C. Xiang, H.J. Sue, J. Chu, and B. Coleman, Scratch Behavior and Material Property Relationship in Polymers, J. Polym. Sci. Part B-Polym. Phys., 2001, 39(1), p 47–59.
H. Jiang, R. Browning and H.J. Sue, Understanding of Scratch-Induced Damage Mechanisms in Polymers, Polymer, 2009, 50(16), p 4056–4065.
A.T. AlMotasem, J. Bergström, A. Gåård, P. Krakhmalev, and L.J. Holleboom, Atomistic Insights on the Wear/Friction Behavior of Nanocrystalline Ferrite During Nanoscratching as Revealed by Molecular Dynamics, Tribol. Lett., 2017, 65(3), p 101.
J.P. Manaia, F.A. Pires, A.M.P. de Jesus, and S.H. Wu, Mechanical Response of Three Semi Crystalline Polymers under Different Stress States: Experimental Investigation and Modelling, Polym. Test., 2020, 81, p 106156.
J. Jancar, F. Ondreas, P. Lepcio, M. Zboncak, and K. Zarybnicka, Mechanical Properties of Glassy Polymers with Controlled Np Spatial Organization, Polym. Test., 2020, 90, p 106640.
T. Sumitomo, H. Huang, and L.B. Zhou, Deformation and Material Removal in a Nanoscale Multi-Layer Thin Film Solar Panel Using Nanoscratch, Int. J. Mach. Tools Manuf., 2011, 51(3), p 182–189.
V. Chivatanasoontorn, N. Aoki, and M. Kotaki, Effect of Scratch Velocity on Scratch Behavior of Injection-Molded Polypropylene, J. Appl. Polym. Sci., 2012, 125(4), p 2861–2866.
R.L. Browning, H. Jiang, A. Moyse, H.J. Sue, Y. Iseki, K. Ohtani, and Y. Ijichi, Scratch Behavior of Soft Thermoplastic Olefins: Effects of Ethylene Content and Testing Rate, J. Mater. Sci., 2008, 43(4), p 1357–1365.
W.C. Ko, C.K. Tseng, W.J. Wu, and C.K. Lee, Charge Storage and Mechanical Properties of Porous PTFE and Composite PTFE/COC Electrets, E-Polymers, 2010, 10(1), p 032.
A.P. Vasilev, T.S. Struchkova, L.A. Nikiforov, A.A. Okhlopkova, P.N. Grakovich, E.L. Shim, and J.H. Cho, Mechanical and Tribological Properties of Polytetrafluoroethylene Composites with Carbon Fiber and Layered Silicate Fillers, Molecules, 2019, 24(2), p 224.
R. Endo, K. Jounai, H. Uehara, T. Kanamoto, and R.S. Porter, Uniaxial Drawing of Polytetrafluoroethylene Virgin Powder by Extrusion Plus Cold Tensile Draw, J. Polym. Sci. Part B-Polym. Phys., 1998, 36(14), p 2551–2562.
D. Vavlekas, M. Ansari, H. Hao, F. Fremy, J.L. McCoy, and S.G. Hatzikiriakos, Zero Poisson’s Ratio PTFE in Uniaxial Extension, Polym. Test., 2016, 55, p 143–151.
M.P. Walker, N. Alderman, C.S. Petrie, J. Melander, and J. McGuire, Correlation of Impression Removal Force with Elastomeric Impression Material Rigidity and Hardness, J. Prosthodont. Implant Esthet. Reconstruct. Dent., 2013, 22(5), p 362–366.
V.S. Cecon, P.F. Da Silva, K.L. Vorst, and G.W. Curtzwiler, The Effect of Post-Consumer Recycled Polyethylene (PCRPE) on the Properties of Polyethylene Blends of Different Densities, Polym. Degrad. Stab., 2021, 190, p 109627.
H.A. Afifi, M.M. Al-Ackad, and T. Imamura, Polymethyl Methacrylate, Polystyrene and Polyvinyl Chloride: Determination of Elastic Constants by Water Immersion Ultrasonic Sing-around Method, Kautsch. Gummi Kunstst., 2002, 55(5), p 307–310.
C.H. Xue, H. Nan, Y.H. Lu, H.Y. Chen, C.Y. Zhao, and S.A. Xu, Effects of Inorganic-Organic Surface Modification on the Mechanical and Thermal Properties of Polyvinyl Chloride Composites Reinforced with Fly-Ash, Polym. Compos., 2021, 42(4), p 1867–1877.
K. Ermis, H. Unal, and M. Gunay, Glass Bead Effects on Tribological and Mechanical Properties of Plasticized Polyvinyl Chloride Cable Used in Vehicles as a Filler, Mater. Lett., 2021, 304, p 2432–2439.
K. Friedrich, H.J. Sue, P. Liu, and A.A. Almajid, Scratch Resistance of High Performance Polymers, Tribol. Int., 2011, 44(9), p 1032–1046.
J.M. Park and D.S. Kim, The Influence of Crystallinity on Interfacial Properties of Carbon and SiC Two-Fiber/Polyetheretherketone (PEEK) Composites, Polym. Compos., 2000, 21(5), p 789–797.
C.T. Pan, T.T. Wu, C.F. Liu, C.Y. Su, W.J. Wang, and J.C. Huang, Study of Scratching Mg-Based Bmg Using Nanoindenter with Berkovich Probe, Mater. Sci. Eng. Struct. Mater. Prop. Microstruct. Process., 2010, 527(9), p 2342–2349.
M. Liu and F. Yan, Comparison of Microscratch Responses of Metals between Berkovich and Rockwell C Indenters under Progressive Normal Force, Tribol. Lett., 2021, 69(4), p 8564.
P. Cai, Y. Lin, Z. Ren, and D. Chen, Simulation Analysis of Chemical Mechanical Polishing Material Removal of Interconnection Chip, J. Fuzhou Univ. (Nat. Sci. Edit.), 2017, 45(5), p 692–698.
H. Pelletier, A.-L. Durier, C. Gauthier, and R. Schirrer, Viscoelastic and Elastic-Plastic Behaviors of Amorphous Polymeric Surfaces During Scratch, Tribol. Int., 2008, 41(11), p 975–984.
N. Aleksy, G. Kermouche, A. Vautrin, and J.M. Bergheau, Numerical Study of Scratch Velocity Effect on Recovery of Viscoelastic-Viscoplastic Solids, Int. J. Mech. Sci., 2010, 52(3), p 455–463.
C. Gao and M. Liu, Effect of Sample Tilt on Measurement of Friction Coefficient by Constant-Load Scratch Testing of Copper with a Spherical Indenter, J. Test. Eval., 2020, 48(2), p 970–989.
S.D. Mcadams, T.Y. Tsui, W.C. Oliver, and G.M. Pharr, Effects of Interlayers on the Scratch Adhesion Performance of Ultra-Thin Films of Copper and Gold on Silicon Substrates, MRS Proc., 1994, 356, p 809.
T.W. Scharf and J.A. Barnard, Nanotribology of Ultrathin A:SiC/SiC-N Overcoats Using a Depth Sensing Nanoindentation Multiple Sliding Technique, Thin Solid Films, 1997, 308–309, p 340–344.
J. Zhang, Y. Wei, T. Sun, A. Hartmaier, Y. Yan, and X. Li, Twin Boundary Spacing-Dependent Friction in Nanotwinned Copper, Phys. Rev. B, 2012, 85(5), p 054109.
S. Gao, H.G. Li, R.K. Kang, Y. Zhang, and Z.G. Dong, Effect of Strain Rate on the Deformation Characteristic of AlN Ceramics under Scratching, Micromachines, 2021, 12(1), p 77.
K.J. Li, B.Y.H. Ni, and J.C.M. Li, Stick-Slip in the Scratching of Styrene-Acrylonitrile Copolymer, J. Mater. Res., 1996, 11(6), p 1574–1580.
Z. Li, F. Zhang, X. Luo, and Y. Cai, Fundamental Understanding of the Deformation Mechanism and Corresponding Behavior of Rb-SiC Ceramics Subjected to Nano-Scratch in Ambient Temperature, Appl. Surf. Sci., 2019, 469, p 674–683.
C. Li, F. Zhang, Y. Ding, and L. Liu, Surface Deformation and Friction Characteristic of Nano Scratch at Ductile-Removal Regime for Optical Glass BK7, Appl. Opt., 2016, 55(24), p 6547–6553.
M. Liu, and J. Wu, Scratch Behaviour of Materials under Progressive Load by Conical Indenter, Chin. J. Mater. Res., 2022, 36(3), p 191–205.
N.K. Myshkin, M.I. Petrokovets, and A.V. Kovalev, Tribology of Polymers: Adhesion, Friction, Wear, and Mass-Transfer, Tribol. Int., 2005, 38(11–12), p 910–921.
M.M. Hossain, H. Jiang, and H.J. Sue, Effect of Constitutive Behavior on Scratch Visibility Resistance of Polymers-a Finite Element Method Parametric Study, Wear, 2011, 270(11–12), p 751–759.
J.W. Zhang, H. Jiang, C.K. Jiang, G.Z. Kang, Q.H. Kan, and Y.H. Li, Experimental and Numerical Investigations of Evaluation Criteria and Material Parameters’ Coupling Effect on Polypropylene Scratch, Polym. Eng. Sci., 2018, 58(1), p 118–122.
J. Chu, C. Xiang, H.J. Sue, and R.D. Hollis, Scratch Resistance of Mineral-Filled Polypropylene Materials, Polym. Eng. Sci., 2000, 40(4), p 944–955.
J.A. Williams, Analytical Models of Scratch Hardness, Tribol. Int., 1996, 29(8), p 675–694.
W.B. Gu, Z.Q. Yao, and X.G. Liang, Material Removal of Optical Glass BK7 During Single and Double Scratch Tests, Wear, 2011, 270(3–4), p 241–246.
Y. Xu, D. Li, J.B. Shen, S.Y. Guo, and H.J. Sue, Research Progress in Scratch Behaviors of Polymeric Materials, Acta Polym. Sin., 2018, 10, p 1262–1278.
B. Bhatt, T. Murthy, K. Singh, A. Sashanka, B. Vishwanadh, J. Sonber, K. Sairam, G. Nageswara Rao, T. Srinivasa Rao, and V. Kain, Scratch Testing of Hot-Pressed Monolithic Chromium Diboride (CrB2) and CrB2 + MoSi2 Composite, J. Mater. Eng. Perform, 2017, 26(10), p 5043–5055.
M. Wong, A. Moyse, F. Lee, and H.J. Sue, Study of Surface Damage of Polypropylene under Progressive Loading, J. Mater. Sci., 2004, 39(10), p 3293–3308.
D. Zhang, Y. Sun, C.H. Gao, and M. Liu, Measurement of Fracture Toughness of Copper Via Constant-Load Microscratch with a Spherical Indenter, Wear, 2020, 444, p 203158.
R. Hadal, A. Dasari, J. Rohrmann, and R.D.K. Misra, Susceptibility to Scratch Surface Damage of Wollastonite- and Talc-Containing Polypropylene Micrometric Composites, Mater. Sci. Engi. Struct. Mater. Prop. Microstruct. Process., 2004, 380(1–2), p 326–339.
M. Wong, G.T. Lim, A. Moyse, J.N. Reddy, and H.J. Sue, A New Test Methodology for Evaluating Scratch Resistance of Polymers, Wear, 2004, 256(11–12), p 1214–1227.
G. Zhang, C. Zhang, P. Nardin, W.Y. Li, H. Liao, and C. Coddet, Effects of Sliding Velocity and Applied Load on the Tribological Mechanism of Amorphous Poly-Ether-Ether-Ketone(PEEK), Tribol. Int., 2008, 41(2), p 79–86.
C. Gao and M. Liu, Effects of Normal Load on the Coefficient of Friction by Microscratch Test of Copper with a Spherical Indenter, Tribol. Lett., 2019, 67(1), p 8.
C. Gao and M. Liu, Instrumented Indentation of Fused Silica by Berkovich Indenter, J. Non-Cryst. Solids, 2017, 475, p 151–160.
C. Gauthier, S. Lafaye, and R. Schirrer, Elastic Recovery of a Scratch in a Polymeric Surface: Experiments and Analysis, Tribol. Int., 2001, 34(7), p 469–479.
B.J. Briscoe, P.D. Evans, E. Pelillo, and S.K. Sinha, Scratching Maps for Polymers, Wear, 1996, 200(1–2), p 137–147.
B.J. Briscoe, E. Pelillo, and S.K. Sinha, Scratch Hardness and Deformation Maps for Polycarbonate and Polyethylene, Polym. Eng. Sci., 1996, 36(24), p 2996–3005.
R.T. Zhu, Y.F. Li, X.X. Zhang, and J.Q. Zhou, Strain-Rate Sensitivity of Scratch Hardness and Deformation Mechanism in Nanocrystalline Ni under Micro-Scratch Testing, J. Mater. Sci., 2016, 51(12), p 5889–5900.
M.M. Hossain, R. Minkwitz, P. Charoensirisomboon, and H.J. Sue, Quantitative Modeling of Scratch-Induced Deformation in Amorphous Polymers, Polymer, 2014, 55(23), p 6152–6166.
E.M. Arruda, M.C. Boyce, and H. Quintusbosz, Effects of Initial Anisotropy on the Finite Strain Deformation-Behavior of Glassy-Polymers, Int. J. Plast, 1993, 9(7), p 783–811.
E.M. Arruda and M.C. Boyce, Evolution of Plastic Anisotropy in Amorphous Polymers During Finite Straining, Int. J. Plast, 1993, 9(6), p 697–720.
O.A. Hasan and M.C. Boyce, A Constitutive Model for the Nonlinear Viscoelastic Viscoplastic Behavior of Glassy-Polymers, Polym. Eng. Sci., 1995, 35(4), p 331–344.
D. Zhang, Y. Sun, C. Gao, and M. Liu, Measurement of Fracture Toughness of Copper Via Constant-Load Microscratch with a Spherical Indenter, Wear, 2020, 444, p 5452.
S.L. Zhang and J.C.M. Li, Slip Process of Stick-Slip Motion in the Scratching of a Polymer, Mater. Sci. Eng. A, 2003, 344(1–2), p 182–189.
P. Kurkcu, L. Andena, and A. Pavan, An Experimental Investigation of the Scratch Behaviour of Polymers: 1 Influence of Rate-Dependent Bulk Mechanical Properties, Wear, 2012, 290, p 86–93.
S.K. Sinha and D.B.J. Lim, Effects of Normal Load on Single-Pass Scratching of Polymer Surfaces, Wear, 2006, 260(7–8), p 751–765.
E. Amitay-Sadovsky and H.D. Wagner, Evaluation of Young’s Modulus of Polymers from Knoop Microindentation Tests, Polymer, 1998, 39(11), p 2387–2390.
M. Liu and H. Proudhon, Finite Element Analysis of Contact Deformation Regimes of an Elastic-Power Plastic Hardening Sinusoidal Asperity, Mech. Mater., 2016, 103, p 78–86.
P. Kurkcu, L. Andena, and A. Pavan, An Experimental Investigation of the Scratch Behaviour of Polymers-2: Influence of Hard or Soft Fillers, Wear, 2014, 317(1–2), p 277–290.
M. Liu, X. Liu, and C. Gao, Microscratch Properties of Polycarbonate by Spherical Indenter, Tribology, 2021, 21, p 890–901.
M. Liu, Q. Zheng, and C. Gao, Characterization of Mechanical Properties of Bulk Metallic Glasses Based on Knoop Hardness, Acta Mech. Solida Sin., 2021, 42(4), p 376–392.
A. Abd El-Fattah, H. Youssef, M.A.H. Gepreel, R. Abbas, and S. Kandil, Surface Morphology and Mechanical Properties of Polyether Ether Ketone (PEEK) Nanocomposites Reinforced by Nano-Sized Silica (SiO2) for Prosthodontics and Restorative Dentistry, Polymers, 2021, 13(17), p 3006.
S.L. Zhang and J.C.M. Li, Slip Process of Stick-Slip Motion in the Scratching of a Polymer, Mater. Sci. Eng. Struct. Mater. Prop. Microstruct. Process., 2003, 344(1–2), p 182–189.
W. Zhou, Y. He, and X. Lu, Scratch Deformation Mechanism of Copper Based on Acoustic Emission, Insight–Non-Destruct. Test. Cond. Monit., 2016, 58(5), p 256–263.
L. Liu, H.T. Duan, D. Jia, J.S. Tu, S.P. Zhan, Y.H. Li, X.S. Luo, W. Zhan, W. Xiong, and J. Li, Effect of Contact Pressure on Reciprocating Wear Behavior of PEEK PTFE, and UHMWPE, Polymer-Korea, 2020, 44(6), p 827–834.
M. Liu, C. Huang, and C. Gao, Effect of Sample Tilt and Normal Load on Micro-Scratch Test of Copper with a Spherical Indenter, Tribology, 2021, 41(1), p 27–37.
M. Liu, F. Yan, and C. Gao, Effects of Progressive Normal Force on Microscratch Responses of Metallic Materials, Acta. Metall. Sin., 2021, 57(10), p 1333–1342.
M. Liu, Influence of Sample Tilt and Applied Load on Microscratch Behavior of Copper Under a Spherical Diamond Indenter, Tribol. Lett., 2021, 69(3), p 1–19.
Acknowledgments
This project is supported by National Natural Science Foundation of China (Grant No. 51705082), Fujian Provincial Minjiang Scholar Program (Grant No. 0020-510759), and Science and Education Park of Fuzhou University in the city of Jinjiang (No. 2019-JJFDKY-11).
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ML contributed to conceptualization, methodology, experiment, data curation, validation, and writing–review and editing. PX contributed to writing—original draft, data analysis, investigation, and figure drawing.
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Liu, M., Xie, P. Rate and Load Effects on Scratch Behavior of Thermoplastics by Berkovich Indenter. J. of Materi Eng and Perform 32, 9323–9343 (2023). https://doi.org/10.1007/s11665-022-07787-0
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DOI: https://doi.org/10.1007/s11665-022-07787-0