Abstract
The influence of the initial composition on the solidification path, microstructure evolution, thermophysical properties and mechanical properties of Al-Cu-Mg alloys was investigated. The solidification paths of the investigated alloys were determined by analyzing the solidification structure, and then the experimentally determined paths were compared with those from the calculated results. Three of the investigated alloys experienced typical ternary eutectic solidification, and the other four alloys experienced quasiperitectic reactions. Due to differences in the initial compositions, different eutectic morphologies were formed during the solidification process. The binary eutectic phases, (α-Al + Al2Cu) and (α-Al + Al6CuMg4), and the (α-Al + Al6CuMg4 + Al8Mg5) ternary eutectic phase tended to exhibit divorced growth, and the (α-Al + Al2CuMg), (α-Al + Al6CuMg4) and (α-Al + Al2Cu + Al2CuMg) eutectic phases tended to exhibit coupled growth. The results indicated that the initial composition, solidification path, microstructure and morphology could greatly affect the melting enthalpy, microhardness and compressive strength of the investigated Al-Cu-Mg alloys.
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S.W. Chen and C.C. Huang, Solidification Curves of Al-Cu, Al-Mg and Al-Cu-Mg Alloys, Acta Mater., 1996, 44, p 1955–1965
A. Roósz and H.E. Exner, Numerical Modelling of Dendritic Solidification in Aluminium-Rich Al-Cu-Mg Alloys, Acta Metall. Mater., 1990, 38, p 375–380
F.Y. Xie, T. Kraft, Y. Zuo, C.H. Moon, and Y.A. Chang, Microstructure and Microsegregation in Al-Rich Al-Cu-Mg Alloys, Acta Mater., 1999, 47, p 489–500
I. Vušanović and M.J.M. Krane, Microsegregation During Solidification of Al-Cu-Mg alloys with Varying Composition, Int. Commun. Heat Mass Transf., 2002, 29, p 1037–1046
Q. Du, D.G. Eskin, and L. Katgerman, An Efficient Technique for Describing a Multi-component Open System Solidification Path, Calphad., 2008, 32, p 478–484
E.H. Yan, X.Z. Li, Y.Q. Su, D.M. Liu, D.M. Xu, J.J. Guo, and H.Z. Fu, Prediction of the Solidification Path of Al-4.37Cu-27.02Mg Ternary Eutectic Alloy with a Unified Microsegregation Model Coupled with Thermo-Calc, Int. J. Mater. Res., 2013, 104, p 244–254
R. Chen, Q.Y. Xu, and B.C. Liu, Simulation of the Dendrite Morphology and Microsegregation in Solidification of Al-Cu-Mg Aluminum Alloys, Acta Metall. Sin., 2015, 28, p 173–181
S.C. Wang and M.J. Starink, Precipitates and Intermetallic Phases in Precipitation Hardening Al-Cu-Mg-(Li) Based Alloys, Int. Mater. Rev., 2005, 50, p 193–215
S.C. Wang and M.J. Starink, Two Types of S Phase Precipitates in Al-Cu-Mg Alloys, Acta Mater., 2007, 55, p 933–941
J.Z. Liu, S.S. Yang, S.B. Wang, J.H. Chen, and C.L. Wu, The Influence of Cu/Mg Atomic Ratios on Precipitation Scenarios and Mechanical Properties of Al-Cu-Mg Alloys, J. Alloys Compd., 2014, 613, p 139–142
Y. Gan, D. Zhang, W. Zhang, and Y. Li, Effect of Cooling Rate on Microstructure and Mechanical Properties of Squeeze Cast Al-Cu-Mg Alloy, Int. J. Cast Met. Res., 2015, 28, p 50–58
Z.W. Qi, B.Q. Cong, B.J. Qi, H.Y. Sun, G.Z. Jia, and L. Ding, Microstructure and Mechanical Properties of Double-Wire + Arc Additively Manufactured Al-Cu-Mg Alloys, J. Mater. Process. Technol., 2018, 255, p 347–353
R.K.W. Marceau, G. Sha, R. Ferragut, A. Dupasquier, and S.P. Ringer, Solute Clustering in Al-Cu-Mg Alloys During the Early Stages of Elevated Temperature Ageing, Acta Mater., 2010, 58, p 4923–4939
Y.Q. Xu, L.H. Zhan, Z.Y. Ma, M.H. Huang, K. Wang, and Z. Sun, Effect of Heating Rate on Creep Aging Behavior of Al-Cu-Mg Alloy, Mater. Sci. Eng. A, 2017, 688, p 488–497
Y.Q. Xu, L.H. Zhan, M.H. Huang, R.H. Shen, Z.Y. Ma, L.Z. Xu, K. Wang, and X. Wang, Deformation Behavior of Al-Cu-Mg Alloy during Non-isothermal Creep Age Forming Process, J. Mater. Process Technol., 2018, 255, p 26–34
I. Zuiko and R. Kaibyshev, Aging Behavior of an Al-Cu-Mg Alloy, J. Alloys Compd., 2018, 759, p 108–119
P.L.M. Kanta, V.C. Srivastava, K. Venkateswarlu, S. Paswan, B. Mahato, G. Das, K. Sivaprasad, and K.G. Krishna, Corrosion Behavior of Ultrafine-Grained AA2024 Aluminum Alloy Produced by Cryorolling, Int. J. Miner. Metall. Mater., 2017, 24, p 1293–1305
P. Xia, Z.Y. Liu, W.T. Wu, Q. Zhao, P.Y. Ying, and S. Bai, Texture Effect on Fatigue Crack Propagation Behavior in Annealed Sheets of an Al-Cu-Mg Alloy, JMEPEG, 2018, 27, p 4693–4702
J.K. Sunde, D.N. Johnstone, S. Wenner, A.T.J.V. Helvoort, P.A. Midgley, and R. Holmestad, Crystallographic Relationships of T-/S-phase Aggregates in an Al-Cu-Mg-Ag Alloy, Acta Mater., 2019, 166, p 587–596
S. Bai, X.L. Yi, Z.Y. Liu, J. Wang, J.G. Zhao, and P.Y. Ying, The Influence of Preaging on the Strength and Precipitation Behavior of a Deformed Al-Cu-Mg-Ag Alloy, J. Alloys Compd., 2018, 764, p 62–72
G.W. Bo, F.L. Jiang, Z.Y. Dong, G. Wang, and H. Zhang, Revealing the Influence of Pre-precipitation Microstructure on Hot Workability in an Al-Cu-Mg-Zr Alloy, Mater. Sci. Eng. A, 2019, 755, p 147–157
W.L. Zhang, D.H. Xiao, T. Li, J.D. Du, and D.Y. Ding, Microstructure and Mechanical Properties of Two-stage Aged Al-Cu-Mg-Ag-Sm Alloy, Rare Met., 2019, 38, p 42–51
Y.F. Song, X.F. Ding, X.J. Zhao, L.R. Xiao, and C.X. Yu, The Effect of SiC Addition on the Dimensional Stability of Al-Cu-Mg Alloy, J. Alloys Compd., 2018, 750, p 111–116
J.W. Geng, G. Liu, T.R. Hong, M.L. Wang, D. Chen, N.H. Ma, and H.W. Wang, Tuning the Microstructure Features of In Situ Nano TiB2/Al-Cu-Mg Composites to Enhance Mechanical Properties, J. Alloys Compd., 2019, 775, p 193–201
W.W. Yang, Z.M. Guo, L.C. Guo, H.Q. Cao, J. Luo, and A.P. Ye, In Situ Fabrication and Properties of AlN Dispersion Strengthened 2024 Aluminum Alloy, Int. J. Miner. Metall. Mater., 2014, 21, p 1228–1232
N.S. Anas, R.K. Dash, T.N. Rao, and R. Vijay, Effect of Carbon Nanotubes as Reinforcement on the Mechanical Properties of Aluminum-Copper-Magnesium Alloy, JMEPEG, 2017, 26, p 3376–3386
S.E. Hernández-Martínez, J.J. Cruz-Rivera, C.G. Garay-Reyes, and J.L. Hernández-Rivera, Experimental and Numerical Analyses of the Consolidation Process of AA 7075-2 wt.% ZrO2 Powders by Equal Channel Angular Pressing, JMEPEG, 2019, 28, p 154–161
A. Barros, C. Cruz, A.P. Silva, N. Cheung, A. Garcia, O. Rocha, and A. Moreira, Horizontally Solidified Al-3 wt.%Cu-(05 wt.%Mg) Alloys: Tailoring Thermal Parameters, Microstructure, Microhardness, and Corrosion Behavior, Acta Metall. Sin., 2019, 32, p 695–709
J.O. Lima, C.R. Barbosa, I.A.B. Magno, J.M. Nascimento, A.S. Barros, M.C. Oliveira, F.A. Souza, and O.L. Rocha, Microstructural Evolution During Unsteady-Statehorizontal Solidification of Al-Si-Mg (356) Alloy, Trans. Nonferrous Met. Soc. China, 2018, 28, p 1073–1083
R. Chen, Y.F. Shi, Q.Y. Xu, and B.C. Liu, Effect of Cooling Rate on Solidification Parameters and Microstructure of Al-7Si-0.3Mg-0.15Fe Alloy, Trans. Nonferrous Met. Soc. China, 2014, 24, p 1645–1652
G.W. Zhao, X.Z. Li, D.M. Xu, J.J. Guo, H.Z. Fu, Y. Du, and Y.H. He, Thermo-Calc Based Multicomponent Microsegregation Model and Solidification Paths Calculations, China Foundry, 2012, 9, p 269–274
G.W. Zhao, C. Ding, X.C. Ye, C.H. Huang, and H.H. Wu, Influences of Initial Compositions, Dendrite Morphologies and Solid-Back Diffusion on Solidification Path of Al-Si-Mg Alloys, J. Phase Equilib. Diffus., 2018, 39, p 212–225
G.W. Zhao, C. Ding, and M. Gu, Effects of Cooling Rate and Initial Composition on the Solidification Path and Microstructure of Al-Cu-Si Alloys, Int. J. Cast Met. Res., 2019, 32, p 36–45
Acknowledgments
This work was supported by the National Natural Science Foundation of China (Grant No. 51604162), the Opening Fund of Hubei Key Laboratory of Hydroelectric Machinery Design and Maintenance (Grant No. 2017KJX12) and the applied basic research projects of Yichang Science and Technology Bureau (Grant No. A18-302-a05). We wish to thank Harbin Institute of Technology for providing the thermodynamic calculation and data of Al-Cu-Mg alloys.
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Zhao, G., Chen, J., Ding, C. et al. Influence of the Composition on the Solidification Path, Microstructure Evolution and Mechanical Properties of Al-Cu-Mg Alloys. J. of Materi Eng and Perform 28, 6980–6992 (2019). https://doi.org/10.1007/s11665-019-04409-0
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DOI: https://doi.org/10.1007/s11665-019-04409-0