Abstract
The corrosion mechanisms of Cu-7Ni-3Al-1Fe-1Mn (wt.%) alloy in a 3.5% NaCl solution are investigated through a multi-analytical approach. The formation, growth and stable corrosion stage of the stable corrosion layer are reflected by the change of electrochemical response with time. EDS and GI-XRD results show the presence of Cu2(OH)3Cl and Cu2O that are the main corrosion products, with the former predominantly present at topmost corrosion layer, and Cu2O is mainly located in the inner part, followed by aluminum oxide closer to the alloy substrate.
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B. Hou, X. Li, X. Ma, C. Du, D. Zhang, M. Zheng, W. Xu, D. Lu, and F. Ma, The Cost of Corrosion in China, NPJ Mater. Degrad., 2017, 1(1), p p4
G.E. Mcguire, Analysis of Protective Oxide Films on Copper-Nickel Alloys by Auger Spectroscopy, J. Electrochem. Soc., 1978, 125(11), p p1801
A.M. Alfantazi, T.M. Ahmed, and D. Tromans, Corrosion Behavior of Copper Alloys in Chloride Media, Mater. Des., 2009, 30(7), p 2425–2430
G. Kear, B.D. Barker, and K. Stokes, Electrochemical Corrosion Behaviour of 90-10 Cu-Ni Alloy in Chloride-Based Electrolytes, J. Appl. Electrochem., 2004, 34(7), p 659–669
W.A. Badawy, M.M. El-Rabiee, and N.H. Helal, Effect of Nickel Content on the Electrochemical Behavior of Cu-Al-Ni Alloys in Chloride Free Neutral Solutions, Electrochim. Acta, 2011, 56(2), p 913–918
S.C. Vanithakumari, P. Yadavalli, and R.P. George, Development of Hydrophobic Cupronickel Surface with Biofouling Resistance by Sandblasting, Surf. Coat. Technol., 2018, 345, p 89–95
X.C. Huang, H. Lu, and D.Y. Li, Understanding the Corrosion Behavior of Isomorphous Cu-Ni Alloy from Its Electron Work Function, Mater. Chem. Phys., 2016, 173, p 238–245
R.C.N. Liberto, R. Magnabosco, and N. Alonso-Falleiros, Selective Corrosion of 550 °C Aged Cu10Ni-3Al-13Fe Alloy in NaCl Aqueous Solution, Corros. Sci., 2011, 53(5), p 1976–1982
Q. Lei, Z. Li, and C. Dai, Effect of Aluminum on Microstructure and Property of Cu-Ni-Si Alloys, Mater. Sci. Eng. A, 2013, 572(6), p 65–74
Y.R. Cho, Y.H. Kim, and T.D. Lee, Precipitation Hardening and Recrystallization in Cu-4% to 7% Ni-3% Al Alloys, J. Mater. Sci., 1991, 26(11), p 2879–2886
R. Yang, J.B. Wen, Y.J. Zhou, K.X. Song, and Z.C. Song, Effect of Al Element on the Microstructure and Properties of Cu-Ni-Fe-Mn Alloys, Materials, 2018, 11(9), p p1777
W.A. Badawy, K.M. Ismail, and A.M. Fathi, Effect of Ni Content on the Corrosion Behavior of Cu-Ni Alloys in Neutral Chloride Solutions, Electrochim. Acta, 2005, 50(18), p 3603–3608
T. Chang, G. Herting, and Y. Jin, The Golden Alloy Cu5Zn5Al1Sn: Patina Evolution in Chloride-Containing Atmospheres, Corros. Sci., 2018, 133, p 190–203
T. Chang, I.O. Wallinder, and Y. Jin, The Golden Alloy Cu-5Zn-5Al-1Sn: A Multi-analytical Surface Characterization, Corros. Sci., 2018, 131, p 94–103
K.A. Christofidou, K.J. Robinson, and P.M. Mignanelli, The Effect of Heat Treatment on Precipitation in the Cu-Ni-Al Alloy Hiduron®; 130, Mater. Sci. Eng. A, 2017, 692, p 192–198
H. Nady, N.H. Helal, and M.M. El-Rabiee, The Role of Ni Content on the Stability of Cu-Al-Ni Ternary Alloy in Neutral Chloride Solutions, Mater. Chem. Phys., 2012, 134(2-3), p 945–950
H. Yao, J. Wen, and Y. Xiong, Extrusion Temperature Impacts on Biometallic Mg-2.0Zn-0.5Zr-3.0Gd (wt.%) Solid-Solution Alloy, J. Alloys Compd., 2018, 739, p 468–480
X. Ma, L. Xu, and W. Wang, Synthesis and Characterisation of Composite Nanoparticles of Mesoporous Silica Loaded with Inhibitor for Corrosion Protection of Cu-Zn Alloy, Corros. Sci., 2017, 120, p 139–147
W. Wei, G. Chen, and J. Wang, Microstructure and Tensile Properties of Ultrafine Grained Copper Processed by Equal-Channel Angular Pressing, Rare Met., 2006, 25(6), p 697–703
C.I.S. Santos, M.H. Mendonça, and I.T.E. Fonseca, Corrosion of Brass in Natural and Artificial Seawater, J. Appl. Electrochem., 2008, 38(5), p 627–635
H.P. Lee, Kinetics and Mechanisms of Cu Electrodissolution in Chloride Media, J. Electrochem. Soc., 1986, 133(10), p 2035–2043
J. Crousier and A. Beccaria, Behaviour of Cu-Ni Alloys in Natural Sea Water and NaCl Solution, Mater. Corros., 1990, 41(4), p 185–189
S.N. Saud, E. Hamzah, and T. Abubakar, Influence of Silver Nanoparticles Addition on the Phase Transformation, Mechanical Properties and Corrosion Behaviour of Cu-Al-Ni Shape Memory Alloys, J. Alloys Compd., 2014, 612(6), p 471–478
G. Kear, B.D. Barker, and F.C. Walsh, Electrochemical Corrosion of Unalloyed Copper in Chloride Media—A Critical Review, Corros. Sci., 2004, 46(1), p 109–135
H.D. Speckmann, S. Haupt, and H.H. Strehblow, A Quantitative Surface Analytical Study of Electrochemically-Formed Copper Oxides by XPS and X-Ray-Induced Auger Spectroscopy, Surf. Interface Anal., 1988, 11(3), p 148–155
M. Hafner, W. Burgstaller, and A.I. Mardare, Aluminium-Copper-Nickel Thin Film Compositional Spread: Nickel Influence on Fundamental Alloy Properties and Chemical Stability of Copper, Thin Solid Films, 2015, 580(2), p 36–44
M. Ascencio, M. Pekguleryuz, and S. Omanovic, An Investigation of the Corrosion Mechanisms of WE43 Mg Alloy in a Modified Simulated Body Fluid Solution: The Influence of Immersion Time, Corros. Sci., 2014, 87(5), p 489–503
Q.N. Song, N. Xu, Y.F. Bao, Y.F. Jiang, W. Gu, Z. Yang, Y.G. Zheng, and Y.X. Qiao, Corrosion Behavior of Cu40Zn in Sulfide-Polluted 3.5% NaCl Solution, J. Mater. Eng. Perform., 2017, 26(10), p 1–9
J.A. Wharton, R.C. Barik, and G. Kear, The Corrosion of Nickel-Aluminium Bronze in Seawater, Corros. Sci., 2005, 47(12), p 3336–3367
I. Constantinides, A. Adriaens, and F. Adams, Surface Characterization of Artificial Corrosion Layers on Copper Alloy Reference Materials, Appl. Surf. Sci., 2002, 189(1-2), p 90–101
B. Yin, Y. Yin, and Y. Lei, Experimental and Density Functional Studies on the Corrosion Behavior of the Copper-Nickel-Tin Alloy, Chem. Phys. Lett., 2011, 509(4-6), p 192–197
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This work was supported by the National Key R&D Program of China under Grant No. 2016YFB0301400.
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Yang, R., Wen, J., Zhou, Y. et al. An Investigation of the Corrosion Mechanisms of Cu-7Ni-3Al-1Fe-1Mn Alloy in Chloride-Containing Environment. J. of Materi Eng and Perform 28, 2866–2872 (2019). https://doi.org/10.1007/s11665-019-04021-2
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DOI: https://doi.org/10.1007/s11665-019-04021-2