Abstract
The influence of the austempering process on microstructure evolution, mechanical properties, wear resistance, and corrosion resistance of Cu-bearing carbidic austempered ductile iron (CADI) was investigated. The results show that with an increase in the austempering temperature, the amount of acicular ferrite decreases, the volume fraction and carbon content of retained austenite increase gradually, the hardness and tensile strength decrease, and the impact toughness and corrosion resistance increase. Wear tests show that as the austempering temperature increases, the wear resistance of Cu-bearing CADI is improved and decreases when the temperature exceeds 300 °C. Comparing to the conventional single-step austempering process, two-step austempering process (namely added pre-quenching at 260 °C) significantly improves the wear resistance of Cu-bearing CADI by more than 16% without compromising toughness.
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References
I.C.H. Hughes, Austempered Ductile Irons-their Properties and Significance, Mater. Des., 1985, 6(3), p 124–126. https://doi.org/10.1016/0261-3069(85)90055-X
M. Kuna, M. Springmann, K. Mädler, P. Hübner, and G. Pusch, Fracture Mechanics Based Design of a Railway Wheel Made of Austempered Ductile Iron, Eng. Fract. Mech., 2005, 72(2), p 241–253. https://doi.org/10.1016/j.engfracmech.2003.10.007
A.G. Fuller, Austempered Ductile Irons-Present Applications, Mater. Des., 1985, 6(3), p 127–130. https://doi.org/10.1016/0261-3069(85)90056-1
J. Lefevre and K.L. Hayrynen, Austempered Materials for Powertrain Applications, J. Mater. Eng. Perform., 2013, 22(7), p 1914–1922. https://doi.org/10.1007/s11665-013-0557-4
T. Takahashi, T. Abe, and S. Tada, Effect of Bainite Transformation and Retained Austenite on Mechanical Properties of Austempered Spheroidal Graphite Cast Steel, Metall. Mater. Trans. A, 1996, 27(6), p 1589–1598. https://doi.org/10.1007/bf02649817
G. Artola, I. Gallastegi, J. Izaga, M. Barreña, and A. Rimmer, Austempered Ductile Iron (ADI) Alternative Material for High-Performance Applications, Int. J. Metalcast., 2017, 11(1), p 131–135. https://doi.org/10.1007/s40962-016-0085-8
W. Shizhong and X. Liujie, Review on Research Progress of Steel and Iron Wear-Resistant Material, Acta Metall. Sin., 2019, https://doi.org/10.11900/0412.1961.2019.00370
B. Stokes, N. Gao, and P.A.S. Reed, Effects of Graphite Nodules on Crack Growth Behaviour of Austempered Ductile Iron, Mater. Sci. Eng., A, 2007, 445–446, p 374–385. https://doi.org/10.1016/j.msea.2006.09.058
V. Dakre, D.R. Peshwe, S.U. Pathak, and A. Likhite, Effect of Austenitization Temperature on Microstructure and Mechanical Properties of Low-Carbon-Equivalent Austempered Carbidic Ductile Iron, Int. J. Miner. Metall. Mater., 2018, 25(7), p 770–778. https://doi.org/10.1007/s12613-018-1625-4
Y.C. Peng, H.J. Jin, J.H. Liu, and G.L. Li, Influence of Cooling Rate on the Microstructure and Properties of a New Wear Resistant Carbidic Austempered Ductile Iron (CADI), Mater. Charact., 2012, 72, p 53–58. https://doi.org/10.1016/j.matchar.2012.07.006
S. Sebastián, J. Sikora, and R.C. Dommarco, Influence of Chemical Composition and Solidification Rate on the Abrasion and Impact Properties of CADI, ISIJ Int., 2009, 49(8), p 1239–1245. https://doi.org/10.2355/isijinternational.49.1239
O. Eric, D. Rajnovic, S. Zec, L. Sidjanin, and M.T. Jovanović, Microstructure and Fracture of Alloyed Austempered Ductile Iron, Mater. Charact., 2006, 57(4–5), p 211–217. https://doi.org/10.1016/j.matchar.2006.01.014
S.K. Putatunda, Development of Austempered Ductile Cast Iron (ADI) with Simultaneous High Yield Strength and Fracture Toughness by a Novel Two-Step Austempering Process, Mater. Sci. Eng., A, 2001, 315(1), p 70–80. https://doi.org/10.1016/S0921-5093(01)01210-2
H.Q. Cheng, H.G. Fu, S.Q. Ma, J. Lin, and Y.P. Lei, Effects of Austenitizing Process on Microstructures and Properties of Carbidic Austempered Ductile Iron, Mater. Res. Express, 2019, 6, p 016522. https://doi.org/10.1088/2053-1591/aae44c
A. Hegde and S. Sharma, Comparison of Machinability of Manganese Alloyed Austempered Ductile Iron Produced Using Conventional and Two Step Austempering Processes, Mater. Res. Expres, 2018, https://doi.org/10.1088/2053-1591/aac254
J. Yang and S.K. Putatunda, Improvement in Strength and Toughness of Austempered Ductile Cast Iron by a Novel Two-Step Austempering Process, Mater. Des., 2004, 25(3), p 219–230. https://doi.org/10.1016/j.matdes.2003.09.021
A.H. Elsayed, M.M. Megahed, A.A. Sadek, and K.M. Abouelela, Fracture Toughness Characterization of Austempered Ductile Iron Produced using Both Conventional and Two-Step Austempering Processes, Mater. Des., 2009, 30(6), p 1866–1877. https://doi.org/10.1016/j.matdes.2008.09.013
V. Dakre, D.R. Peshwe, S.U. Pathak, and A. Likhite, Mechanical Characterization of Austempered Ductile Iron Obtained by Two Step Austempering Process, Trans. Indian Inst. Met., 2017, 70(9), p 2381–2387. https://doi.org/10.1007/s12666-017-1099-5
C. Han, Y.F. Sun, Y. Wu, and Y.H. Ma, Effects of Vanadium and Austempering Temperature on Microstructure and Properties of CADI, Metallogr. Microstruct. Anal., 2015, 4(3), p 135–145. https://doi.org/10.1007/s13632-015-0197-1
U. Batra, S. Ray, and S.R. Prabhakar, Austempering and Austempered Ductile Iron Microstructure in Copper Alloyed Ductile Iron, J. Mater. Eng. Perform., 2003, 12(4), p 426–429. https://doi.org/10.1361/105994903770342962
S.P. Mahadik, M.S. Harne, and V.B. Raka, Study on Effect of Austempering Temperature and Time on the Corrosion Resistance of Carbidic Austempered Ductile Iron (CADI) Material, Int. J. Sci. Res. Dev., 2017, 13(1), p 234–240. https://doi.org/10.29070/JAST
R. Nan, H.G. Fu, S.Q. Ma, P.H. Yang, J. Lin, X.Y. Guo, and Y.P. Lei, Microstructure and Properties of Cu-Bearing Carbidic Austempered Ductile Iron, Int. J. Mater. Res., 2019, 110(7), p 621–635. https://doi.org/10.3139/146.111787
R. Nan, H.G. Fu, P.H. Yang, J. Lin, and Y.P. Lei, Effect of Austenitizing Temperature on the Microstructure Evolution and Properties of Cu-Bearing CADI, Mater. Test., 2019, 61(9), p 865–874. https://doi.org/10.3139/120.111394
P.H. Yang, H.G. Fu, R. Nan, X.Y. Guo, J. Lin, and Y.P. Lei, Effect of Ti Modification on Microstructures and Properties of Carbidic Austempered Ductile Iron, J. Mater. Eng. Perform., 2019, 28(4), p 2335–2347. https://doi.org/10.1007/s11665-019-03986-4
P.H. Yang, H.G. Fu, J. Lin, H.Q. Cheng, and Y.P. Lei, Experimental and Ab Initio Study of the Influence of a Compound Modifier on Carbidic Ductile Iron, Metall. Res. Technol., 2019, https://doi.org/10.1051/metal/2018124
P.H. Yang, H.G. Fu, X.W. Zhao, J. Lin, and Y.P. Lei, Wear Behavior of CADI, Obtained at Different Austenitizing Temperatures, Tribol. Int., 2019, 140, p 105876. https://doi.org/10.1016/j.triboint.2019.105876
X. Sun, Y. Wang, D.Y. Li, and G. Wang, Modification of Carbidic Austempered Ductile Iron with Nano Ceria for Improved Mechanical Properties and Abrasive Wear Resistance, Wear, 2013, 301(1–2), p 116–121. https://doi.org/10.1016/j.wear.2012.12.018
Y.C. Peng, H.J. Jin, J.H. Liu, and G.L. Li, Effect of Boron on the Microstructure and Mechanical Properties of Carbidic Austempered Ductile Iron, Mater. Sci. Eng., A, 2011, 529, p 321–325. https://doi.org/10.1016/j.msea.2011.09.034
C.H. Hsu and M.L. Chen, Corrosion Behavior of Nickel Alloyed and Austempered Ductile Irons in 3.5% Sodium Chloride, Corros. Sci., 2010, 52(9), p 2945–2949. https://doi.org/10.1016/j.corsci.2010.05.006
M.L. Ding, B.J. Yu, L. Sun, and X.J. Yu, Effects of Heat Treatment on Microstructure and Mechanical Properties of High Ni-Cr Centrifugal Composite Ductile Cast Iron Rolls, Heat Treat. Met., 2014, 39(11), p 89–92. https://doi.org/10.13251/j.issn.0254-6051.2014.11.021
J. Yang and S.K. Putatunda, Effect of Microstructure on Abrasion Wear Behavior of Austempered Ductile Cast Iron (ADI) Processed by a Novel Two-Step Austempering Process, Mater. Sci. Eng., A, 2005, 406(1–2), p 217–228. https://doi.org/10.1016/j.msea.2005.06.036
P.P. Rao and S.K. Putatunda, Investigations on the Fracture Toughness of Austempered Ductile Irons Austenitised at Different Temperatures, Mater. Sci. Eng., A, 2003, 349, p 136–149. https://doi.org/10.1016/s0921-5093(02)00633-0
J.H. Liu, G.L. Li, X.B. Zhao, X.Y. Hao, and J.J. Zhang, Effect of Austempering Temperature on Microstructure and Properties of Carbide Austempered Ductile Iron, Adv. Mater. Res., 2011, 284–286, p 1085–1088. https://doi.org/10.4028/www.scientific.net/amr.284-286.1085
S.K. Putatunda and P.K. Gadicherla, Effect of Austempering Time on Mechanical Properties of a Low Manganese Austempered Ductile Iron, J. Mater. Eng. Perform., 2000, 9(2), p 193–203. https://doi.org/10.1361/105994900770346150
K.S. Ravishankar, P.P. Rao, and K.R. Udupa, Improvement in Fracture Toughness of Austempered Ductile Iron by Two-Step Austempering Process, Int. J. Cast Met. Res., 2010, 23(6), p 330–343. https://doi.org/10.1179/136404610X12693537270091
C.H. Hsu and K.T. Lin, Effects of Copper and Austempering on Corrosion Behavior of Ductile Iron in 3.5 Pct Sodium Chloride, Metall. Mater., 2014, 45(3), p 1517–1523. https://doi.org/10.1007/s11661-013-2059-2
P.H. Yang, H.G. Fu, X.W. Zhao, J. Lin, and Y.P. Lei, Wear Behavior of CADI, Obtained at Different Austenitizing Temperatures, Tribol. Int., 2019, https://doi.org/10.1016/j.triboint.2019.105876
X.H. Sun, X.B. Zou, G.J. Yin, K. Jiang, and Y.J. Tang, Electrochemical and Microscopic Investigation on Passive Behavior of Ductile Iron in Simulated Cement-Mortar Pore Solution, Constr. Build. Mater., 2017, 150, p 703–713. https://doi.org/10.1016/j.conbuildmat.2017.06.042
J. Yang and S.K. Putatunda, Influence of a Novel Two-Step Austempering Process on the Strain-Hardening Behavior of Austempered Ductile Cast Iron (ADI), Mater. Sci. Eng., A, 2004, 382(1–2), p 265–279. https://doi.org/10.1016/j.msea.2004.04.076
S.K. Putatunda, S. Unni, and G. Lawes, Mechanical and Magnetic Properties of a New Austenitic Structural Steel, Mater. Sci. Eng., A, 2005, 406(1–2), p 254–260. https://doi.org/10.1016/j.msea.2005.06.056
C.D. Wagner, W.M. Riggs, and L.E. Davi. Handbook of X-Ray Photoelectron Spectroscopy. Perkin-Elmer Corporation, Physical Electronic Division, Eden Prairle, MN 1979. https://doi.org/10.1002/sia.740030412
E.S. Ilton, J.E. Post, P.J. Heaney, F.T. Ling, and S.N. Kerisita, XPS Determination of Mn Oxidation States in Mn (Hydr)oxides, Appl. Surf. Sci., 2016, 336(15), p 475–485. https://doi.org/10.1016/j.apsusc.2015.12.159
S. Balos, D. Rajnovic, M. Dramicanin, D. Labus, O. Eric-Cekic, J. Grbovic-Novakovic, and L. Sidjanin, Abrasive Wear Behaviour of ADI, Material with Various Retained Austenite Content, Int. J. Cast Met. Res., 2016, 29(4), p 187–193. https://doi.org/10.1080/13640461.2015.1125982
S.K. Putatunda, S. Kesani, R. Tackett, and G. Lawes, Development of Austenite Free ADI (Austempered Ductile Cast Iron), Mater. Sci. Eng., A, 2006, 435(11), p 112–122. https://doi.org/10.1016/j.msea.2006.07.051
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The authors would like to thank the financial support for this work from National Natural Science Foundation of China under Grant (51775006).
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Nan, R., Fu, H., Yang, P. et al. Microstructure Evolution and Wear Resistance of Cu-Bearing Carbidic Austempered Ductile Iron after Austempering. J. of Materi Eng and Perform 29, 2440–2459 (2020). https://doi.org/10.1007/s11665-020-04788-9
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DOI: https://doi.org/10.1007/s11665-020-04788-9