Abstract
Tensile properties of an Al-Si-Mg casting alloy with reduced Si content and Cr addition were investigated at room and high temperatures. It was found that the studied alloy exhibits a remarkable performance up to 200 °C, with comparable or slightly higher strength than typical values for Al-Si-Mg-Cu alloys, commonly used for high-temperature applications, and good elongation. This is due to the choice of proper heat treatment and to the formation of dispersoids containing Cr during heat treatment, which are stable at the considered temperatures, as demonstrated by scanning and transmission electron microscopy (STEM) analysis. Interestingly, exposure to 300 °C during tensile tests enhanced an additional formation of dispersoids. It is believed that heating the material in T6 condition led to such observed dispersoids formation since precursors were already present in the Al matrix. This is not sufficient to avoid material softening at 300 °C, but it represents an interesting point in order to develop alternative heat treatment routes for dispersion-strengthened Al alloys.
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References
Mahle GmbH, Ed., Pistons and Engine Testing, Springer Science & Business Media, Stuttgart, 2012, p 59–76
J. Man, L. Jing, and S. Jie, The Effects of Cu Addition on the Microstructure and Thermal Stability of an Al-Mg-Si Alloy, J. Alloys Compd., 2007, 437, p 146–150
M. Zamani, S. Seifeddine, and A. Jarfors, High Temperature Tensile Deformation Behavior and Failure Mechanisms of an Al-Si-Cu-Mg Cast Alloy—The Microstructural Scale Effect, Mater. Des., 2015, 86, p 361–370
Y. Li, S. Brusethaug, and A. Olsen, Influence of Cu on the Mechanical Properties and Precipitation Behavior of AlSi7Mg0.5 Alloy During Aging Treatment, Scr. Mater., 2006, 54, p 99–103
M. Javidani and D. Larouche, Application of Cast Al-Si Alloys in Internal Combustion Engine Components, Int. Mater. Rev., 2014, 59(3), p 132–158
L. Ceschini, A. Morri, A. Morri, S. Toschi, S. Johansson, and S. Seifeddine, Effect of Microstructure and Overaging on the Tensile Behavior at Room and Elevated Temperature of C355-T6 Cast Aluminum Alloy, Mater. Des., 2015, 83, p 626–634
E. Kilinc and Y. Birol, Optimising the T6 Heat Treatment for Gravity Cast AlSi7MgCu0.5 Alloy V8 Cylinder Heads, Int. J. Cast Met. Res., 2017, 30(4), p 244–250
S. Roy, L. Allard, A. Rodriguez, T. Watkins, and A. Shyam, Comparative Evaluation of Cast Aluminum Alloys for Automotive Cylinder Heads: Part I—Microstructure Evolution, Metall. Mater. Trans. A, 2017, 48(5), p 2529–2542
J.R. Davis, Ed., ASM Speciality Handbook, Aluminum and Aluminum Alloys, ASM International, Davis & Associates, Materials Park, 1993
W. Kasprzak, B. Amirkhiz, and M. Niewczas, Structure and Properties of Cast Al-Si Based Alloy with Zr-V-Ti Additions and Its Evaluation of High Temperature Performance, J. Alloys Compd., 2014, 595, p 67–79
S. Shaha, F. Czerwinski, W. Kasprzak, J. Friedman, and D. Chen, Improving High-Temperature Tensile and Low-Cycle Fatigue Behavior of Al-Si-Cu-Mg Alloys Through Micro-additions of Ti, V, and Zr, Metall. Mater. Trans. A, 2015, 46A, p 3063–3078
S. Shaha, F. Czerwinski, W. Kasprzak, J. Friedman, and D. Chen, Ageing Characteristics and High-Temperature Tensile Properties of Al-Si-Cu-Mg Alloys with Micro-Additions of Cr, Ti, V and Zr, Mater. Sci. Eng. A, 2016, 652, p 353–364
M. Zamani, L. Morini, L. Ceschini, and S. Seifeddine, The Role of Transition Metal Additions on the Ambient and Elevated Temperature Properties of Al-Si Alloys, Mater. Sci. Eng. A, 2017, 693, p 42–50
M. Di Giovanni, E. Cerri, D. Casari, M. Merlin, L. Arnberg, and G. Garagnani, The Influence of Ni and V Trace Elements on High-Temperature Tensile Properties and Aging of A356 Aluminum Foundry Alloy, Metall. Mater. Trans. A, 2016, 47(5), p 2049–2057
L. Lattanzi, M. Di Giovanni, M. Giovagnoli, A. Fortini, M. Merlin, D. Casari, M. Di Sabatino, E. Cerri, and G. Garagnani, Room Temperature Mechanical Properties of A356 Alloy with Ni Additions from 0.5 to 2 wt.%, Metals, 2018, 8, p 224
S. Pramod, A.K.P. Rao, B. Murty, and S. Bakshi, Effect of Sc Addition and T6 Aging Treatment on the Microstructure Modification and Mechanical Properties of A356 Alloy, Mater. Sci. Eng. A, 2016, 674, p 438–450
S. Mondol, T. Alam, R. Banerjee, S. Kumar, and K. Chattopadhyay, Development of a High Temperature High Strength Al Alloy by Addition of Small Amounts of Sc and Mg to 2219 Alloy, Mater. Sci. Eng. A, 2017, 687, p 221–231
A. Farkoosh, X. Grant Chen, and M. Pekguleryuz, Dispersoid Strengthening of a High Temperature Al-Si-Cu-Mg Alloy via Mo Addition, Mater. Sci. Eng. A, 2015, 620, p 181–189
M. Colombo, E. Gariboldi, and A. Morri, Influences of Different Zr Additions on the Microstructure, Room and High Temperature Mechanical Properties of an Al-7Si-0.4 Mg Alloy Modified with 0.25%Er, Mater. Sci. Eng. A, 2018, 713, p 151–160
M. Colombo, E. Gariboldi, and A. Morri, Er Addition to Al-Si-Mg-Based Casting Alloy: Effects on Microstructure, Room and High Temperature Mechanical Properties, J. Alloys Compd., 2017, 708, p 1234–1244
Z. Gao, H. Li, Y. Lai, Y. Ou, and D. Li, Effects of Minor Zr and Er on Microstructure and Mechanical Properties of Pure Aluminum, Mater. Sci. Eng. A, 2013, 580, p 92–98
M. Tocci, R. Donnini, G. Angella, and A. Pola, Effect of Cr and Mn Addition and Heat Treatment on AlSi3Mg Casting Alloy, Mater. Charact., 2017, 123, p 75–82
M. Tocci, M. Losio, P. Suwanpinji, and A. Pola, Experimental Investigation on the Formation of Cr-Containing Dispersoids in an AlSi3 Alloy by X-Ray Synchrotron Radiation, J. Alloys Compd., 2018, 742, p 555–562
M. Tocci, A. Pola, L. Montesano, G. La Vecchia, M. Merlin, and G. Garagnani, Investigation of Mechanical Properties of AlSi3Cr Alloy, Frattura Integr. Strutt., 2017, 42, p 337–351
G. Gottardi, M. Tocci, M. Montesano, and A. Pola, Cavitation Erosion Behaviour of an Innovative Aluminium Alloy for Hybrid Aluminium Forging, Wear, 2018, 394–395, p 1–10
Y. Wang, H. Liao, Y. Wu, and J. Yang, Effect of Si Content on Microstructure and Mechanical Properties of Al-Si-Mg Alloys, Mater. Des., 2014, 53, p 634–638
B. Zhu, P. Leisner, S. Seifeddine, and E. Jarfors, Influence of Si and Cooling Rate on Microstructure and Mechanical Properties of Al-Si-Mg Cast Alloys, Surf. Interface Anal., 2016, 48, p 861–869
D. Dwivedi, R. Sharma, and A. Kumar, Influence of Silicon Content and Heat Treatment Parameters on Mechanical Properties of Cast Al-Si-Mg Alloys, Int. J. Cast Met. Res., 2006, 19(5), p 275–282
S. Joseph and S. Kumar, A Systematic Investigation of Fracture Mechanisms in Al-Si Based Eutectic Alloy-Effect of Si Modification, Mater. Sci. Eng. A, 2013, 588, p 111–124
M. Dighe and A. Gokhale, Relationship Between Microstructural Extremum and Fracture Path in a Cast Al-Si-Mg Alloy, Scr. Mater., 1997, 9(1), p 1435–1440
C. Caceres, C. Davidson, and J. Griffiths, The Deformation and Fracture Behaviour of an AlSiMg Casting Alloy, Mater. Sci. Eng. A, 1995, 197(2), p 171–179
T. Hosch and R. Napolitano, The Effect of the Flake to Fiber Transition in Silicon Morphology on the Tensile Properties of Al-Si Eutectic Alloys, Mater. Sci. Eng. A, 2010, 582(1), p 226–232
A. Fortini, L. Lattanzi, M. Merlin, and G. Garagnani, Comprehensive Evaluation of Modification Level Assessment in Sr-Modified Aluminium Alloys, Int. J. Metalcast., 2018, 12(4), p 697–711
M. Tocci, A. Pola, L. Raza, L. Armellin, and U. Afeltra, Optimization of Heat Treatment Parameters for a Non-conventional Al-Si-Mg Alloy with Cr Addition by DoE Method, Metall. Ital., 2016, 6, p 141–144
S. Shabestari, The Effect of Iron and Manganese on the Formation of Intermetallic Compounds in Aluminum-Silicon Alloys, Mater. Sci. Eng. A, 2004, 383, p 289–298
J. Taylor, Iron-Containing Intermetallic Phases in Al-Si Based Casting Alloys, Procedia Mater. Sci., 2012, 1, p 19–33
M. Drouzy, S. Jacob, and M. Richard, Interpretation of Tensile Results by Means of Quality Index and Probable Yield Strength, AFS Int. Cast Met. J., 1980, 5(2), p 43–50
M. Tiryakioğlu, J. Campbell, and N. Alexopoulos, Quality Indices for Aluminum Alloy Castings: A Critical Review, Metall. Mater. Trans. B, 2009, 40B, p 802–811
C. Càceres, Microstructure Design and Heat Treatment Selection for Casting Alloys Using the Quality Index, J. Mater. Eng. Perform., 2000, 9(2), p 215–221
C. Càceres, I. Svensson, and J. Taylor, Strength-Ductility Behaviour of Al-Si-Cu-Mg Casting Alloys in T6 Temper, Int. J. Cast Met. Res., 2003, 15(5), p 531–543
N. Alexopoulos and M. Tiryakioǧlu, On the Uniform Elongation of Cast Al-7%Si-0.6%Mg (A357) Alloys, Mater. Sci. Eng. A, 2009, 507, p 236–240
E. Sjolander, Heat Treatment of Al-Si-Cu-Mg Casting Alloys, Ph.D. Dissertation, Department of Mechanical Engineering School of Engineering, Jönköping University, 2011.
H. Elhadari, H. Patel, D. Chen, and W. Kasprzak, Tensile and Fatigue Properties of Cast Aluminium Alloy with Ti, Zr and V Additions, Mater. Sci. Eng. A, 2011, 528, p 8128–8138
E. Gariboldi, J. Lemke, L. Rovatti, O. Baer, G. Timelli, and F. Bonollo, High Temperature Behavior of High Pressure Die Cast Alloys Based on the Al-Si-Cu System: The Role Played by Chemical Composition, Metals, 2018, 8(5), p 348
J. Ferguson, H. Lopez, K. Cho, and C. Kim, Temperature Effects on the Tensile Properties of Precipitation-Hardened Al-Mg-Cu-Si Alloys, Metals, 2016, 6, p 43
L. Lodgaard and N. Ryum, Precipitation of Dispersoids Containing Mn and/or Cr in Al-Mg-Si Alloys, Mater. Sci. Eng. A, 2000, 283, p 144–152
R. Hu, T. Ogura, H. Tezuka, T. Sato, and Q. Liu, Dispersoid Formation and Recrystallization Behavior in an Al-Mg-Si-Mn Alloy, J. Mater. Sci. Technol., 2010, 26, p 237
L. Lodgaard and N. Ryum, Precipitation of Chromium Containing Dispersoids in Al-Mg-Si Alloys, Mater. Sci. Technol., 2000, 16, p 599–604
R. Kemsies, B. Milkereit, S. Wenner, R. Holmestad, and O. Kessler, In Situ DSC Investigation Into the Kinetics and Microstructure of Dispersoid Formation in Al-Mn-Fe-Si(-Mg) Alloys, Mater. Des., 2018, 146, p 96–107
D. Askeland, P. Fulay, and W. Wright, The Science and Engineering of Materials, Cengage Learning, Boston, 2011
M. Rahimian, S. Amirkhanlou, P. Blake, and S. Ji, Nanoscale Zr-Containing Precipitates: A Solution for Significant Improvement of High-Temperature Strength in Al-Si-Cu-Mg Alloys, Mater. Sci. Eng. A, 2018, 721, p 328–338
P. Hidnert and H. Krider, Thermal Expansion of Aluminum and Some Aluminum Alloys, J. Res. Natl. Bur. Stand., 1952, 48(3), p 209–220
W. Kasprzak, D. Chen, and S. Shaha, Heat Treatment Development for a Rapidly Solidified Heat Resistant Cast Al-Si Alloy, J. Mater. Eng. Perform., 2013, 22(7), p 1839–1847
H. Lopez, Microstructural Features Associated with the Effect of Temperature on the Dimensional Stability of an Automotive Al-A319 Alloy, AIMS Mater. Sci., 2016, 3(2), p 634–644
Acknowledgments
The authors would like to thank Maxion Wheels Italia Srl for providing the alloy, F. Peli (Dept. of Mechanical and Industrial Engineering of the University of Brescia) for his support in tensile samples preparation and Dr. L. Montesano (Dept. of Mechanical and Industrial Engineering of the University of Brescia) for SEM analysis.
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Tocci, M., Donnini, R., Angella, G. et al. Tensile Properties of a Cast Al-Si-Mg Alloy with Reduced Si Content and Cr Addition at High Temperature. J. of Materi Eng and Perform 28, 7097–7108 (2019). https://doi.org/10.1007/s11665-019-04438-9
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DOI: https://doi.org/10.1007/s11665-019-04438-9