Abstract
Commercial purity aluminum was reinforced with different percentages of carbon nanohorns (CNH) using ball milling (1 h) followed by spark plasma sintering (SPS) at 550 °C for 5 min under 50 MPa pressure with heating rate 100 °C/min. The microstructure, hardness and compression properties of the spark-plasma-sintered carbon-nanohorns-reinforced aluminum (Al-CNH) composites were evaluated. Transmission electron microscopy revealed a uniform distribution of 0.3% CNH in Al, but above 0.3% CNH, agglomeration occurred. The compression strength of Al-0.3%CNH composites increased by 44% compared to the milled Al sample without CNH.
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S. Iijima, M. Yudasaka, R. Yamada, S. Bandow, K. Suenaga, F. Kokai et al., Nano-Aggregates of Single-Walled Graphitic Carbon Nanohorns, Chem. Phys. Lett., 1999, 309, p 165–170
T. Yamaguchi, S. Bandow, and S. Iijima, Synthesis of Carbon Nanohorn Particles by Simple Pulsed Arc Discharge Ignited Between Pre-heated Carbon Rods, Chem. Phys. Lett., 2004, 389, p 181–185
X. Sun, W. Bao, Y. Lv, J. Deng, and X. Wang, Synthesis of High Quality Single-Walled Carbon Nanotubes by Arc Discharge Method in Large Scale, Mater. Lett., 2007, 61, p 3956–3958
T. Azami, D. Kasuya, R. Yuge, M. Yudasaka, S. Iijima, T. Yoshitake et al., Large-Scale Production of Single-Wall Carbon Nanohorns with High Purity, J. Phys. Chem. C, 2008, 112, p 1330–1334
T. Isshiki, M. Hashimoto, M. Morii, Y. Ota, K. Kaneda, H. Takahashi, M. Yudasaka, S. Iijima, and F. Okino, Preparation and Mechanical Properties of Rubber Composites Reinforced with Carbon Nanohorns, J. Nanosci. Nanotechnol., 2010, 10, p 3810–3814
D.B. Miracle, Metal Matrix Composites-From Science to Technological Significance, Compos. Sci. Technol., 2005, 65, p 2526–2540
Z.Y. Liu, K. Zhao, B.L. Xiao, W.G. Wang, and Z.Y. Ma, Fabrication of CNT/Al Composites with Low Damage to CNTs by a Novel Solution-Assisted Wet Mixing Combined with Powder Metallurgy Processing, Mater. Des., 2016, 97, p 424–430
B. Chen, J. Shen, X. Ye, L. Jia, S. Li, J. Umeda, M. Takahashi, and K. Kondoh, Length Effect of Carbon Nanotubes on the Strengthening Mechanisms in Metal Matrix Composites, Acta Mater., 2017, 140, p 317–325
B. Guo, S. Ni, J. Yi, R. Shen, Z. Tang, Y. Du, and M. Song, Microstructures and Mechanical Properties of Carbon Nanotubes Reinforced pure Aluminum Composites Synthesized by Spark Plasma Sintering and Hot Rolling, Mater. Sci. Eng., A, 2017, 698, p 282–288
N. Saheb, Z. Iqbal, A. Khalil, A.S. Hakeem, N. Al Aqeeli, T. Laoui, A.M. Al-Qutub, and R. Kirchner, Spark Plasma Sintering of Metals and Metal Matrix Nanocomposites: A Review, J. Nanomater., 2012, 983470, p 1–13
C. Masuda, Y.S. Nishimiya, and J. Tang, Fabrication of Carbon Nanotube(MWCNT) Reinforced Aluminum Alloy Matrix Composite, TMS Annual Meeting, 2007, p 115–119
H. Kwon, M. Estili, K. Takagi, T. Miyazaki, and A. Kawasaki, Combination of Hot Extrusion and Spark Plasma Sintering for Producing Carbon Nanotube Reinforced Aluminum Matrix Composites, Carbon, 2009, 47, p 570–577
H. Kwon, D.H. Park, J.F. Silvain, and A. Kawasaki, Investigation of Carbon Nanotube Reinforced Aluminum Matrix Composite Materials, Compos. Sci. Technol., 2010, 70, p 546–550
H. Kwon, M. Leparoux, and A. Kawasaki, Functionally Graded Dual-Nanoparticulate-Reinforced Aluminium Matrix Bulk Materials Fabricated by Spark Plasma Sintering, J. Mater. Sci. Technol., 2014, 30, p 736–742
K. Morsi, A.M.K. Esawi, P. Borah, S. Lanka, and A. Sayed, Characterization and Spark Plasma Sintering of Mechanically Milled Aluminum-Carbon Nanotube (CNT) Composite Powders, J. Compo. Mater., 2010, 44, p 1991–2003
I.Y. Kim, J.H. Lee, G.S. Lee, S.H. Baik, Y.J. Kim, and Y.Z. Lee, Friction and Wear Characteristics of the Carbon Nanotube-Aluminum Composites with Different Manufacturing Conditions, Wear, 2009, 267, p 593–598
V. Yadav and S.P. Harimkar, Microstructure and Properties of Spark Plasma Sintered Carbon Nanotube Reinforced Aluminum Matrix Composites, Adv. Eng. Mater., 2011, 13, p 1128–1134
H. Choi, L. Wang, D. Cheon, and W. Lee, Preparation by Mechanical Alloying of Al Powders with Single-, Double-, and Multi-walled Carbon Nanotubes for Carbon/Metal Nanocomposites, Compos. Sci. Technol., 2013, 74, p 91–98
H.J. Choi, S.M. Lee, and D.H. Bae, Wear Characteristic of Aluminum-Based Composites Containing Multi-walled Carbon Nanotubes, Wear, 2010, 270, p 12–18
M. Jagannatham, M.S.S. Saravanan, K. Sivaprasad, and S.P. Kumaresh Babu, Mechanical and Tribological Behavior of Multiwalled Carbon nanotubes Reinforced AA7075 Composites Prepared by Powder Metallurgy and Hot Extrusion, J. Mater. Eng. Perform., 2018, 27(11), p 5675–5688
Y.F. Wu, G.Y. Kim, and A.M. Russell, Mechanical Alloying of Carbon Nanotube and Al6061 Powder for Metal Matrix Composites, Mater. Sci. Eng., A, 2012, 532, p 558–566
Y.F. Wu, G.Y. Kim, and A.M. Russell, Effects of Mechanical Alloying on an Al6061-CNT Composite Fabricated by Semi-solid Powder Processing, Mater. Sci. Eng., A, 2012, 538, p 164–172
R. Pérez-Bustamante, F. Pérez-Bustamante, I. Estrada-Guel, L. Licea-Jiménez, M. Miki-Yoshida, and R. Martínez-Sánchez, Effect of Milling Time and CNT Concentration on Hardness of CNT/Al2024 Composites Produced by Mechanical Alloying, Mater. Charact., 2013, 75, p 13–19
S.W. Lee, H.J. Choi, Y. Kim, and D.H. Bae, Deformation Behaviour of Nanoparticle/Fiber-Reinforced Nanocrystalline Al-Matrix Composites, Mater. Sci. Eng., A, 2007, 449–51, p 782–785
T. Peng and I. Chang, Mechanical Alloying of Multi-walled Carbon Nanotubes Reinforced Aluminum Composite Powder, Powder Technol., 2014, 266, p 7–15
F.Z. Aneta and B. Stanislaw, Manufacturing and Physico-Mechanical Characterization of Carbon Nanohorns/Polyacrylonitrile Nanocomposites, J. Mater. Sci., 2011, 46, p 5680–5689
P. Jojibabu, M. Jagannatham, P. Haridoss, G.D. Janaki Ram, A.P. Deshpande, and S.R. Bakshi, Effect of Different Carbon Nano-fillers on Rheological Properties and Lap Shear Strength of Epoxy Adhesive Joints, Composites A, 2016, 82, p 53–64
B. Debalina, N. Vaishakh, M. Jagannatham, K. Vasantha Kumar, N.S. Karthiselva, R. Vinu, P. Haridoss, and S.R. Bakshi, Effect of Different Nano-carbon Reinforcements on Microstructure and Properties of TiO2 Composites Prepared by Spark Plasma Sintering, Ceram. Int., 2016, 42, p 14266–14277
B. Peng, M. Locascio, P. Zapol, S.Y. Li, S.L. Mielke, G.C. Schatz et al., Measurements of Near-Ultimate Strength for Multiwalled Carbon Nanotubes and Irradiation-Induced Crosslinking Improvements, Nat. Nanotechnol., 2008, 3, p 626–631
M.F. Yu, O. Lourie, M.J. Dyer, K. Moloni, T.F. Kelly, and R.S. Ruoff, Strength and Breaking Mechanism of Multiwalled Carbon Nanotubes Under Tensile Load, Science, 2000, 287, p 637–640
B.A. Joseph, M. Jagannatham, D. Rohit Reddy, and P. Haridoss, Synthesis of Thin Bundled Single Walled Carbon Nanotubes and Nanohorn Hybrids by Arc Discharge Technique in Open Air Atmosphere, Diamond Rel. Mater., 2015, 55, p 12–15
H. Kurita, M. Estili, H. Kwon, T. Miyazaki, W. Zhou, J.-F. Silvain et al., Load-Bearing Contribution of Multi-walled Carbon Nanotubes on Tensile Response of Aluminum, Composites A, 2015, 68, p 133–139
M. Jagannatham, S. Sankaran, and P. Haridoss, Microstructure and Mechanical Behavior of Copper Coated Multiwall Carbon Nanotubes Reinforced Aluminum Composites, Mater. Sci. Eng., A, 2015, 638, p 197–207
F.A. Khalid, O. Beffort, U.E. Klotz, B.A. Keller, P. Gasser, and S. Vaucher, Study of Microstructure and Interfaces in an Aluminum-C60 Composite Material, Acta Mater., 2003, 51, p 4575–4582
H.J. Choi, J.H. Shin, and D.H. Bae, Self-assembled Network Structures in Al/C60 Composites, Carbon, 2010, 48, p 3700–3707
K. Choi, J. Seo, D.H. Bae, and H.J. Choi, Mechanical Properties of Aluminum-Based Nanocomposite Reinforced with Fullerenes, Trans. Nonferrous Met. Soc. China, 2014, 24, p s47–s52
J.H. Shin, K. Choi, S. Shiko, H.J. Choi, and D.H. Bae, Mechanical Damping Behavior of Al/C60-Fullerene Composites with Supersaturated Al-C Phases, Composites B, 2015, 77, p 194–198
H.F.C. Robles and H.A. Calderon, Nanostructured Al/Al4C3 Composites Reinforced with Graphite or Fullerene and Manufactured by Mechanical Milling and Spark Plasma Sintering, Mater. Chem. Phys., 2012, 132, p 815–822
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Jagannatham, M., Sankaran, S. & Haridoss, P. Microstructure and Mechanical Properties of Carbon Nanohorns Reinforced Aluminum Composites Prepared by Ball Milling and Spark Plasma Sintering. J. of Materi Eng and Perform 29, 582–592 (2020). https://doi.org/10.1007/s11665-019-04534-w
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DOI: https://doi.org/10.1007/s11665-019-04534-w